Citation: Zhi-Yuan Yue, Hua-Kai Li, Na Wang, Shan-Shan Liu, Le-Ping Miao, Heng-Yun Ye, Chao Shi. Dehydration-triggered structural phase transition-associated ferroelectricity in a hybrid perovskite-type crystal[J]. Chinese Chemical Letters, ;2024, 35(10): 109355. doi: 10.1016/j.cclet.2023.109355 shu

Dehydration-triggered structural phase transition-associated ferroelectricity in a hybrid perovskite-type crystal

Chaotic Matter Science Research Center, Jiangxi University of Science and Technology, Ganzhou 341000, China

nawang0810@163.com

shic@jxust.edu.cn

Received Date: 24 October 2023
Revised Date: 15 November 2023
Accepted Date: 27 November 2023
Available Online: 2 December 2023

Figures(5)

Since the appearance of Rochelle salt, ferroelectrics have received extensive attention from researchers due to they are playing an important role in sensors, memories, mechanical actuation, and so on. In recent years, with the rapid development of molecular ferroelectrics, high-performance molecular ferroelectrics have become effective complement to inorganic ferroelectrics. However, compared with inorganic ferroelectrics, the family of molecular ferroelectrics is relatively scarce, and exploring high-performance ferroelectric materials through new synthesis strategies has become the trend of molecular ferroelectrics. Here, we successfully transformed non-polar material 1 (2-H₂PCA)₂(H₂O)CdCl₆ (2-H₂PCA = 2-picolylamine cation) into polar material 2 (2-H₂PCA)₂CdCl₆ by single-crystal to single-crystal transformation (SCSCT). Meanwhile, 2 exhibits clear ferroelectricity with a high-temperature T_c of 378 K, a P_s of 1.18 µC/cm² at 300 K. This work not only realizes the purpose of synthesizing ferroelectrics by forming polar structures by SCSCT, but also realizes the reversibility of SCSCT, which provides ideas for the construction and exploration of new molecular ferroelectrics.
- Hybrid perovskite,
- Ferroelectric materials,
- Single-crystal to single-crystal transformation,
- Phase transition,
- Stimulus-structure-response
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