Citation: Gregorio F. Ortiz. Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery[J]. Chinese Chemical Letters, ;2024, 35(10): 109391. doi: 10.1016/j.cclet.2023.109391 shu

Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery

Gregorio F. Ortiz

Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China

gregorio.ortiz@hqu.edu.cn

Received Date: 25 September 2023
Revised Date: 16 November 2023
Accepted Date: 4 December 2023
Available Online: 12 December 2023

Figures(7)

Magnesium rechargeable batteries (MRBs) present opportunities for grid-scale energy storage applications as a complement to Li-ion batteries (LIBS). The major challenges are the low reversible capacity, inferior cycling stability and unsatisfactory energy densities. Na₃VCr_0.5Fe_0.5(PO₄)₃ with a well-defined NASION-type structure is used as cathode in Mg cell. Two-electrons reaction (~116 mAh/g), 1.5 V average voltage and 65% of capacity retention over 100 cycles are accomplished. Mg is inserted by a biphasic reaction with the participation of V³⁺/V⁴⁺/V⁵⁺ redox couples in the electrochemical reaction while the non-active redox couples such as Cr³⁺/Cr⁴⁺ and Fe²⁺/Fe³⁺ served as stabilizer to buffer the volume variation. A thermal stability up to ~412 ℃ is also exhibited. Therefore, incorporating a mixture of three transition metal (V/Cr/Fe) in this type of structures will broaden new perspectives for realizing high performance cathodes for MRBs.
- Multi-electron reaction,
- Mg batteries,
- NASICON,
- Na₃VCr_0.5Fe_0.5(PO₄)₃,
- Iron and chromium doping
1. [1]
  D. Aurbach, Z. Lu, A. Schechter, et al., Nature 407 (2000) 724. doi: 10.1038/35037553
2. [2]
  M. Zhang, S. Feng, Y. Wu, Y. Li, Acta Phys. Chim. Sin. 39 (2023) 2205050.
3. [3]
  D. Imamura, M. Miyayama, M. Hibino, T. Kudo, J. Electrochem. Soc. 150 (2003) A753. doi: 10.1149/1.1571531
4. [4]
  R. Zhang, X. Yu, K.W. Nam, et al., Electrochem. Commun. 23 (2012) 110. doi: 10.1016/j.elecom.2012.07.021
5. [5]
  C. Yuan, Y. Zhang, Y. Pan, et al., Electrochim. Acta 116 (2014) 404. doi: 10.1016/j.electacta.2013.11.090
6. [6]
  L. Wang, Z.H. Wang, P.E. Vullum, et al., Nano Lett. 18 (2018) 763. doi: 10.1021/acs.nanolett.7b03978
7. [7]
  Y.L. Liang, H.D. Yoo, Y.F. Li, et al., Nano Lett. 15 (2015) 2194. doi: 10.1021/acs.nanolett.5b00388
8. [8]
  B. Liu, T. Luo, G. Mu, et al., ACS Nano 7 (2013) 8051. doi: 10.1021/nn4032454
9. [9]
  H.D. Yoo, Y.L. Liang, H. Dong, et al., Nat. Commun. 8 (2017) 339. doi: 10.1038/s41467-017-00431-9
10. [10]
  X.Q. Sun, P. Bonnick, L.F. Nazar, ACS Energy Lett. 1 (2016) 297. doi: 10.1021/acsenergylett.6b00145
11. [11]
  R. Yokozaki, H. Kobayashi, I. Honma, Ceram. Int. 47 (2021) 10236–10241. doi: 10.1016/j.ceramint.2020.10.184
12. [12]
  N. Kitamura, T. Imura, N. Ishida, C. Ishibashi, Y. Idemoto, ACS Omega 7 (2022) 46915–46921. doi: 10.1021/acsomega.2c06633
13. [13]
  R. Ruiz, C. Pérez-Vicente, S. Rubio, et al., Energy Storage Mater. 48 (2022) 12–19. doi: 10.1016/j.ensm.2022.02.047
14. [14]
  Y. Wang, Z. Liu, C. Wang, et al., Adv. Mater. 30 (2018) 1802563. doi: 10.1002/adma.201802563
15. [15]
  S. Rubio, Z. Liang, Y. Li, et al., Electrochim. Acta 404 (2022) 139738. doi: 10.1016/j.electacta.2021.139738
16. [16]
  C. Pérez-Vicente, S. Rubio, R. Ruiz, et al., Small 19 (2023) 2206010. doi: 10.1002/smll.202206010
17. [17]
  Y. Li, Q. An, Y. Cheng, et al., Nano Energy 34 (2017) 188. doi: 10.1016/j.nanoen.2017.02.012
18. [18]
  M. Cabello, R. Alcántara, F. Nacimiento, et al., Electrochim. Acta 246 (2017) 908–913. doi: 10.1016/j.electacta.2017.06.080
