Citation: Maosen Xu, Pengfei Zhu, Qinghong Cai, Meichun Bu, Chenghua Zhang, Hong Wu, Youzhou He, Min Fu, Siqi Li, Xingyan Liu. In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity[J]. Chinese Chemical Letters, ;2024, 35(10): 109524. doi: 10.1016/j.cclet.2024.109524 shu

In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity

Maosen Xu ^a ,
Pengfei Zhu ^a ,
Qinghong Cai ^a ,
Meichun Bu ^a ,
Chenghua Zhang ^{b, *,} ,
Hong Wu ^a ,
Youzhou He ^{a, *,} ,
Min Fu ^a ,
Siqi Li ^c ,
Xingyan Liu ^{a, *,}

a.
Chongqing Key Laboratory of Catalysis and New Environmental Materials, College of Environment and Resources, Chongqing Technology and Business University, Chongqing 400067, China
b.
School of Pharmacy, North Sichuan Medical College, Nanchong 637100, China
c.
State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China

zchua@nsmc.edu.cn

yzhectbu@163.com

xyliuctbu@126.com

Received Date: 28 September 2023
Revised Date: 28 December 2023
Accepted Date: 14 January 2024
Available Online: 18 January 2024

Figures(5)

Deep oxidation of NO molecules to nitrate species by photocatalysis with virtually no toxic byproduct NO₂ generation is a challenging task. In this study, TiO₂ in-situ grows based on NH₂−MIL-125(Ti) (NM-125) not only inhibited TiO₂ agglomeration, but also contacted more tightly to obtain efficient interfacial effects, thus displaying excellent photocatalytic NO removal activity (68.08%). The formation of TiO₂ is directly confirmed by characterizations such as X-ray diffraction (XRD), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS). Meanwhile, UV–vis, photoluminescence, and photoelectrochemical analysis indicate that TiO₂ formation effectively improves the optical properties. Moreover, the strong electron interaction and electron transport direction between NM-125 and TiO₂ are investigated by density functional theoretical (DFT) calculation. Finally, combined with the results of electron spin resonance (ESR) and in-situ FT-IR test, the intermediate processes of NO adsorption and photocatalytic oxidation reaction are discussed in depth, where the production of reactive oxygen species (ROS) under light is the key factor in the successful degradation of NO. Compared with NM-125 which can only produce ^•OH through photogenerated electrons since the lower valence band position, NMT-2 can directly produce ^•OH through photogenerated holes, thereby relieving the pressure on photogenerated electrons and producing more ROS. This study will provide reasonable guidance for the modification of NM-125 for photocatalytic removal of ppb-level NO.
- Photocatalysis,
- NH₂-MIL-125(Ti),
- TiO₂,
- NO removal,
- ROS
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In-situ fabrication of TiO2/NH2−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity

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通讯作者: 陈斌, bchen63@163.com

In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity