Citation: Hui Peng, Xiao Wang, Weiguo Huang, Shuiyue Yu, Linghang Kong, Qilin Wei, Jialong Zhao, Bingsuo Zou. Efficient tunable visible and near-infrared emission in Sb³⁺/Sm³⁺-codoped Cs₂NaLuCl₆ for near-infrared light-emitting diode, triple-mode fluorescence anti-counterfeiting and information encryption[J]. Chinese Chemical Letters, ;2024, 35(11): 109462. doi: 10.1016/j.cclet.2023.109462 shu

Efficient tunable visible and near-infrared emission in Sb³⁺/Sm³⁺-codoped Cs₂NaLuCl₆ for near-infrared light-emitting diode, triple-mode fluorescence anti-counterfeiting and information encryption

Hui Peng ^{a, *,} ,
Xiao Wang ^a ,
Weiguo Huang ^a ,
Shuiyue Yu ^a ,
Linghang Kong ^a ,
Qilin Wei ^{b, *,} ,
Jialong Zhao ^a ,
Bingsuo Zou ^{a, *,}

a.
State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures, MOE Key Laboratory of New Processing Technology for Nonferrous Metals and Materials, and School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China
b.
School of Chemistry and Chemical Engineering, Shandong University, Ji'nan 250100, China

penghuimaterial@163.com

qlwei@sdu.edu.cn

zoubs@gxu.edu.cn

Received Date: 2 December 2023
Revised Date: 19 December 2023
Accepted Date: 26 December 2023
Available Online: 6 January 2024

Figures(5)

Rare earth ions (RE³⁺)-doped double perovskites have attracted tremendous attention for its fascinating optical properties. Nevertheless, RE³⁺ generally exhibits poor photoluminescence quantum yield (PLQY) for their parity-forbidden 4f-4f transition and the low doping concentration. Herein, we reported Sb³⁺/Sm³⁺-codoped rare earth-based double perovskite Cs₂NaLuCl₆ that enables efficient visible and near-infrared (NIR) emission, which stems from self-trapped exciton (STE) and Sm³⁺, respectively. Benefit from up to 72.89% energy transfer efficiency from STE to Sm³⁺ and high doping concentrations due to similar ionic activity between Sm³⁺ and Lu³⁺, thus eruptive PLQY of 74.58% in the visible light region and 23.12% in the NIR light region can be obtained. Moreover, Sb³⁺/Sm³⁺-codoped Cs₂NaLuCl₆ exhibits tunable emission characteristic in the visible light region under different excitation wavelengths, which can change from blue emission (254 nm excitation) to white emission (365 nm excitation). More particularly, only the NIR emission can be captured by the NIR camera when a 700 nm cutoff filter is added. The excellent stability and unique optical properties of Sb³⁺/Sm³⁺-codoped Cs₂NaLuCl₆ enable us to demonstrate its applications in NIR light-emitting diode, triple-mode fluorescence anti-counterfeiting and information encryption. These findings provide new inspiration for the application of rare earth-based double perovskite in optoelectronic devices.
- Rare earth-based double perovskites,
- Self-trapped exciton,
- Near-infrared emission,
- Energy transfer,
- Multifunctional applications
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Efficient tunable visible and near-infrared emission in Sb3+/Sm3+-codoped Cs2NaLuCl6 for near-infrared light-emitting diode, triple-mode fluorescence anti-counterfeiting and information encryption

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通讯作者: 陈斌, bchen63@163.com

Efficient tunable visible and near-infrared emission in Sb³⁺/Sm³⁺-codoped Cs₂NaLuCl₆ for near-infrared light-emitting diode, triple-mode fluorescence anti-counterfeiting and information encryption