Citation: Chen Lian, Si-Han Zhao, Hai-Lou Li, Xinhua Cao. A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant[J]. Chinese Chemical Letters, ;2024, 35(10): 109343. doi: 10.1016/j.cclet.2023.109343 shu

A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant

Chen Lian ^b ,
Si-Han Zhao ^a ,
Hai-Lou Li ^{a, *,} ,
Xinhua Cao ^{a, *,}

a.
College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, China
b.
MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, China

lhl@xynu.edu.cn

caoxhchem@163.com

Received Date: 26 October 2023
Revised Date: 14 November 2023
Accepted Date: 29 November 2023
Available Online: 6 December 2023

Figures(4)

A novel Ce-containing poly(tungstobismuthate) Cs₁₈Na₈H₂₀[Ce₃(H₂O)₁₀W₈Bi₄O₂₈(B-α-BiW₉ O₃₃)₄]₂·64H₂O (1) has been synthesized by a facile one-pot self-assembly reaction strategy. Its structural characterization is realized by virtue of single-crystal X-ray diffraction, infrared spectroscopy, powder X-ray diffraction and thermogravimetric analysis. The polyoxoanion of 1 is an octameric architecture consisting of two tetrameric entities [Ce₃(H₂O)₁₀W₈Bi₄O₂₈(B-α-BiW₉O₃₃)₄]²³⁻ linked by two CeOW bonds, and adjacent polyoxoanions are further combined together by means of Ce³⁺ linkers, resulting in an infinite 1D chain architecture. Compound 1 is the currently largest tungstobismuthate, and also represents the first example of lanthanide-encapsulated tungstobismuthate exhibiting an extended structure. Furthermore, compound 1 as a heterogeneous catalyst, exhibits high activity for the oxidative decontamination of a sulfur mustard simulant, 2-chloroethyl ethyl sulfide (CEES) into 2-chloroethyl ethyl sulfoxide (CEESO).
- Polyoxometalates,
- Tungstobismuthate,
- Cluster,
- Lanthanide,
- Oxidation
1. [1]
  S.T. Zheng, G.Y. Yang, Chem. Soc. Rev. 41 (2012) 7623–7646. doi: 10.1039/c2cs35133a
2. [2]
  J. Lin, N. Li, S. Yang, et al., J. Am. Chem. Soc. 142 (2020) 13982–13988. doi: 10.1021/jacs.0c06582
3. [3]
  D.L. Long, R. Tsunashima, L. Cronin, Angew. Chem. Int. Ed. 49 (2010) 1736–1758. doi: 10.1002/anie.200902483
4. [4]
  H.L. Li, M. Zhang, C. Lian, et al., CCS Chem. 2 (2020) 2095–2103.
5. [5]
  Y.L. Wu, X.X. Li, Y.J. Qi, et al., Angew. Chem. Int. Ed. 57 (2018) 8572–8576. doi: 10.1002/anie.201804088
6. [6]
  S.R. Li, H.Y. Wang, H.F. Su, et al., Small Methods 5 (2021) 2000777. doi: 10.1002/smtd.202000777
7. [7]
  S.S. Wang, G.Y. Yang, Chem. Rev. 115 (2015) 4893–4962. doi: 10.1021/cr500390v
8. [8]
  J. Liu, W. Shi, X. Wang, J. Am. Chem. Soc. 143 (2021) 16217–16225. doi: 10.1021/jacs.1c07477
9. [9]
  K. Qin, D. Zang, Y. Wei, Chin. Chem. Lett. 34 (2023) 107999. doi: 10.1016/j.cclet.2022.107999
10. [10]
  K. Zheng, B. Niu, C. Lin, et al., Chin. Chem. Lett. 34 (2023) 107238. doi: 10.1016/j.cclet.2022.02.043
11. [11]
  Q. Zhang, F.Y. Li, L. Xu, Polyoxometalates 2 (2023) 9140018. doi: 10.26599/POM.2022.9140018
12. [12]
  H.L. Li, C. Lian, D.P. Yin, et al., Inorg. Chem. 59 (2020) 12842–12849. doi: 10.1021/acs.inorgchem.0c01910
13. [13]
  J.X. Liu, N.V. Izarova, P. Kögerler, Chem. Commun. 55 (2019) 10744–10747. doi: 10.1039/C9CC04623B
14. [14]
  X. Xu, Y. Chen, Y. Zhang, et al., Inorg. Chem. 58 (2019) 11636–11648. doi: 10.1021/acs.inorgchem.9b01570
15. [15]
  Y. Ma, F. Gao, W. Xiao, et al., Chin. Chem. Lett. 33 (2022) 4395–4399. doi: 10.1016/j.cclet.2021.12.023
16. [16]
  Z. Li, X.X. Li, T. Yang, et al., Angew. Chem. Int. Ed. 56 (2017) 2664–2669. doi: 10.1002/anie.201612046
17. [17]
  Y.N. Gu, Y. Chen, Y.L. Wu, et al., Inorg. Chem. 57 (2018) 2472–2479. doi: 10.1021/acs.inorgchem.7b02728
18. [18]
  S. Li, Z. Weng, L. Jiang, et al., Chin. Chem. Lett. 34 (2023) 107251. doi: 10.1016/j.cclet.2022.02.056
19. [19]
  J. Goura, B.S. Bassil, J.K. Bindra, et al., Chem. Eur. J. 26 (2020) 15821–15824. doi: 10.1002/chem.202002832
20. [20]
  X.B. Han, Z.M. Zhang, T. Zhang, et al., J. Am. Chem. Soc. 136 (2014) 5359–5366. doi: 10.1021/ja412886e
21. [21]
  Z.M. Zhang, X. Duan, S. Yao, et al., Chem. Sci. 7 (2016) 4220–4229. doi: 10.1039/C5SC04408A
22. [22]
  Z.M. Zhang, S. Yao, Y.G. Li, et al., Chem. Commun. 49 (2013) 2515–2517. doi: 10.1039/c3cc38981b
23. [23]
  J. Cai, X.Y. Zheng, J. Xie, et al., Inorg. Chem. 56 (2017) 8439–8445. doi: 10.1021/acs.inorgchem.7b01104
24. [24]
  Y.J. Wang, S.Y. Wu, Y.Q. Sun, et al., Chem. Commun. 55 (2019) 2857–2860. doi: 10.1039/C9CC00073A
25. [25]
  D. Wang, J. Jiang, M.Y. Cao, et al., Nano Res. 15 (2022) 3628–3637. doi: 10.1007/s12274-021-3940-8
26. [26]
  L. Liu, J. Jiang, L. Cui, et al., Inorg. Chem. 61 (2022) 1949–1960. doi: 10.1021/acs.inorgchem.1c03103
27. [27]
  Z. Li, Z.H. Lv, H. Yu, et al., CCS Chem. 4 (2022) 2938–2945. doi: 10.31635/ccschem.021.202101573
28. [28]
  S.R. Li, W.D. Liu, L.S. Long, et al., Polyoxometalates 2 (2023) 9140022. doi: 10.26599/POM.2023.9140022
29. [29]
  S.X. Shang, Z.G. Lin, A.X. Yin, et al., Inorg. Chem. 57 (2018) 8831–8840. doi: 10.1021/acs.inorgchem.8b00693
30. [30]
  Z.K. Zhu, Y.Y. Lin, R.D. Lai, et al., Chin. Chem. Lett. 34 (2023) 107773. doi: 10.1016/j.cclet.2022.107773
31. [31]
  J.M. Cameron, J. Gao, D.L. Long, et al., Inorg. Chem. Front. 1 (2014) 178–185. doi: 10.1039/C3QI00075C
32. [32]
  I.V. Kalinina, E.V. Peresypkina, N.V. Izarova, et al., Inorg. Chem. 53 (2014) 2076–2082. doi: 10.1021/ic402668v
33. [33]
  E. Tanuhadi, N.I. Gumerova, A. Prado-Roller, et al., Inorg. Chem. 60 (2021) 8917–8923. doi: 10.1021/acs.inorgchem.1c00810
34. [34]
  J. Li, N. Song, M. Wang, et al., Inorg. Chem. 61 (2022) 17166–17177. doi: 10.1021/acs.inorgchem.2c02677
35. [35]
  J.W. Zhao, H.L. Li, X. Ma, et al., Sci. Rep. 6 (2016) 26406. doi: 10.1038/srep26406
36. [36]
  K. Wassermann, M.H. Dickman, M.T. Pope, Angew. Chem. Int. Ed. 36 (1997) 1445–1448. doi: 10.1002/anie.199714451
