Citation: Dongmei Dai, Xiaobing Lai, Xiaojuan Wang, Yunting Yao, Mengmin Jia, Liang Wang, Pengyao Yan, Yaru Qiao, Zhuangzhuang Zhang, Bao Li, Dai-Huo Liu. Increasing (010) active plane of P2-type layered cathodes with hexagonal prism towards improved sodium-storage[J]. Chinese Chemical Letters, ;2024, 35(10): 109405. doi: 10.1016/j.cclet.2023.109405 shu

Increasing (010) active plane of P2-type layered cathodes with hexagonal prism towards improved sodium-storage

Dongmei Dai ^{a, 1} ,
Xiaobing Lai ^{a, 1} ,
Xiaojuan Wang ^a ,
Yunting Yao ^a ,
Mengmin Jia ^a ,
Liang Wang ^a ,
Pengyao Yan ^a ,
Yaru Qiao ^a ,
Zhuangzhuang Zhang ^{a, *,} ,
Bao Li ^{a, b, *,} ,
Dai-Huo Liu ^{a, *,}

a.
Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions (Ministry of Education), School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China
b.
CAS Henan Industrial Technology Innovation & Incubation Center, Zhengzhou 450016, China

zhangzhuangzhuang@htu.edu.cn

libao@htu.edu.cn

liudaihuo@htu.edu.cn

Received Date: 25 October 2023
Revised Date: 6 December 2023
Accepted Date: 11 December 2023
Available Online: 22 December 2023

Figures(5)

Na-ion cathode materials with a fast charge and discharge behavior are needed to develop future high-energy sodium-ion batteries (SIBs). However, inevitably complicated phase transitions and sluggish kinetics during insertion and removal of Na⁺ in P2-type layered transition metal oxides generate structural instability and severe capacity decay. To get rid of such a dilemma, we report a structural optimization strategy to promote P2-type layered transition metal oxides with more (010) active planes as an efficient cathode for SIBs. As a result, as-prepared hexagonal-prism P2-type layered Na_0.71Ni_0.16Li_0.09Co_0.16Mn_0.6O₂ cathode with more (010) active planes delivers a reversible capacity of 120.1 mAh/g at 0.1 C, impressive rate capability of 52.7 mAh/g at 10 C, and long-term cycling stability (capacity retention of 95.6% over 200 cycles). The outstanding electrochemical performance benefited from the unique hexagonal-prism with more (010) active facets, which can effectively shorten the diffusion distances of Na⁺, increase the Na-ion migration dynamics and nanostructural stability during cycling verified by morphology characterization, Rietveld refinement, GITT, density functional theory calculations and operando XRD.
- Layered cathodes,
- Hexagonal-prism shape,
- P2-type structure,
- Sodium ion batteries,
- Enhanced diffusion kinetics
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