Citation: Yiqian Jiang, Zihan Yang, Xiuru Bi, Nan Yao, Peiqing Zhao, Xu Meng. Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation[J]. Chinese Chemical Letters, ;2024, 35(8): 109331. doi: 10.1016/j.cclet.2023.109331 shu

Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation

Yiqian Jiang ^{a, b, 1} ,
Zihan Yang ^{a, b, 1} ,
Xiuru Bi ^a ,
Nan Yao ^{a, b} ,
Peiqing Zhao ^{a, *,} ,
Xu Meng ^{a, *,}

a.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

zhaopq@licp.cas.cn

xumeng@licp.cas.cn

Received Date: 28 August 2023
Revised Date: 1 November 2023
Accepted Date: 15 November 2023
Available Online: 23 November 2023

Figures(5)

In Fenton-like oxidation, the catalyst directly influences the reaction mechanism for the degradation of pollutants from water. Here, a α-MnO₂ catalyst (OAm-1) was synthesized via a self-assembly method with the assistance of a surfactant. OAm-1 possessed a large specific surface area of 221 m²/g, abundant mesoporous structures and a large proportion of Mn(Ⅲ). Further characterization exhibited that OAm-1 had abundant oxygen vacancies and excellent reducibility and conductivity. The adsorption and catalytic ability of OAm-1 were studied in the degradation of oxytetracycline (OTC) via the activation of hydrogen peroxide (H₂O₂). Through the radical quenching experiments, electron resonance spectroscopy (EPR), X-ray photoelectron spectroscopy (XPS) and Fourier-transform infrared spectroscopy (FT-IR) analysis, Mn(Ⅲ) of OAm-1 was proved to be the active sites for the chemisorption of OTC. Systematic electrochemical experiments and analysis have shown that a process of electron transfer mediated by OAm-1 occurred between the pollutant and H₂O₂ during a Fenton-like reaction. This work experimentally verifies the electron transfer process dominated nonradical mechanism over α-MnO₂, which is helpful for understanding the catalytic mechanism of the Fenton-like oxidation.
- Mediated electron transfer,
- Hydrogen peroxide,
- Oxidative degradation,
- Manganese oxide,
- Fenton oxidation
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Mediated electron transfer process in α-MnO2 catalyzed Fenton-like reaction for oxytetracycline degradation

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通讯作者: 陈斌, bchen63@163.com

Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation