Citation: Xue-Zhi Wang, Yi-Tong Liu, Chuang-Wei Zhou, Bei Wang, Dong Luo, Mo Xie, Meng-Ying Sun, Yong-Liang Huang, Jie Luo, Yan Wu, Shuixing Zhang, Xiao-Ping Zhou, Dan Li. Amplified circularly polarized luminescence of chiral metal-organic frameworks via post-synthetic installing pillars[J]. Chinese Chemical Letters, ;2024, 35(10): 109380. doi: 10.1016/j.cclet.2023.109380 shu

Amplified circularly polarized luminescence of chiral metal-organic frameworks via post-synthetic installing pillars

Xue-Zhi Wang ^{a, b} ,
Yi-Tong Liu ^b ,
Chuang-Wei Zhou ^b ,
Bei Wang ^b ,
Dong Luo ^b ,
Mo Xie ^b ,
Meng-Ying Sun ^b ,
Yong-Liang Huang ^c ,
Jie Luo ^b ,
Yan Wu ^{d, *,} ,
Shuixing Zhang ^{a, *,} ,
Xiao-Ping Zhou ^{b, *,} ,
Dan Li ^b

a.
Department of Radiology, The First Affiliated Hospital, Jinan University, Guangzhou 510632, China
b.
College of Chemistry and Materials Science, and Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, China
c.
Department of Medicinal Chemistry, Shantou University Medical College, Shantou 515041, China
d.
Department of Anesthesiology, The First Affiliated Hospital of Sun Yat-sen University, Guangzhou 510080, China

wuyan27@mail.sysu.edu.cn

shui7515@126.com

zhouxp@jnu.edu.cn

Received Date: 9 November 2023
Revised Date: 3 December 2023
Accepted Date: 6 December 2023
Available Online: 13 December 2023

Figures(6)