37. [37]
  K. Fukaya, T. Yamase, Angew. Chem. Int. Ed. 42 (2003) 654–658. doi: 10.1002/anie.200390180
38. [38]
  W.C. Chen, H.L. Li, X.L. Wang, et al., Chem. Eur. J. 19 (2013) 11007–11015. doi: 10.1002/chem.201300615
39. [39]
  W.C. Chen, C. Qin, X.L. Wang, et al., Dalton Trans. 44 (2015) 11290–11293. doi: 10.1039/C5DT01711D
40. [40]
  H.L. Li, C. Lian, L.J. Chen, et al., Nanoscale 12 (2020) 16091–16101. doi: 10.1039/D0NR04051G
41. [41]
  H.L. Li, C. Lian, L.J. Chen, et al., Inorg. Chem. 58 (2019) 8442–8450. doi: 10.1021/acs.inorgchem.9b00582
42. [42]
  K. Cui, F. Li, L. Xu, et al., Dalton Trans. 41 (2012) 4871–4877. doi: 10.1039/c2dt11478j
43. [43]
  J.C. Liu, Q. Han, L.J. Chen, et al., Angew. Chem. Int. Ed. 57 (2018) 8416–8420. doi: 10.1002/anie.201803649
44. [44]
  I.D. Brown, D. Altermatt, Acta Crystallogr. Sect. B: Struct. Sci. B41 (1985) 244–247. doi: 10.1107/S0108768185002063
45. [45]
  A. Atilgan, T. Islamoglu, A.J. Howarth, et al., ACS Appl. Mater. Interfaces 9 (2017) 24555–24560. doi: 10.1021/acsami.7b05494
46. [46]
  N. Emmanuel, P. Bianchi, J. Legros, et al., Green Chem. 22 (2020) 4105–4115. doi: 10.1039/D0GC01142H
47. [47]
  E. Oheix, E. Gravel, E. Doris, Chem. Eur. J. 27 (2021) 54–68. doi: 10.1002/chem.202003665
48. [48]
  B.M. Smith, Chem. Soc. Rev. 37 (2008) 470–478. doi: 10.1039/B705025A
49. [49]
  H.R. Tian, Z. Zhang, S.M. Liu, et al., J. Mater. Chem. A 8 (2020) 12398–12405. doi: 10.1039/D0TA00537A
50. [50]
  H. Wang, G.W. Wagner, A.X. Lu, et al., ACS Appl. Mater. Interfaces 10 (2018) 18771–18777. doi: 10.1021/acsami.8b04576
51. [51]
  J. Dong, J. Hu, Y. Chi, et al., Angew. Chem. Int. Ed. 56 (2017) 4473–4477. doi: 10.1002/anie.201700159
52. [52]
  F. Carniato, C. Bisio, R. Psaro, et al., Angew. Chem. Int. Ed. 53 (2014) 10095–10098. doi: 10.1002/anie.201405134
53. [53]
  K. Ma, T. Islamoglu, Z. Chen, et al., J. Am. Chem. Soc. 141 (2019) 15626–15633. doi: 10.1021/jacs.9b07301
54. [54]
  C.T. Buru, P. Li, B.L. Mehdi, et al., Chem. Mater. 29 (2017) 5174–5181. doi: 10.1021/acs.chemmater.7b00750
55. [55]
  Y. Zhi, Z. Yao, W. Jiang, et al., ACS Appl. Mater. Interfaces 11 (2019) 37578–37585. doi: 10.1021/acsami.9b10958
56. [56]
  N. Zhen, J. Dong, Z. Lin, et al., Chem. Commun. 56 (2020) 13967–13970. doi: 10.1039/D0CC06277D
57. [57]
  H.L. Li, C. Lian, G.Y. Yang, Sci. China Chem. 65 (2022) 892–897. doi: 10.1007/s11426-022-1215-1
58. [58]
  J.Y. Sun, Z.L. Wang, Z. Zhang, et al., Polyoxometalates 3 (2024) 9140039. doi: 10.26599/POM.2023.9140039
59. [59]
  Y. Hou, H. An, Y. Zhang, et al., ACS Catal. 8 (2018) 6062–6069. doi: 10.1021/acscatal.8b00972
60. [60]
  H.L. Li, C. Lian, G.Y. Yang, Dalton Trans. 52 (2023) 857–861. doi: 10.1039/D2DT03820J
61. [61]
  L. Yang, Z. Zhang, C. Zhang, et al., Inorg. Chem. Front. 9 (2022) 4824–4833. doi: 10.1039/D2QI00838F
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