Citation: Jia-Cheng Hou, Hong-Tao Ji, Yu-Han Lu, Jia-Sheng Wang, Yao-Dan Xu, Yan-Yan Zeng, Wei-Min He. Sustainable and practical semi-heterogeneous photosynthesis of 5-amino-1,2,4-thiadiazoles over WS₂/TEMPO[J]. Chinese Chemical Letters, ;2024, 35(8): 109514. doi: 10.1016/j.cclet.2024.109514 shu

Sustainable and practical semi-heterogeneous photosynthesis of 5-amino-1,2,4-thiadiazoles over WS₂/TEMPO

School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China

weiminhe@usc.edu.cn

Received Date: 29 November 2023
Revised Date: 28 December 2023
Accepted Date: 4 January 2024
Available Online: 13 January 2024

Figures(7)

An eco-friendly and practical method for the clean preparation of 5-amino-1,2,4-thiadiazoles was developed. With WS₂ as the semiconductor photocatalyst, both TEMPO and O₂ (in air) as the redox catalysts, a variety of thiadiazoles were semi-heterogeneously formed in high to quantitative yields and could be easily collected by CPME extraction and rinsing. Furthermore, the catalytic system can be reusable for at least 5 reaction runs.
- Green chemistry,
- Thiadiazoles,
- Heterogeneous catalyst,
- Redox catalyst,
- Extraction
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Sustainable and practical semi-heterogeneous photosynthesis of 5-amino-1,2,4-thiadiazoles over WS2/TEMPO

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通讯作者: 陈斌, bchen63@163.com

Sustainable and practical semi-heterogeneous photosynthesis of 5-amino-1,2,4-thiadiazoles over WS₂/TEMPO