Citation: Chen Lian, Si-Han Zhao, Hai-Lou Li, Xinhua Cao. A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant[J]. Chinese Chemical Letters, ;2024, 35(10): 109343. doi: 10.1016/j.cclet.2023.109343 shu

A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant

Chen Lian ^b ,
Si-Han Zhao ^a ,
Hai-Lou Li ^{a, *,} ,
Xinhua Cao ^{a, *,}

a.
College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, China
b.
MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, China

lhl@xynu.edu.cn

caoxhchem@163.com

Received Date: 26 October 2023
Revised Date: 14 November 2023
Accepted Date: 29 November 2023
Available Online: 6 December 2023

Figures(4)

A novel Ce-containing poly(tungstobismuthate) Cs₁₈Na₈H₂₀[Ce₃(H₂O)₁₀W₈Bi₄O₂₈(B-α-BiW₉ O₃₃)₄]₂·64H₂O (1) has been synthesized by a facile one-pot self-assembly reaction strategy. Its structural characterization is realized by virtue of single-crystal X-ray diffraction, infrared spectroscopy, powder X-ray diffraction and thermogravimetric analysis. The polyoxoanion of 1 is an octameric architecture consisting of two tetrameric entities [Ce₃(H₂O)₁₀W₈Bi₄O₂₈(B-α-BiW₉O₃₃)₄]²³⁻ linked by two CeOW bonds, and adjacent polyoxoanions are further combined together by means of Ce³⁺ linkers, resulting in an infinite 1D chain architecture. Compound 1 is the currently largest tungstobismuthate, and also represents the first example of lanthanide-encapsulated tungstobismuthate exhibiting an extended structure. Furthermore, compound 1 as a heterogeneous catalyst, exhibits high activity for the oxidative decontamination of a sulfur mustard simulant, 2-chloroethyl ethyl sulfide (CEES) into 2-chloroethyl ethyl sulfoxide (CEESO).
- Polyoxometalates,
- Tungstobismuthate,
- Cluster,
- Lanthanide,
- Oxidation
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