Citation: Zhaohong Chen, Mengzhen Li, Jinfei Lan, Shengqian Hu, Xiaogang Chen. Organic ferroelastic enantiomers with high T_c and large dielectric switching ratio triggered by order-disorder and displacive phase transition[J]. Chinese Chemical Letters, ;2024, 35(10): 109548. doi: 10.1016/j.cclet.2024.109548 shu

Organic ferroelastic enantiomers with high T_c and large dielectric switching ratio triggered by order-disorder and displacive phase transition

Ordered Matter Science Research Center, Nanchang University, Nanchang 330031, China

chenxg@ncu.edu.cn

Received Date: 7 July 2023
Revised Date: 12 January 2024
Accepted Date: 19 January 2024
Available Online: 23 January 2024

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Molecular-based ferroelastics with dielectric switching properties are highly desirable for their applications on microelectronic dielectric switches, sensors, data storage, and so on. However, the current reports mostly focus on organic-inorganic hybrids containing toxic heavy metal atoms, and the relatively low phase transition temperature limits their application. In this paper, low-toxic organic salt ferroelastic enantiomers (R/S)-4-fluoro-1-azabicyclo[3.2.1]octonium chloride [(R/S)-F-321] were designed and synthesized under the introducing chirality strategy. They undergo a 432F422-type ferroelastic phase transition with a high Curie temperature (T_c) of 470 K, simultaneously exhibiting excellent dielectric switching characteristics. In addition to the ordered-disordered movement of cations, the significant displacement of anions is also responsible for such high T_c and large dielectric switching ratios, which is very rare in molecular-based switching materials. This work enriches the development of molecular ferroelastic switching materials and gives inspiration for the exploration of environmentally friendly high T_c organic salt ferroelastics with prominent switching performances.
- Organic salt,
- Enantiomers,
- Ferroelastic,
- Dielectric switching,
- Phase transition
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沈阳化工大学材料科学与工程学院沈阳 110142

Organic ferroelastic enantiomers with high Tc and large dielectric switching ratio triggered by order-disorder and displacive phase transition

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通讯作者: 陈斌, bchen63@163.com

Organic ferroelastic enantiomers with high T_c and large dielectric switching ratio triggered by order-disorder and displacive phase transition