Citation: Xiaotao Jin, Yanlan Wang, Yingping Huang, Di Huang, Xiang Liu. Percarbonate activation catalyzed by nanoblocks of basic copper molybdate for antibiotics degradation: High performance, degradation pathways and mechanism[J]. Chinese Chemical Letters, ;2024, 35(10): 109499. doi: 10.1016/j.cclet.2024.109499 shu

Percarbonate activation catalyzed by nanoblocks of basic copper molybdate for antibiotics degradation: High performance, degradation pathways and mechanism

Xiaotao Jin ^a ,
Yanlan Wang ^b ,
Yingping Huang ^a ,
Di Huang ^{a, *,} ,
Xiang Liu ^{a, *,}

a.
Engineering Research Center of Eco-Environment in Three Gorges Reservoir Region of Ministry of Education, College of Materials and Chemical Engineering, China Three Gorges University, Yichang 443002, China
b.
Department of chemistry and chemical engineering, Liaocheng University, Liaocheng 252059, China

huangd94@iccas.ac.cn

xiang.liu@ctgu.edu.cn

Received Date: 27 September 2023
Revised Date: 13 December 2023
Accepted Date: 2 January 2024
Available Online: 10 January 2024

Figures(4)

Sodium percarbonate (Na₂CO₃·1.5H₂O₂, SPC) has been extensively employed as a solid substitute of H₂O₂ for Fenton process in water treatment, because of its high stability during the production, transport, storage and usage. In addition, SPC can be applied in a wider range of work pH, it is also applied as a buffer in Fenton reaction for preventing a drop in pH. Herein, we have synthesized basic copper molybdate (BCM) nanoblocks with the molecular formula of Cu₃(MoO₄)₂(OH)₂ as an efficient and heterogeneous catalyst for antibiotics degradation via percarbonate activation. First, fully physical characterizations confirmed BCM nanocomposite exhibited a structure of nanoblocks. We also found that BCM/SPC system could work in a much wider pH range, compared with H₂O₂. Then, BCM/SPC system presented a good anti-interference ability for natural organic matter in OTC degradation. EPR results and Quenching tests confirmed that the co-presence of ^·CO₃⁻, ^·O₂⁻, ¹O₂ and ^·OH in BCM/SPC system.
- Sodium percarbonate,
- Fenton process,
- Water treatment,
- Copper molybdate,
- Nanoblocks
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