19. [19]
  Y. Fei, Y. Man, J. Sun, et al., Small 19 (2023) 2301954. doi: 10.1002/smll.202301954
20. [20]
  Y. Man, P. Jaumaux, Y. Xu, et al., Sci. Bull. 68 (2023) 1819–1842. doi: 10.1016/j.scib.2023.07.027
21. [21]
  S. Rubio, R. Liu, X. Liu, et al., J. Mater. Chem. A 7 (2019) 18081–18091. doi: 10.1039/C9TA05608D
22. [22]
  Z. Jian, W. Han, X. Lu, et al., Adv. Energy Mater. 3 (2013) 156–160. doi: 10.1002/aenm.201200558
23. [23]
  R. Liu, H. Liu, T. Sheng, et al., ACS Appl. Energy Mater. 1 (2018) 3603–3606. doi: 10.1021/acsaem.8b00889
24. [24]
  X. Liu, G. Feng, E. Wang, et al., ACS Appl. Mater. Interfaces 11 (2019) 12421–12430. doi: 10.1021/acsami.8b21257
25. [25]
  H. Li, Y. Wang, X. Zhao, et al., ACS Energy Lett. 8 (2023) 3666–3675. doi: 10.1021/acsenergylett.3c01183
26. [26]
  S. Rubio, Z. Liang, X. Liu, et al., Energy Storage Mater. 38 (2021) 462–472. doi: 10.1016/j.ensm.2021.03.035
27. [27]
  F. Lalere, J.B. Leriche, M. Courty, et al., J. Power Sources 247 (2014) 975–980. doi: 10.1016/j.jpowsour.2013.09.051
28. [28]
  R. Liu, G. Xu, Q. Li, et al., ACS Appl. Mater. Interfaces 9 (2017) 43632. doi: 10.1021/acsami.7b13018
29. [29]
  R.D. Shannon, Acta Crystal. A32 (1976) 751–767. doi: 10.1107/S0567739476001551
30. [30]
  A. Sadezky, H. Muckenhuber, H. Grothe, R. Niessner, U. Pöschl, Carbon 43 (2005) 1731–1742. doi: 10.1016/j.carbon.2005.02.018
31. [31]
  A. Criado, P. Lavela, C. Pérez-Vicente, G.F. Ortiz, J.L. Tirado, J. Electroanal. Chem. 856 (2020) 113694. doi: 10.1016/j.jelechem.2019.113694
32. [32]
  Z.D. Huang, T. Masese, Y. Orikasa, T. Mori, K. Yamamoto, RSC Adv. 5 (2015) 8598. doi: 10.1039/C4RA14416C
33. [33]
  L.M. Zhou, Q. Liu, Z.H. Zhang, et al., Adv. Mater. 30 (2018) 1801984. doi: 10.1002/adma.201801984
34. [34]
  J. Zeng, Y. Yang, S.B. Lai, et al., Chem. Eur. J. 23 (2017) 16898–16905. doi: 10.1002/chem.201704303
35. [35]
  J.J. Wang, S.S. Tan, G.B. Zhang, et al., Sci. China Mater. 63 (2020) 1651–1662. doi: 10.1007/s40843-020-1311-1
36. [36]
  R. Liu, S. Zheng, Y. Yuan, et al., Adv. Energy Mater. 11 (2021) 2003256. doi: 10.1002/aenm.202003256
37. [37]
  D. Park, Y.S. Yun, J.M. Park, J. Colloid Interface Sci. 317 (2008) 54. doi: 10.1016/j.jcis.2007.09.049
38. [38]
  D. Dwibedi, R. Gond, P. Barpanda, Chem. Mater. 31 (2019) 7501–7509. doi: 10.1021/acs.chemmater.9b02220
39. [39]
  M.J. Aragón, P. Lavela, G.F. Ortiz, J.L. Tirado, J. Electrochem. Soc. 162 (2015) A3077. doi: 10.1149/2.0151502jes
40. [40]
  T. Broux, T. Bamine, L. Simonelli, et al., J. Phys. Chem. C 121 (2017) 4103–4111.
41. [41]
  H. Li, M. Xu, C. Gao, et al., Energy Storage Mater. 6 (2020) 325–333.
42. [42]
  W. Zhang, Y. Wu, Z. Xu, et al., Adv. Energy Mater. 12 (2022) 2201065. doi: 10.1002/aenm.202201065
43. [43]
  R.R. Samigullin, O.A. Drozhzhin, E.V. Antipov, ACS Appl. Energy Mater. 5 (2022) 14–19. doi: 10.1021/acsaem.1c03151
44. [44]
  R.R. Samigullin, M.V. Zakharkin, O.A. Drozhzhin, E.V. Antipov, Energies 16 (2023) 3051. doi: 10.3390/en16073051
1. [1]
  Lumin Zheng , Ying Bai , Chuan Wu . Multi-electron reaction and fast Al ion diffusion of δ-MnO₂ cathode materials in rechargeable aluminum batteries via first-principle calculations. Chinese Chemical Letters, 2024, 35(4): 108589-. doi: 10.1016/j.cclet.2023.108589
2. [2]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
3. [3]
  Shunshun Jiang , Ji Zhang , Jing Wang , Shan-Tao Zhang . Excellent energy storage properties in non-stoichiometric Bi_0.5Na_0.5TiO₃-based relaxor ferroelectric ceramics. Chinese Chemical Letters, 2024, 35(7): 108955-. doi: 10.1016/j.cclet.2023.108955
