Citation: Peng Zhou, Ziang Jiang, Yang Li, Peng Xiao, Feixiang Wu. Sulphur-template method for facile manufacturing porous silicon electrodes with enhanced electrochemical performance[J]. Chinese Chemical Letters, ;2024, 35(8): 109467. doi: 10.1016/j.cclet.2023.109467 shu

Sulphur-template method for facile manufacturing porous silicon electrodes with enhanced electrochemical performance

Powder Metallurgy Research Institute, School of Metallurgy and Environment, Central South University, Changsha 410083, China

xiaopeng@csu.edu.cn

feixiang.wu@csu.edu.cn

Received Date: 27 November 2023
Revised Date: 12 December 2023
Accepted Date: 26 December 2023
Available Online: 5 January 2024

Figures(4)

Sulphur (S)-template method based on conventional slurry-casting method has been developed to produce porous silicon (Si) electrodes. The facile fabrication technology is suitable for current production line and expected to be widely applied to various electrode materials under large volume change during operation. Specifically, S particles as template agent are mixed with active material Si, carbon conductor and binder forming uniform slurry. After casting and drying, the electrodes are immersed in carbon disulfide solution to remove S particles rapidly, generating pores in-situ at the original position of S particles. Electrochemical analysis shows that the pores inside electrodes are able to shorten lithium ion diffusion paths, reduce normal expansion rate and decrease formation of cracks in the Si electrode (2 mg_Si/cm²), demonstrating a reversible capacity of 951 mAh/g at 0.5 A/g after 100 cycles (with a capacity retention of 99.5%) and a capacity of ~826 mAh/g at 2 A/g.
- Sulphur-template,
- Porous electrodes,
- Silicon anodes,
- Low volume expansion,
- Lithium-ion batteries
1. [1]
  M. Armand, J.M. Tarascon, Nature 451 (2008) 652–657. doi: 10.1038/451652a
2. [2]
  D. Chao, B. Ouyang, P. Liang, et al., Adv. Mater. 30 (2018) 1804833. doi: 10.1002/adma.201804833
3. [3]
  J.W. Choi, D. Aurbach, Nat. Rev. Mater. 1 (2016) 16013. doi: 10.1038/natrevmats.2016.13
4. [4]
  D. Li, F. Chu, Z. He, et al., Mater. Today 58 (2022) 80–90. doi: 10.1016/j.mattod.2022.07.004
5. [5]
  G.K. Sung, C.M. Park, J. Mater. Chem. A 5 (2017) 5685–5689. doi: 10.1039/C7TA00358G
6. [6]
  B. Wang, J. Ryu, S. Choi, et al., ACS Nano 13 (2019) 2307–2315.
7. [7]
  D. Zhang, J. Lu, C. Pei, et al., Adv. Energy Mater. 12 (2022) 2103689. doi: 10.1002/aenm.202103689
8. [8]
  Q. Man, Y. An, C. Liu, et al., J. Energy Chem. 76 (2023) 576–600. doi: 10.1016/j.jechem.2022.09.020
9. [9]
  D. Chao, X. Xia, J. Liu, et al., Adv. Mater. 26 (2014) 5794–5800. doi: 10.1002/adma.201400719
10. [10]
  Z. Yao, X. Xia, C.A. Zhou, et al., Adv. Sci. 5 (2018) 1700786. doi: 10.1002/advs.201700786
11. [11]
  R. Mo, D. Rooney, K. Sun, et al., Nat. Commun. 8 (2017) 13949. doi: 10.1038/ncomms13949
12. [12]
  X. Shi, Y. Gan, Q. Zhang, et al., Adv. Mater. 33 (2021) 2100837. doi: 10.1002/adma.202100837
13. [13]
  J. Ji, H. Ji, L.L. Zhang, et al., Adv. Mater. 25 (2013) 4673–4677. doi: 10.1002/adma.201301530
14. [14]
  H. Shang, Z. Zuo, L. Yu, et al., Adv. Mater. 30 (2018) 1801459. doi: 10.1002/adma.201801459
15. [15]
  L. Liu, B. Wu, J. Tao, et al., Adv. Compos. Hybrid Mater. 5 (2022) 3002–3011. doi: 10.1007/s42114-022-00528-w
16. [16]
  J. Tao, L. Liu, J. Han, et al., Energy Storage Mater. 60 (2023) 102809. doi: 10.1016/j.ensm.2023.102809
17. [17]
  K. Chansoon, C.Y. Whan, J. Power Sources 485 (2021) 229311. doi: 10.1016/j.jpowsour.2020.229311
18. [18]
  N. Qin, L. Jin, G. Xing, et al., Adv. Energy Mater. 13 (2023) 2204077. doi: 10.1002/aenm.202204077
19. [19]
  Y.T. Malik, S.Y. Shin, J.I. Jang, et al., Small 19 (2023) 2206141. doi: 10.1002/smll.202206141
20. [20]
  Y. Son, S. Sim, H. Ma, et al., Adv. Mater. 30 (2018) 1705.
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2. [2]
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4. [4]
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11. [11]
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12. [12]
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13. [13]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
14. [14]
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15. [15]
  Yuanzhe Lu , Yuanqin Zhu , Linfeng Zhong , Dingshan Yu . Long-lifespan aqueous alkaline and acidic batteries enabled by redox conjugated covalent organic polymer anodes. Chinese Journal of Structural Chemistry, 2024, 43(3): 100249-100249. doi: 10.1016/j.cjsc.2024.100249
16. [16]
  Ying Li , Yanjun Xu , Xingqi Han , Di Han , Xuesong Wu , Xinlong Wang , Zhongmin Su . A new metal–organic rotaxane framework for enhanced ion conductivity of solid-state electrolyte in lithium-metal batteries. Chinese Chemical Letters, 2024, 35(9): 109189-. doi: 10.1016/j.cclet.2023.109189
17. [17]
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18. [18]
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19. [19]
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20. [20]
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沈阳化工大学材料科学与工程学院沈阳 110142