Citation: Yang Li, Xiaoxu Liu, Tianyi Ji, Man Zhang, Xueru Yan, Mengjie Yao, Dawei Sheng, Shaodong Li, Peipei Ren, Zexiang Shen. Potassium ion doped manganese oxide nanoscrolls enhanced the performance of aqueous zinc-ion batteries[J]. Chinese Chemical Letters, ;2025, 36(1): 109551. doi: 10.1016/j.cclet.2024.109551 shu

Potassium ion doped manganese oxide nanoscrolls enhanced the performance of aqueous zinc-ion batteries

Yang Li ^a ,
Xiaoxu Liu ^{a, *,} ,
Tianyi Ji ^a ,
Man Zhang ^a ,
Xueru Yan ^a ,
Mengjie Yao ^a ,
Dawei Sheng ^a ,
Shaodong Li ^a ,
Peipei Ren ^a ,
Zexiang Shen ^b

a.
Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, School of Material Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China
b.
Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore

Received Date: 17 December 2023
Revised Date: 13 January 2024
Accepted Date: 19 January 2024
Available Online: 24 January 2024

Figures(6)

α-MnO₂ is a potential positive electrode material for aqueous zinc-ion batteries, but its electrochemical performance of zinc storage requires further improvement. In this paper, potassium ion-doped manganese dioxide nanoscrolls (KMnO₂) with oxygen vacancy were synthesized by a one-step hydrothermal method. It was observed that the electrochemical specific capacity was 250.9 mAh/g at a current density of 0.2 C, which was better than the existing commercial α-MnO₂. At a high current of 1 C, these batteries demonstrate improved cycle stability. Synchrotron radiation and other experiments as well as DFT theoretical calculations provided additional evidence that K doping was efficient in regulating the metal bond type and the mean charge regulation of covalent bonds with oxygen atoms in MnO₂. When MnO and MnK bonds are present, KMnO₂ showed outstanding adsorption of Zn²⁺ and further enhanced the Zn²⁺ embedding process. Simultaneously, oxygen defects caused by doping boosted the development of the nanoscroll structure, leading to an increase in active sites available for electrochemical reactions and subsequently enhancing the electrical conductivity of α-MnO₂. This study exhibits the potential of optimizing materials based on manganese with the introduction of a potassium doping strategy, resulting in improved performance for aquatic zinc-ion batteries, and presents novel perspectives for related research.
- Manganese dioxide,
- K⁺ doping,
- Nanoscrolls,
- XAFS,
- Aqueous zinc-ion batteries
1. [1]
  X. Liu, T. Ji, H. Guo, et al., Electrochem. Energy Rev. 5 (2021) 401–433. doi: 10.3390/met11030401
2. [2]
  X. Liu, T. Wang, T. Ji, et al., J. Mater. Chem. A 10 (2022) 8031–8046. doi: 10.1039/d1ta10588d
3. [3]
  H. Yang, T. Zhang, D. Chen, et al., Adv. Mater. 35 (2023) e2300053. doi: 10.1002/adma.202300053
4. [4]
  A. Zhang, R. Zhao, Y. Wang, et al., Energy Storage Mater. 16 (2023) 3240–3301. doi: 10.1039/d3ee01344h
5. [5]
  X. Zhao, X. Liang, Y. Li, et al., Energy Storage Mater. 42 (2021) 533–569. doi: 10.1016/j.ensm.2021.07.044
6. [6]
  G. Li, L. Sun, S. Zhang, et al., Adv. Funct. Mater. (2023) 2301291.
7. [7]
  W. Qiu, H. Xiao, H. Feng, et al., Chem. Eng. J. 422 (2021) 129890. doi: 10.1016/j.cej.2021.129890
8. [8]
  S. Kim, B.R. Koo, Y.R. Jo, et al., J. Mater. Chem. A 9 (2021) 17211–17222. doi: 10.1039/d1ta04051k
9. [9]
  B. Yang, D. Li, S. Wang, et al., ACS Appl. Mater. 14 (2022) 18476–18485. doi: 10.1021/acsami.2c01362
10. [10]
  S. Liu, R. Zhang, J. Mao, et al., Sci. Adv. 8 (2022) eabn5097. doi: 10.1126/sciadv.abn5097
11. [11]
  D.L. Chao, W.H. Zhou, F.X. Xie, et al., Sci. Adv. 6 (2020) eaba4098. doi: 10.1126/sciadv.aba4098
12. [12]
  Y. Liu, X. Wu, Chin. Chem. Lett. 33 (2022) 1236–1244. doi: 10.1016/j.cclet.2021.08.081
13. [13]
  B. Tang, L. Shan, S. Liang, et al., Energy Environ. Sci. 12 (2019) 3288–3304. doi: 10.1039/c9ee02526j
14. [14]
  Y. Xu, G. Zhang, J. Liu, et al., Energy Environ. Mater. 6 (2023) e12575. doi: 10.1002/eem2.12575
15. [15]
  J. Lei, L. Jiang, Y.C. Lu, Chem. Phys. Rev. 4 (2023) 021307. doi: 10.1063/5.0146094
16. [16]
  Q. Zhao, A. Song, S. Ding, et al., Adv. Mater. 32 (2020) 2002450. doi: 10.1002/adma.202002450
17. [17]
  Wei Liu, Q. Su, R. Zhu, et al., ACS Appl. Mater. 6 (2023) 6689–6699. doi: 10.1021/acsaem.3c00777
18. [18]
  Z. Wang, Y. Wang, Y. Lin, et al., ACS Appl. Mater. 14 (2022) 47725–47736. doi: 10.1021/acsami.2c13030
19. [19]
  G. Liu, H. Huang, R. Bi, et al., J. Mater. Chem. A 7 (2019) 20806–20812. doi: 10.1039/c9ta08049j
20. [20]
  N. Liang, X. Sun, L. Qi, et al., Energy Technol. 10 (2022) 2200502. doi: 10.1002/ente.202200502
21. [21]
  F.W. Fenta, B.W. Olbasa, M.-C. Tsai, et al., J. Mater. Chem. A 8 (2020) 17595–17607. doi: 10.1039/d0ta04175k
22. [22]
  Z. Qin, Y. Song, D. Yang, et al., ACS Appl. Mater. 14 (2022) 10526–10534. doi: 10.1021/acsami.1c22674
23. [23]
  Y. Yuan, R. Sharpe, K. He, et al., Nat. Sustain. 5 (2022) 890–898. doi: 10.1038/s41893-022-00919-3
24. [24]
  Q. Chen, X. Lou, Y. Yuan, et al., Adv. Mater. 35 (2023) 2306294. doi: 10.1002/adma.202306294
25. [25]
  X. Yang, Y. Ni, Y. Lu, et al., Angew. Chem. Int. Ed. 61 (2022) e202209642. doi: 10.1002/anie.202209642
26. [26]
  Y. Jiao, L. Kang, J. Berry-Gair, et al., J. Mater. Chem. A 8 (2020) 22075–22082. doi: 10.1039/d0ta08638j
27. [27]
  M. Wang, X. Zheng, X. Zhang, et al., Adv. Energy Mater. 11 (2020) 2002904.
28. [28]
  Y. Wang, J. Xie, J. Luo, et al., Small Methods 6 (2022) e2200560. doi: 10.1002/smtd.202200560
29. [29]
  C. Xu, B. Li, H. Du, et al., Angew. Chem. Int. Ed. 124 (2012) 957–959. doi: 10.1002/ange.201106307
30. [30]
  N. Zhang, F. Cheng, J. Liu, et al., Nat. Commun. 8 (2017) 405. doi: 10.1007/978-3-319-70090-8_42
31. [31]
  X. Gao, H. Wu, W. Li, et al., Small 16 (2020) 1905842. doi: 10.1002/smll.201905842
32. [32]
  Y. Huang, J. Mou, W. Liu, et al., Nano-Micro Lett. 11 (2019) 49. doi: 10.1007/s40820-019-0278-9
33. [33]
  P. Ruan, X. Xu, D. Zheng, et al., ChemSusChem 15 (2022) e202201118. doi: 10.1002/cssc.202201118
34. [34]
  D. Chao, C. Ye, F. Xie, et al., Adv. Mater. 32 (2020) 2001894. doi: 10.1002/adma.202001894
35. [35]
  T. Xiong, Z.G. Yu, H. Wu, et al., Adv. Energy Mater. 9 (2019) 1803815. doi: 10.1002/aenm.201803815
36. [36]
  J. Zhang, W. Li, J. Wang, et al., Angew. Chem. Int. Ed. 62 (2023) e202215654. doi: 10.1002/anie.202215654
37. [37]
  K. Han, F. An, F. Yan, et al., J. Mater. Chem. A 9 (2021) 15637–15647. doi: 10.1039/d1ta03994f
38. [38]
  W. Sun, F. Wang, S. Hou, et al., J. Am. Chem. Soc. 139 (2017) 9775–9778. doi: 10.1021/jacs.7b04471
39. [39]
  S. Wang, G. Yuan, J. Yang, et al., ChemSusChem 15 (2022) e202200786. doi: 10.1002/cssc.202200786
40. [40]
  C. Zhu, G. Fang, S. Liang, et al., Energy Storage Mater. 24 (2020) 394–401. doi: 10.1016/j.ensm.2019.07.030
41. [41]
  X. Wu, G. Liu, S. Yang, et al., Chin. Chem. Lett. 34 (2023) 107540. doi: 10.1016/j.cclet.2022.05.054
42. [42]
  J. Tianyi, L. Xiaoxu, Z. Jiupeng, et al., Chem. J. Chin. Univ. 41 (2020) 821–828.
43. [43]
  S. Fleischmann, J.B. Mitchell, R. Wang, et al., Chem. Rev. 120 (2020) 6738–6782. doi: 10.1021/acs.chemrev.0c00170
44. [44]
  C. Choi, D.S. Ashby, D.M. Butts, et al., Nat. Rev. Mater. 5 (2020) 5–19.
45. [45]
  X. Liu, T. Wang, T. Zhang, et al., Adv. Energy Mater. 12 (2022) 202202388.
46. [46]
  T. Ji, X. Liu, H. Wang, et al., Research 6 (2023) 0092. doi: 10.34133/research.0092
47. [47]
  X. Wang, Y. Liu, Z. Wei, et al., Adv. Mater. 34 (2022) 2206812. doi: 10.1002/adma.202206812
48. [48]
  M. Zhang, X. Liu, J. Gu, et al., Chin. Chem. Lett. 34 (2023) 108471. doi: 10.1016/j.cclet.2023.108471
49. [49]
  C. Huang, Q. Wang, D. Zhang, et al., Nano Res. 15 (2022) 8118–8127. doi: 10.1007/s12274-022-4498-9
50. [50]
  Z. You, W. Hua, N. Li, et al., Chin. Chem. Lett. 34 (2023) 107525. doi: 10.1016/j.cclet.2022.05.039
51. [51]
  C. Chen, K. Xu, X. Ji, et al., J. Mater. Chem. A 3 (2015) 12461–12467. doi: 10.1039/C5TA01930C
52. [52]
  Y. Ma, M. Xu, R. Liu, et al., Energy Storage Mater. 48 (2022) 212–222. doi: 10.1016/j.ensm.2022.03.024
1. [1]
  Jun Guo , Zhenbang Zhuang , Wanqiang Liu , Gang Huang . "Co-coordination force" assisted rigid-flexible coupling crystalline polymer for high-performance aqueous zinc-organic batteries. Chinese Chemical Letters, 2024, 35(9): 109803-. doi: 10.1016/j.cclet.2024.109803
2. [2]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
3. [3]
  Lingjiang Kou , Yong Wang , Jiajia Song , Taotao Ai , Wenhu Li , Mohammad Yeganeh Ghotbi , Panya Wattanapaphawong , Koji Kajiyoshi . Mini review: Strategies for enhancing stability of high-voltage cathode materials in aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 110368-. doi: 10.1016/j.cclet.2024.110368
4. [4]
  Yunyu Zhao , Chuntao Yang , Yingjian Yu . A review on covalent organic frameworks for rechargeable zinc-ion batteries. Chinese Chemical Letters, 2024, 35(7): 108865-. doi: 10.1016/j.cclet.2023.108865
5. [5]
  Jie Zhou , Quanyu Li , Xiaomeng Hu , Weifeng Wei , Xiaobo Ji , Guichao Kuang , Liangjun Zhou , Libao Chen , Yuejiao Chen . Water molecules regulation for reversible Zn anode in aqueous zinc ion battery: Mini-review. Chinese Chemical Letters, 2024, 35(8): 109143-. doi: 10.1016/j.cclet.2023.109143
6. [6]
  Bin Feng , Tao Long , Ruotong Li , Yuan-Li Ding . Rationally constructing metallic Sn-ZnO heterostructure via in-situ Mn doping for high-rate Na-ion batteries. Chinese Chemical Letters, 2025, 36(2): 110273-. doi: 10.1016/j.cclet.2024.110273
7. [7]
  Yuhuan Meng , Long Zhang , Lequan Wang , Junming Kang , Hongbin Lu . 20 nm-ultra-thin fluorosiloxane interphase layer enables dendrite-free, fast-charging, and flexible aqueous zinc metal batteries. Chinese Chemical Letters, 2024, 35(12): 110025-. doi: 10.1016/j.cclet.2024.110025
8. [8]
  Jingjing Zhang , Lan Ding , Vadim Popkov , Kezhen Qi . Aqueous indium metal batteries. Chinese Chemical Letters, 2025, 36(2): 110407-. doi: 10.1016/j.cclet.2024.110407
9. [9]
  Daheng Wen , Weiwei Fang , Yongmei Liu , Tao Tu . Valorization of carbon dioxide with alcohols. Chinese Chemical Letters, 2024, 35(7): 109394-. doi: 10.1016/j.cclet.2023.109394
10. [10]
  Yan Wang , Huixin Chen , Fuda Yu , Shanyue Wei , Jinhui Song , Qianfeng He , Yiming Xie , Miaoliang Huang , Canzhong Lu . Oxygen self-doping pyrolyzed polyacrylic acid as sulfur host with physical/chemical adsorption dual function for lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(7): 109001-. doi: 10.1016/j.cclet.2023.109001
11. [11]
  Li Lin , Song-Lin Tian , Zhen-Yu Hu , Yu Zhang , Li-Min Chang , Jia-Jun Wang , Wan-Qiang Liu , Qing-Shuang Wang , Fang Wang . Molecular crowding electrolytes for stabilizing Zn metal anode in rechargeable aqueous batteries. Chinese Chemical Letters, 2024, 35(7): 109802-. doi: 10.1016/j.cclet.2024.109802
12. [12]
  Mengjun Sun , Zhi Wang , Jvhui Jiang , Xiaobing Wang , Chuang Yu . Gelation mechanisms of gel polymer electrolytes for zinc-based batteries. Chinese Chemical Letters, 2024, 35(5): 109393-. doi: 10.1016/j.cclet.2023.109393
13. [13]
  Xiaoxing Ji , Xiaojuan Li , Chenggang Wang , Gang Zhao , Hongxia Bu , Xijin Xu . Ni_xB/rGO as the cathode for high-performance aqueous alkaline zinc-based battery. Chinese Chemical Letters, 2024, 35(10): 109388-. doi: 10.1016/j.cclet.2023.109388
14. [14]
  Yuan Dong , Mutian Ma , Zhenyang Jiao , Sheng Han , Likun Xiong , Zhao Deng , Yang Peng . Effect of electrolyte cation-mediated mechanism on electrocatalytic carbon dioxide reduction. Chinese Chemical Letters, 2024, 35(7): 109049-. doi: 10.1016/j.cclet.2023.109049
15. [15]
  Haijing Cui , Weihao Zhu , Chuning Yue , Ming Yang , Wenzhi Ren , Aiguo Wu . Recent progress of ultrasound-responsive titanium dioxide sonosensitizers in cancer treatment. Chinese Chemical Letters, 2024, 35(10): 109727-. doi: 10.1016/j.cclet.2024.109727
16. [16]
  Wei-Jia Wang , Kaihong Chen . Molecular-based porous polymers with precise sites for photoreduction of carbon dioxide. Chinese Chemical Letters, 2025, 36(1): 109998-. doi: 10.1016/j.cclet.2024.109998
17. [17]
  Dong Cheng , Youyou Feng , Bingxi Feng , Ke Wang , Guoxin Song , Gen Wang , Xiaoli Cheng , Yonghui Deng , Jing Wei . Polyphenol-mediated interfacial deposition strategy for supported manganese oxide catalysts with excellent pollutant degradation performance. Chinese Chemical Letters, 2024, 35(5): 108623-. doi: 10.1016/j.cclet.2023.108623
18. [18]
  Yinyin Xu , Yuanyuan Li , Jingbo Feng , Chen Wang , Yan Zhang , Yukun Wang , Xiuwen Cheng . Covalent organic frameworks doped with manganese-metal organic framework for peroxymonosulfate activation. Chinese Chemical Letters, 2024, 35(4): 108838-. doi: 10.1016/j.cclet.2023.108838
19. [19]
  Jiahao Liu , Peng Liu , Junhong Duan , Qiongxuan Xie , Jie Feng , Hongpei Tan , Ze Mi , Ying Li , Yunjie Liao , Pengfei Rong , Wenhu Zhou , Xiang Gao . Macrophages-mediated tumor accumulation and deep penetration of bismuth/manganese biomineralized nanoparticles for enhanced radiotherapy. Chinese Chemical Letters, 2024, 35(12): 109632-. doi: 10.1016/j.cclet.2024.109632
20. [20]
  Linshan Peng , Qihang Peng , Tianxiang Jin , Zhirong Liu , Yong Qian . Highly efficient capture of thorium ion by citric acid-modified chitosan gels from aqueous solution. Chinese Chemical Letters, 2024, 35(5): 108891-. doi: 10.1016/j.cclet.2023.108891

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(141)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142