4. [4]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
5. [5]
  Fanjun Kong , Yixin Ge , Shi Tao , Zhengqiu Yuan , Chen Lu , Zhida Han , Lianghao Yu , Bin Qian . Engineering and understanding SnS_0.5Se_0.5@N/S/Se triple-doped carbon nanofibers for enhanced sodium-ion batteries. Chinese Chemical Letters, 2024, 35(4): 108552-. doi: 10.1016/j.cclet.2023.108552
6. [6]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
7. [7]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
8. [8]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
9. [9]
  Zizhuo Liang , Fuming Du , Ning Zhao , Xiangxin Guo . Revealing the reason for the unsuccessful fabrication of Li3Zr2Si2PO12 by solid state reaction. Chinese Journal of Structural Chemistry, 2023, 42(11): 100108-100108. doi: 10.1016/j.cjsc.2023.100108
10. [10]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
11. [11]
  Kebo Xie , Qian Zhang , Fei Ye , Jungui Dai . A multi-enzymatic cascade reaction for the synthesis of bioactive C-oligosaccharides. Chinese Chemical Letters, 2024, 35(6): 109028-. doi: 10.1016/j.cclet.2023.109028
12. [12]
  Yan Wang , Huixin Chen , Fuda Yu , Shanyue Wei , Jinhui Song , Qianfeng He , Yiming Xie , Miaoliang Huang , Canzhong Lu . Oxygen self-doping pyrolyzed polyacrylic acid as sulfur host with physical/chemical adsorption dual function for lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(7): 109001-. doi: 10.1016/j.cclet.2023.109001
13. [13]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
14. [14]
  Tingting Huang , Zhuanlong Ding , Hao Liu , Ping-An Chen , Longfeng Zhao , Yuanyuan Hu , Yifan Yao , Kun Yang , Zebing Zeng . Electron-transporting boron-doped polycyclic aromatic hydrocarbons: Facile synthesis and heteroatom doping positions-modulated optoelectronic properties. Chinese Chemical Letters, 2024, 35(4): 109117-. doi: 10.1016/j.cclet.2023.109117
15. [15]
  Yongjing Deng , Feiyang Li , Zijian Zhou , Mengzhu Wang , Yongkang Zhu , Jianwei Zhao , Shujuan Liu , Qiang Zhao . Chiral induction and Sb³⁺ doping in indium halides to trigger second harmonic generation and circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(8): 109085-. doi: 10.1016/j.cclet.2023.109085
16. [16]
  Ya Song , Mingxia Zhou , Zhu Chen , Huali Nie , Jiao-Jing Shao , Guangmin Zhou . Integrated interconnected porous and lamellar structures realized fast ion/electron conductivity in high-performance lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(6): 109200-. doi: 10.1016/j.cclet.2023.109200
17. [17]
  Yi Liu , Peng Lei , Yang Feng , Shiwei Fu , Xiaoqing Liu , Siqi Zhang , Bin Tu , Chen Chen , Yifan Li , Lei Wang , Qing-Dao Zeng . Topologically engineering of π-conjugated macrocycles: Tunable emission and photochemical reaction toward multi-cyclic polymers. Chinese Chemical Letters, 2024, 35(10): 109571-. doi: 10.1016/j.cclet.2024.109571
18. [18]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
19. [19]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
20. [20]
  Peng Wang , Daijie Deng , Suqin Wu , Li Xu . Cobalt-based deep eutectic solvent modified nitrogen-doped carbon catalyst for boosting oxygen reduction reaction in zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100199-100199. doi: 10.1016/j.cjsc.2023.100199

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(126)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Some facets of the Mg/Na3VCr0.5Fe0.5(PO4)3 battery

Metrics

通讯作者: 陈斌, bchen63@163.com

Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery