Citation: Yihong Li, Zhong Qiu, Lei Huang, Shenghui Shen, Ping Liu, Haomiao Zhang, Feng Cao, Xinping He, Jun Zhang, Yang Xia, Xinqi Liang, Chen Wang, Wangjun Wan, Yongqi Zhang, Minghua Chen, Wenkui Zhang, Hui Huang, Yongping Gan, Xinhui Xia. Plasma enhanced reduction method for synthesis of reduced graphene oxide fiber/Si anode with improved performance[J]. Chinese Chemical Letters, ;2024, 35(11): 109510. doi: 10.1016/j.cclet.2024.109510 shu

Plasma enhanced reduction method for synthesis of reduced graphene oxide fiber/Si anode with improved performance

Yihong Li ^{a, b} ,
Zhong Qiu ^{a, b} ,
Lei Huang ^{a, b} ,
Shenghui Shen ^c ,
Ping Liu ^{a, b} ,
Haomiao Zhang ^a ,
Feng Cao ^d ,
Xinping He ^{b, *,} ,
Jun Zhang ^b ,
Yang Xia ^b ,
Xinqi Liang ^{e, f} ,
Chen Wang ^g ,
Wangjun Wan ^g ,
Yongqi Zhang ^{e, *,} ,
Minghua Chen ^f ,
Wenkui Zhang ^b ,
Hui Huang ^b ,
Yongping Gan ^b ,
Xinhui Xia ^{a, b, h, *,}

a.
School of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China
b.
College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, China
c.
School of Materials Science and & Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China
d.
Department of Engineering Technology, Huzhou College, Huzhou 313000, China
e.
Institute of Fundamental and Frontier Science, University of Electronic Science and Technology of China, Chengdu 611371, China
f.
Key Laboratory of Engineering Dielectric and Applications (Ministry of Education), School of Electrical and Electronic Engineering, Harbin University of Science and Technology, Harbin 150080, China
g.
Zhejiang Academy of Science and Technology for Inspection & Quarantine, Hangzhou 311215, China
h.
State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou 350116, China

xinpinghe@zjut.edu.cn

yqzhang@uestc.edu.cn

helloxxh@zju.edu.cn

Received Date: 8 October 2023
Revised Date: 3 January 2024
Accepted Date: 11 January 2024
Available Online: 15 January 2024

Figures(6)

Silicon (Si) is considered as one of the most promising anode materials for advanced lithium-ion batteries due to its high theoretical capacity, environmental friendliness, and widespread availability. However, great challenges such as volumetric expansion, limited ionic/electronic conductivity properties and complex manufacturing processes hinder its practical applications. Herein, a novel plasma-enhanced reduced graphene oxide fibers/Si (PrGOFs/Si) composite anode is first proposed by using wet-spinning technology followed by plasma-enhanced reduction method. The PrGOFs provide large space to accommodate the volume expansion of Si nanoparticles (SiNPs) by forming a flexible 3D conductive network. Compared to the conventional thermally reduced graphene oxide fibers/Si (TrGOFs/Si) sample, the PrGOFs/Si anodes demonstrate higher conductivity, specific surface area, and superior fabrication efficiency. Accordingly, the PrGOFs/Si anodes exhibit a reversible capacity of 698.3 mAh/g, and maintain a specific capacity of 602.5 mAh/g at a current density of 200 mA/g after 100 cycles, superior to conventional TrGOFs/Si counterparts. This research presents a novel strategy for the preparation of high-performance Si/carbon anodes for energy storage applications.
- Li ion batteries,
- Si anode,
- Plasma,
- Graphene fibers,
- Carbon
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