Post-synthetic installation strategy is an effective approach to improve the functions of metal-organic frameworks (MOFs). Herein, a pair of chiral MOFs is successfully constructed through solvothermal subcomponent self-assembly and exhibit circularly polarized luminescence (CPL). These MOFs contain coordinatively unsaturated Zn sites and channels, which allow the installation of pyridyl-terminated pillars into the original structure. Such a post-synthetic installation process reinforces the MOFs' rigidity and increases the photoluminescence quantum yields (PLQYs). Furthermore, the luminescence dissymmetry factors (g_lum) of these post-modified MOFs are amplified after installing the pillars. This work provides an appealing strategy for boosting the CPL performance of chiral MOFs.
- Chiral metal-organic frameworks,
- Circularly polarized luminescence,
- Post-synthetic installation,
- Pyridyl-terminated pillars,
- Chirality transfer
1. [1]
  X. Zhan, F.F. Xu, Z. Zhou, et al., Adv. Mater. 33 (2021) e2104418. doi: 10.1002/adma.202104418
2. [2]
  H. Fan, K. Li, T. Tu, et al., Angew. Chem. Int. Ed. 61 (2022) e202200727. doi: 10.1002/anie.202200727
3. [3]
  T. Kawasaki, M. Sato, S. Ishiguro, et al., J. Am. Chem. Soc. 127 (2005) 3274–3275. doi: 10.1021/ja0422108
4. [4]
  S. Shuvaev, M.A. Fox, D. Parker, Angew. Chem. Int. Ed. 57 (2018) 7488–7492. doi: 10.1002/anie.201801248
5. [5]
  J. Kumar, T. Nakashima, T. Kawai, J. Phys. Chem. Lett. 6 (2015) 3445–3452. doi: 10.1021/acs.jpclett.5b01452
6. [6]
  B.N. Willis, D. Schnable, N.D. Schley, G. Ung, J. Am. Chem. Soc. 144 (2022) 22421–22425. doi: 10.1021/jacs.2c10364
7. [7]
  M. Li, Y. Zhou, J. Li, et al., Chin. Chem. Lett. 35 (2024) 108831. doi: 10.1016/j.cclet.2023.108831
8. [8]
  Y. Deng, F. Li, Z. Zhou, et al., Chin. Chem. Lett. 35 (2024) 109085. doi: 10.1016/j.cclet.2023.109085
9. [9]
  M. Li, S.H. Li, D. Zhang, et al., Angew. Chem. Int. Ed. 57 (2018) 2889–2893. doi: 10.1002/anie.201800198
10. [10]
  Y.P. Zhang, S.Q. Song, M.X. Mao, et al., Sci. China Chem. 65 (2022) 1347–1355. doi: 10.1007/s11426-022-1249-7
11. [11]
  M. Xu, G. Li, W. Li, et al., Angew. Chem. Int. Ed. 61 (2022) e202117042. doi: 10.1002/anie.202117042
12. [12]
  X. Yang, X. Jin, A. Zheng, P. Duan, ACS Nano 17 (2023) 2661–2668. doi: 10.1021/acsnano.2c10646
13. [13]
  G. Park, D.Y. Jeong, S.Y. Yu, et al., Angew. Chem. Int. Ed. 62 (2023) e202309762. doi: 10.1002/anie.202309762
14. [14]
  G.H. Chen, Y.P. He, Y. Yu, Q.H. Li, J. Zhang, Sci. China Chem. 66 (2023) 2558–2562. doi: 10.1007/s11426-023-1707-4
15. [15]
  H. Furukawa, K.E. Cordova, M. O'Keeffe, O.M. Yaghi, Science 341 (2013) 1230444. doi: 10.1126/science.1230444
16. [16]
  H. Zeng, M. Xie, T. Wang, et al., Nature 595 (2021) 542–548. doi: 10.1038/s41586-021-03627-8
17. [17]
  W. Gong, Z. Chen, J. Dong, Y. Liu, Y. Cui, Chem. Rev. 122 (2022) 9078–9144. doi: 10.1021/acs.chemrev.1c00740
18. [18]
  D. Luo, Y.L. Peng, M. Xie, et al., ACS Appl. Mater. Interfaces 14 (2022) 11547–11558. doi: 10.1021/acsami.2c00118
19. [19]
  C. Zhang, S. Li, X.Y. Dong, S.Q. Zang, Aggregate 2 (2021) e48. doi: 10.1002/agt2.48
20. [20]
  L.A. Hall, D.M. D'Alessandro, G. Lakhwani, Chem. Soc. Rev. 52 (2023) 3567–3590. doi: 10.1039/d2cs00129b
21. [21]
  X.Y. Luo, M. Pan, Coord. Chem. Rev. 468 (2022) 214640. doi: 10.1016/j.ccr.2022.214640
22. [22]
  S.M. Chen, L.M. Chang, X.K. Yang, et al., ACS Appl. Mater. Interfaces 11 (2019) 31421–31426. doi: 10.1021/acsami.9b11872
23. [23]
  W.L. Shang, X.F. Zhu, T.L. Liang, et al., Angew. Chem. Int. Ed. 59 (2020) 12811–12816. doi: 10.1002/anie.202005703
24. [24]
  X.Z. Wang, M.Y. Sun, Z.J. Huang, et al., Adv. Opt. Mater. 9 (2021) 2002096. doi: 10.1002/adom.202002096
25. [25]
  H. Jiang, W. Zhang, B. Hou, Y. Liu, Y. Cui, CCS Chem. 5 (2023) 1635–1643. doi: 10.31635/ccschem.022.202202285
26. [26]
  L.Z. Sui, Z.B. Jin, G.M. Niu, et al., CCS Chem. (2023) 2215–2224. doi: 10.31635/ccschem.023.202302932
27. [27]
  X.Z. Wang, C.W. Zhou, J. Zheng, et al., Adv. Sci. 10 (2023) e2207333. doi: 10.1002/advs.202207333
28. [28]
  Y.H. Xiao, P. Weidler, S.S. Lin, et al., Adv. Funct. Mater. 32 (2022) 2204289. doi: 10.1002/adfm.202204289
29. [29]
  Z.L. Gong, Z.Q. Li, Y.W. Zhong, Aggregate 3 (2022) e177. doi: 10.1002/agt2.177
30. [30]
  A. Zheng, T. Zhao, X. Jin, W. Miao, P. Duan, Nanoscale 14 (2022) 1123–1135. doi: 10.1039/d1nr07069j
31. [31]
  S. Mandal, S. Natarajan, P. Mani, A. Pankajakshan, Adv. Funct. Mater. 31 (2020) 2006291.
32. [32]
  Y. Hu, X. Zhang, R.S.H. Khoo, et al., J. Am. Chem. Soc. (2023) 13929–13937. doi: 10.1021/jacs.3c03421
33. [33]
  Z.J. Li, Y. Ju, J. Qiu, et al., Chem. Commun. 59 (2023) 4958–4961. doi: 10.1039/d3cc00278k
34. [34]
  J. Guo, Y. Lian, F.F. Li, et al., Chem Catal. 2 (2022) 2986–3018. doi: 10.1016/j.checat.2022.09.024
35. [35]
  T. Zhao, J. Han, X. Jin, et al., Research 2020 (2020) 6452123.
36. [36]
  C. Zhang, Z.P. Yan, X.Y. Dong, et al., Adv. Mater. 32 (2020) e2002914. doi: 10.1002/adma.202002914
37. [37]
  R. Zhai, Y.H. Xiao, Z.G. Gu, J. Zhang, Nano Res. 15 (2022) 1102–1108. doi: 10.1007/s12274-021-3610-x
38. [38]
  L. Hu, K. Li, W. Shang, X. Zhu, M. Liu, Angew. Chem. Int. Ed. 59 (2020) 4953–4958. doi: 10.1002/anie.202000589
39. [39]
  M. Kazem-Rostami, A. Orte, A.M. Ortuno, et al., J. Am. Chem. Soc. 144 (2022) 9380–9389. doi: 10.1021/jacs.2c01554
40. [40]
  C. Zhang, Z.S. Li, X.Y. Dong, Y.Y. Niu, S.Q. Zang, Adv. Mater. 34 (2022) e2109496. doi: 10.1002/adma.202109496
41. [41]
  C.X. Chen, Z. Wei, J.J. Jiang, et al., Angew. Chem. Int. Ed. 55 (2016) 9932–9936. doi: 10.1002/anie.201604023
42. [42]
  X. Zhang, B.L. Frey, Y.S. Chen, J. Zhang, J. Am. Chem. Soc. 140 (2018) 7710–7715. doi: 10.1021/jacs.8b04277
43. [43]
  J. Pang, S. Yuan, J.S. Qin, et al., J. Am. Chem. Soc. 141 (2019) 3129–3136. doi: 10.1021/jacs.8b12530
44. [44]
  B. Zhao, Q. Yang, J.S. Wang, et al., New J. Chem. 45 (2021) 4401–4407. doi: 10.1039/d0nj05866a
45. [45]
  O. Delgado-Friedrichs, M. O'Keeffe, Acta Crystallogr. Sect. A: Found. Crystallogr. 59 (2003) 351–360. doi: 10.1107/S0108767303012017
46. [46]
  V.A. Blatov, A.P. Shevchenko, D.M. Proserpio, Cryst. Growth Des. 14 (2014) 3576–3586. doi: 10.1021/cg500498k
47. [47]
  L.Q. Zuo, T.F. Zhang, Z.K. Zhang, et al., Inorg. Chem. Commun. 99 (2019) 113–118. doi: 10.1016/j.inoche.2018.11.006
48. [48]
  B. Wang, X.Z. Wang, D. Luo, X.P. Zhou, D. Li, J. Coord. Chem. 75 (2022) 1670–1678. doi: 10.1080/00958972.2022.2040491
49. [49]
  X.Q. Lü, W.X. Feng, Y.N. Hui, et al., Eur. J. Inorg. Chem. 2010 (2010) 2714–2722. doi: 10.1002/ejic.201000100
50. [50]
  Y.D. Zhang, S. Yu, B. Han, et al., Matter 5 (2022) 837–875. doi: 10.1016/j.matt.2022.01.001
51. [51]
  Y. Sang, J. Han, T. Zhao, P. Duan, M. Liu, Adv. Mater. 32 (2020) e1900110. doi: 10.1002/adma.201900110
52. [52]
  Z.H. Sheng, L. Shao, J.J. Chen, et al., ACS Nano 5 (2011) 4350–4358. doi: 10.1021/nn103584t
53. [53]
  L. Ci, L. Song, C. Jin, et al., Nat. Mater. 9 (2010) 430–435. doi: 10.1038/nmat2711
54. [54]
  R.G. Pearson, lnorg. Chem. 27 (1988) 734–740. doi: 10.1021/ic00277a030
55. [55]
  G.J. McManus, J.J. Perry, M. Perry, B.D. Wagner, M.J. Zaworotko, J. Am. Chem. Soc. 129 (2007) 9094–9101. doi: 10.1021/ja071271d
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