Citation: Ying-Yu Zhang, Jia-Qi Luo, Yan Han, Wan-Ying Zhang, Yi Zhang, Hai-Feng Lu, Da-Wei Fu. Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature[J]. Chinese Chemical Letters, ;2025, 36(1): 109530. doi: 10.1016/j.cclet.2024.109530 shu

Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature

Ying-Yu Zhang ^{a, 1} ,
Jia-Qi Luo ^{a, 1} ,
Yan Han ^a ,
Wan-Ying Zhang ^{a, b} ,
Yi Zhang ^a ,
Hai-Feng Lu ^{a, *,} ,
Da-Wei Fu ^{a, b, *,}

a.
Institute for Science and Applications of Molecular Ferroelectrics, Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua 321004, China
b.
Ordered Matter Science Research Center, Jiangsu Key Laboratory for Science and applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, China

luhaifeng@zjnu.edu.cn

dawei@seu.edu.cn

Received Date: 17 October 2023
Revised Date: 11 December 2023
Accepted Date: 17 January 2024
Available Online: 23 January 2024

Figures(6)

Multiple switchable physical channels within one material or device, encompassing optical, electrical, thermal, and mechanical pathways, can enable multifunctionality in mechanical-thermal-opto-electronic applications. Achieving integrated encryption and enhanced performance in storage and sensing presents a formidable challenge in the synthesis and functionality of new materials. In an effort to overcome the complexities associated with these multiple physical functions, this study investigates the large-size crystal of DPACdCl₄ (DPA = diisopropylammonium), revealing significant features in rare multi-channel switches. This compound demonstrates the ability to switch between "OFF/0" and "ON/1" states in the mechanical-thermal-opto-electronic channels. Consequently, DPACdCl₄ possesses four switchable physical channels, characterized by a higher phase transition temperature of 440.7 K and a competitive piezoelectric coefficient of 46 pC/N. Furthermore, solid-state NMR analysis indicates that thermally activated molecular vibrations significantly contribute to its multifunctional switching capabilities.
- Organic-inorganic hybrid,
- Phase transition,
- Crystal,
- Perovskite,
- Piezoelectricity
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Bistable switch molecule DPACdCl4 showing four physical channels and high phase transition temperature

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通讯作者: 陈斌, bchen63@163.com

Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature