Citation: Xiaoxing Ji, Xiaojuan Li, Chenggang Wang, Gang Zhao, Hongxia Bu, Xijin Xu. Ni_xB/rGO as the cathode for high-performance aqueous alkaline zinc-based battery[J]. Chinese Chemical Letters, ;2024, 35(10): 109388. doi: 10.1016/j.cclet.2023.109388 shu

Ni_xB/rGO as the cathode for high-performance aqueous alkaline zinc-based battery

Xiaoxing Ji ^{a, 1} ,
Xiaojuan Li ^{a, 1} ,
Chenggang Wang ^a ,
Gang Zhao ^a ,
Hongxia Bu ^{b, *,} ,
Xijin Xu ^{a, *,}

a.
School of Physics and Technology, University of Jinan, Ji'nan 250022, China
b.
College of Physics and Electronic Engineering, Qilu Normal University, Ji'nan 250200, China

buhx66@163.com

sps_xuxj@ujn.edu.cn

Received Date: 31 October 2023
Revised Date: 27 November 2023
Accepted Date: 6 December 2023
Available Online: 14 December 2023

Figures(4)

Aqueous alkaline zinc batteries (AZBs) exhibit great potential due to their high capacity, high safety and low cost. However, despite these advantages, the lack of high stability and high utilization rate makes the search for high-performance cathode materials a great challenge. Here, an amorphous nickel boride/rGO (NiB/rGO) complex structure was designed. As a result of abundant unsaturated active sites and synergistic electronic effects, amorphous NiB exhibits excellent energy storage properties. As well as having high electrical conductivity, rGO avoids aggregation of NiB nanoparticles, ensuring that NiB/rGO electrodes have a high energy storage capacity. The structure has a strong adhesion between NiB and rGO, which protects its stable structure and extends its life. More importantly, the NiB/rGO//Zn full battery shows remarkable capacity (228.4 mAh/g at 2 A/g), extraordinary cycle durability (93.7% retained after 1000 cycles) and strong energy density 399.7 Wh/kg, when coupled with NiB/rGO cathode. This work will also shed light on other nickel-zinc batteries in order to achieve super durability and capacity.
- Alkaline aqueous zinc battery,
- Nickel boride,
- rGO,
- Cathode materials,
- Energy density
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

NixB/rGO as the cathode for high-performance aqueous alkaline zinc-based battery

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通讯作者: 陈斌, bchen63@163.com

Ni_xB/rGO as the cathode for high-performance aqueous alkaline zinc-based battery