Citation: Yu Mao, Yilin Liu, Xiaochen Wang, Shengyang Ni, Yi Pan, Yi Wang. Acylfluorination of enynes via phosphine and silver catalysis[J]. Chinese Chemical Letters, ;2024, 35(8): 109443. doi: 10.1016/j.cclet.2023.109443 shu

Acylfluorination of enynes via phosphine and silver catalysis

State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

yiwang@nju.edu.cn

Received Date: 30 August 2023
Revised Date: 11 December 2023
Accepted Date: 20 December 2023
Available Online: 23 December 2023

Figures(4)

This work describes intermolecular acylfluorination of gem-difluoroenynes using acyl fluorides as both acyl source and fluorine source. Trifluoromethyl-substituted allenones or furans could be selectively achieved via phosphine and silver catalysis. These approaches exhibit high regioselectivity, atom economy and broad functionality tolerance.
- Phosphine catalysis,
- Silver catalysis,
- Difunctionalization,
- Allenone,
- Furan,
- Trifluoromethyl
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