Citation: Gregorio F. Ortiz. Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery[J]. Chinese Chemical Letters, ;2024, 35(10): 109391. doi: 10.1016/j.cclet.2023.109391 shu

Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery

Gregorio F. Ortiz

Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China

gregorio.ortiz@hqu.edu.cn

Received Date: 25 September 2023
Revised Date: 16 November 2023
Accepted Date: 4 December 2023
Available Online: 12 December 2023

Figures(7)

Magnesium rechargeable batteries (MRBs) present opportunities for grid-scale energy storage applications as a complement to Li-ion batteries (LIBS). The major challenges are the low reversible capacity, inferior cycling stability and unsatisfactory energy densities. Na₃VCr_0.5Fe_0.5(PO₄)₃ with a well-defined NASION-type structure is used as cathode in Mg cell. Two-electrons reaction (~116 mAh/g), 1.5 V average voltage and 65% of capacity retention over 100 cycles are accomplished. Mg is inserted by a biphasic reaction with the participation of V³⁺/V⁴⁺/V⁵⁺ redox couples in the electrochemical reaction while the non-active redox couples such as Cr³⁺/Cr⁴⁺ and Fe²⁺/Fe³⁺ served as stabilizer to buffer the volume variation. A thermal stability up to ~412 ℃ is also exhibited. Therefore, incorporating a mixture of three transition metal (V/Cr/Fe) in this type of structures will broaden new perspectives for realizing high performance cathodes for MRBs.
- Multi-electron reaction,
- Mg batteries,
- NASICON,
- Na₃VCr_0.5Fe_0.5(PO₄)₃,
- Iron and chromium doping
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Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery