Citation: Yi Herng Chan, Zhe Phak Chan, Serene Sow Mun Lock, Chung Loong Yiin, Shin Ying Foong, Mee Kee Wong, Muhammad Anwar Ishak, Ven Chian Quek, Shengbo Ge, Su Shiung Lam. Thermal pyrolysis conversion of methane to hydrogen (H₂): A review on process parameters, reaction kinetics and techno-economic analysis[J]. Chinese Chemical Letters, ;2024, 35(8): 109329. doi: 10.1016/j.cclet.2023.109329 shu

Thermal pyrolysis conversion of methane to hydrogen (H₂): A review on process parameters, reaction kinetics and techno-economic analysis

a.
PETRONAS Research Sdn. Bhd. (PRSB), Kawasan Institusi Bangi, Lot 3288 & 3289, Off Jalan Ayer Itam, Kajang 43000, Malaysia
b.
PETRONAS Carbon Capture & Storage (CCS) Enterprise, PETRONAS Twin Towers, Kuala Lumpur City Centre, Kuala Lumpur 50088, Malaysia
c.
CO₂ Research Center (CO2RES), Department of Chemical Engineering, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia
d.
Department of Chemical Engineering and Energy Sustainability, Faculty of Engineering, Universiti Malaysia Sarawak (UNIMAS), Kota Samarahan 94300, Malaysia
e.
Institute of Sustainable and Renewable Energy (ISuRE), Universiti Malaysia Sarawak (UNIMAS), Kota Samarahan 94300, Malaysia
f.
Higher Institution Centre of Excellence (HICoE), Institute of Tropical Aquaculture and Fisheries (AKUATROP), Universiti Malaysia Terengganu, Kuala Nerus 21030, Malaysia
g.
Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China
h.
Center for Global Health Research (CGHR), Saveetha Medical College, Saveetha Institute of Medical and Technical Sciences (SIMATS), Saveetha University, Chennai 602105, India

^**

chan.yiherng@petronas.com.my

clyiin@unimas.my

lam@umt.edu.my

Received Date: 26 July 2023
Revised Date: 30 October 2023
Accepted Date: 15 November 2023
Available Online: 23 November 2023

Figures(5)

Hydrogen (H₂) is a promising renewable energy which finds wide applications as the world gears toward low-carbon economy. However, current H₂ production via steam methane reforming of natural gas or gasification of coal are laden with high CO₂ footprints. Recently, methane (CH₄) pyrolysis has emerged as a potential technology to generate low-carbon H₂ and solid carbon. In this review, the current state-of-art and recent progress of H₂ production from CH₄ pyrolysis are reviewed in detail. Aspects such as fundamental mechanism and chemistry involved, effect of process parameters on the conversion efficiency and reaction kinetics for various reaction media and catalysts are elucidated and critically discussed. Temperature, among other factors, plays the most critical influence on the methane pyrolysis reaction. Molten metal/salt could lower the operating temperature of methane pyrolysis to < 1000 ℃, whereas plasma technology usually operates in the regime of > 1000 ℃. Based on the reaction kinetics, metal-based catalysts were more efficient in lowering the activation energy of the reaction to 29.5–88 kJ/mol from that of uncatalyzed reaction (147–420.7 kJ/mol). Besides, the current techno-economic performance of the process reveals that the levelized cost of H₂ is directly influenced by the sales price of carbon (by-product) generated, which could offset the overall cost. Lastly, the main challenges of reactor design for efficient product separation and retrieval, as well as catalyst deactivation/poisoning need to be debottlenecked.
- Pyrolysis,
- Methane,
- Hydrogen,
- Reaction kinetics,
- Techno-economic analysis
1. [1]
  J. Zhang, M. Ren, X. Li, et al., Energy Convers. Manag. 205 (2020) 112419. doi: 10.1016/j.enconman.2019.112419
2. [2]
  S.C. Dantas, J.C. Escritori, R.R. Soares, C.E. Hori, Chem. Eng. J. 156 (2010) 380–387. doi: 10.1016/j.cej.2009.10.047
3. [3]
  Z. Chen, Q. Dun, Y. Shi, et al., Chem. Eng. J. 316 (2017) 842–849. doi: 10.1016/j.cej.2017.02.025
4. [4]
  V. Madadi Avargani, S. Zendehboudi, N.M. Cata Saady, M.B. Dusseault, Energy Convers. Manag. 269 (2022) 115927. doi: 10.1016/j.enconman.2022.115927
5. [5]
  H. Wu, M. Wang, F. Jing, et al., Chin. Chem. Lett. 33 (2022) 1983–1987. doi: 10.1016/j.cclet.2021.09.095
6. [6]
  B.D. Catumba, M.B. Sales, P.T. Borges, et al., Int. J. Hydrog. Energy 48 (2023) 7975–7992. doi: 10.1016/j.ijhydene.2022.11.215
7. [7]
  C. Cheng, L. Hughes, J. Clean. Prod. 391 (2023) 136223. doi: 10.1016/j.jclepro.2023.136223
8. [8]
  M. Du, D. Li, S. Liu, J. Yan, Chin. Chem. Lett. 34 (2023) 108156. doi: 10.1016/j.cclet.2023.108156
9. [9]
  D.M. Santos, C.A. Sequeira, J.L.J.Q.N. Figueiredo, J. Quím. Nova 36 (2013) 1176–1193. doi: 10.1590/S0100-40422013000800017
10. [10]
  IEAThe Future of Hydrogen: Seizing Today's Opportunities, IEA, Paris, 2019.
11. [11]
  IEAGlobal Hydrogen Review, France, 2021.
12. [12]
  M. Asif, S. Sidra Bibi, S. Ahmed, et al., Chem. Eng. J. 473 (2023) 145381. doi: 10.1016/j.cej.2023.145381
13. [13]
  S.J. Kim, T.S. Nguyen, J. Mahmood, C.T. Yavuz, Chem. Eng. J. 463 (2023) 142474. doi: 10.1016/j.cej.2023.142474
14. [14]
  A.C. Gangal, R. Edla, K. Iyer, et al., Int. J. Hydrog. Energy 37 (2012) 3712– 3718. doi: 10.1016/j.ijhydene.2011.04.011
15. [15]
  Y.H. Chan, A.C.M. Loy, K.W. Cheah, et al., Chem. Eng. J. 458 (2023) 141398. doi: 10.1016/j.cej.2023.141398
16. [16]
  J. Diab, L. Fulcheri, V. Hessel, V. Rohani, M. Frenklach, Int. J. Hydrog. Energy 47 (2022) 25831–25848. doi: 10.1016/j.ijhydene.2022.05.299
17. [17]
  L. Weger, A. Abánades, T. Butler, Int. J. Hydrog. Energy 42 (2017) 720–731. doi: 10.1016/j.ijhydene.2016.11.029
18. [18]
  S. Shiva Kumar, H. Lim, Energy Rep. 8 (2022) 13793–13813. doi: 10.1016/j.egyr.2022.10.127
19. [19]
  T. Marquardt, A. Bode, S. Kabelac, Energy Convers. Manag. 221 (2020) 113125. doi: 10.1016/j.enconman.2020.113125
20. [20]
  F. Kerscher, A. Stary, S. Gleis, et al., Int. J. Hydrog. Energy 46 (2021) 19897–19912. doi: 10.1016/j.ijhydene.2021.03.114
21. [21]
  S. Postels, A. Abánades, N. von der Assen, et al., Int. J. Hydrog. Energy 41 (2016) 23204–23212. doi: 10.1016/j.ijhydene.2016.09.167
22. [22]
  M. McConnachie, M. Konarova, S. Smart, Int. J. Hydrog. Energy 48 (2023) 25660–25682. doi: 10.1016/j.ijhydene.2023.03.123
23. [23]
  L. Fulcheri, V.J. Rohani, E. Wyse, N. Hardman, E. Dames, Int. J. Hydrog. Energy 48 (2023) 2920–2928. doi: 10.1016/j.ijhydene.2022.10.144
24. [24]
  S. Schneider, S. Bajohr, F. Graf, T. Kolb, ChemBioEng Rev. 7 (2020) 150–158. doi: 10.1002/cben.202000014
25. [25]
  J. Raza, A.H. Khoja, M. Anwar, et al., Renew. Sustain. Energy Rev. 168 (2022) 112774. doi: 10.1016/j.rser.2022.112774
26. [26]
  A. Banu, Y. Bicer, Energy Convers. Manag. : X 12 (2021) 100117.
27. [27]
  Z. Fan, W. Weng, J. Zhou, D. Gu, W. Xiao, J. Energy Chem. 58 (2021) 415–430. doi: 10.1016/j.jechem.2020.10.049
28. [28]
  S. Karimi, F. Bibak, F. Meshkani, et al., Int. J. Hydrog. Energy 46 (2021) 20435–20480. doi: 10.1016/j.ijhydene.2021.03.160
29. [29]
  L. Chen, Z. Qi, S. Zhang, J. Su, G.A. Somorjai, Catalysts 10 (2020) 858. doi: 10.3390/catal10080858
30. [30]
  Z. Yang, Q. Zhang, H. Song, et al., Chin. Chem. Lett. (2023) 108418. doi: 10.1016/j.cclet.2023.108418)
31. [31]
  N. Sánchez-Bastardo, R. Schlögl, H. Ruland, Chem. Ing. Tech. 92 (2020) 1596–1609. doi: 10.1002/cite.202000029
32. [32]
  B.J.L. Pérez, J.A.M. Jiménez, R. Bhardwaj, et al., Int. J. Hydrog. Energy 46 (2021) 4917–4935. doi: 10.1016/j.ijhydene.2020.11.079
33. [33]
  D. Kang, N. Rahimi, M.J. Gordon, H. Metiu, E.W. McFarland, Appl. Catal. B 254 (2019) 659–666. doi: 10.1016/j.apcatb.2019.05.026
34. [34]
  N. Rahimi, D. Kang, J. Gelinas, et al., Carbon 151 (2019) 181–191. doi: 10.1016/j.carbon.2019.05.041
35. [35]
  C.F. Patzschke, B. Parkinson, J.J. Willis, et al., Chem. Eng. J. 414 (2021) 128730. doi: 10.1016/j.cej.2021.128730
36. [36]
  B. Parkinson, C.F. Patzschke, D. Nikolis, S. Raman, K. Hellgardt, Chem. Eng. J. 417 (2021) 127407. doi: 10.1016/j.cej.2020.127407
37. [37]
  B. Parkinson, C.F. Patzschke, D. Nikolis, et al., Int. J. Hydrog. Energy 46 (2021) 6225–6238. doi: 10.1016/j.ijhydene.2020.11.150
38. [38]
  A. Mašláni, M. Hrabovský, P. Krenek, et al., Int. J. Hydrog. Energy 46 (2021) ˇ 1605–1614. doi: 10.1016/j.ijhydene.2020.10.105
39. [39]
  K.R. Parmar, K.K. Pant, S. Roy, Energy Convers. Manag. 232 (2021) 113893. doi: 10.1016/j.enconman.2021.113893
40. [40]
  K. Manasa, G. Naresh, M. Kalpana, et al., J. Energy Inst. 99 (2021) 73–81. doi: 10.1016/j.joei.2021.08.005
41. [41]
  Y.G. Noh, Y.J. Lee, J. Kim, et al., Chem. Eng. J. 428 (2022) 131095. doi: 10.1016/j.cej.2021.131095
42. [42]
  M.S. Vlaskin, A.V. Grigorenko, A.A. Gromov, et al., Results Eng. 15 (2022) 100598. doi: 10.1016/j.rineng.2022.100598
43. [43]
  M. Msheik, S. Rodat, S. Abanades, Energy 260 (2022) 124943. doi: 10.1016/j.energy.2022.124943
44. [44]
  M. Dadsetan, M.F. Khan, M. Salakhi, E.R. Bobicki, M.J. Thomson, Int. J. Hydrog. Energy 48 (2023) 14565–14576. doi: 10.1016/j.ijhydene.2022.12.353
45. [45]
  D. Scheiblehner, D. Neuschitzer, S. Wibner, A. Sprung, H. Antrekowitsch, Int. J. Hydrog. Energy 48 (2023) 6233–6243. doi: 10.1016/j.ijhydene.2022.08.115
46. [46]
  R. Siriwardane, J. Riley, C. Atallah, M. Bobek, Int. J. Hydrog. Energy 48 (2023) 14210–14225. doi: 10.1016/j.ijhydene.2022.12.268
47. [47]
  A.I. Alharthi, E. Abdel–Fattah, M.A. Alotaibi, I. Ud Din, A.A. Nassar, J. Saudi Chem. Soc. 27 (2023) 101641. doi: 10.1016/j.jscs.2023.101641
48. [48]
  L.J.J. Catalan, E. Rezaei, Int. J. Hydrog. Energy 47 (2022) 7547–7568. doi: 10.1016/j.ijhydene.2021.12.089
49. [49]
  M. Plevan, T. Geißler, A. Abánades, et al., Int. J. Hydrog. Energy 40 (2015) 8020–8033. doi: 10.1016/j.ijhydene.2015.04.062
50. [50]
  T. Geißler, M. Plevan, A. Abánades, et al., Int. J. Hydrog. Energy 40 (2015) 14134–14146. doi: 10.1016/j.ijhydene.2015.08.102
51. [51]
  N. Muradov, Thermocatalytic CO₂-free production of hydrogen from hydrocarbon fuels, in: Proceedings of the 2000 Hydrogen Program Review, NREL/CP-570-28890, Florida, 2000.
52. [52]
  N. Muradov, Int. J. Hydrog. Energy 26 (2001) 1165–1175. doi: 10.1016/S0360-3199(01)00073-8
53. [53]
  J.K. Dahl, V.H. Barocas, D.E. Clough, A.W. Weimer, Int. J. Hydrog. Energy 27 (2002) 377–386. doi: 10.1016/S0360-3199(01)00140-9
54. [54]
  J.K. Dahl, A.W. Weimer, W.B. Krantz, Int. J. Hydrog. Energy 29 (2004) 57–65. doi: 10.1016/S0360-3199(03)00046-6
55. [55]
  T.V. Reshetenko, L.B. Avdeeva, Z.R. Ismagilov, A.L. Chuvilin, V.A. Ushakov, Appl. Catal. A: Gen. 247 (2003) 51–63. doi: 10.1016/S0926-860X(03)00080-2
56. [56]
  S. Fukada, N. Nakamura, J. Monden, M. Nishikawa, J. Nucl. Mater. 329-333 (2004) 1365–1369. doi: 10.1016/j.jnucmat.2004.04.199
57. [57]
  D. Trommer, D. Hirsch, A. Steinfeld, Int. J. Hydrog. Energy 29 (2004) 627–633. doi: 10.1016/j.ijhydene.2003.07.001
58. [58]
  S.H. Sharif Zein, A.R. Mohamed, P.S. Talpa Sai, Ind. Eng. Chem. Res. 43 (2004) 4864–4870. doi: 10.1021/ie034208f
59. [59]
  N. Muradov, F. Smith, A. T-Raissi, Catal. Today 102-103 (2005) 225–233. doi: 10.1016/j.cattod.2005.02.018
60. [60]
  S. Abanades, G. Flamant, Sol. Energy 80 (2006) 1321–1332. doi: 10.1016/j.solener.2005.11.004
61. [61]
  S. Abanades, G. Flamant, Int. J. Hydrog. Energy 32 (2007) 1508–1515. doi: 10.1016/j.ijhydene.2006.10.038
62. [62]
  J. Wyss, J. Martinek, M. Kerins, et al., Int. J. Chem. React. Eng. 5 (2007) A69. doi: 10.2202/1542-6580.1311
63. [63]
  P. Homayonifar, Y. Saboohi, B. Firoozabadi, Int. J. Hydrog. Energy 33 (2008) 7027–7038. doi: 10.1016/j.ijhydene.2008.09.007
64. [64]
  J.L. Pinilla, I. Suelves, M.J. Lázaro, R. Moliner, Chem. Eng. J. 138 (2008) 301–306. doi: 10.1016/j.cej.2007.05.056
65. [65]
  H.F. Abbas, W.M.A. Wan Daud, Fuel Process. Technol. 90 (2009) 1167–1174. doi: 10.1016/j.fuproc.2009.05.024
66. [66]
  S. Rodat, S. Abanades, J. Coulié, G. Flamant, Chem. Eng. J. 146 (2009) 120–127. doi: 10.1016/j.cej.2008.09.008
67. [67]
  S. Rodat, S. Abanades, J.L. Sans, G. Flamant, Sol. Energy 83 (2009) 1599–1610. doi: 10.1016/j.solener.2009.05.010
68. [68]
  M. Borghei, R. Karimzadeh, A. Rashidi, N. Izadi, Int. J. Hydrog. Energy 35 (2010) 9479–9488. doi: 10.1016/j.ijhydene.2010.05.072
69. [69]
  A. Amin, W. Epling, E. Croiset, Ind. Eng. Chem. Res. 50 (2011) 12460–12470. doi: 10.1021/ie201194z
70. [70]
  G. Patrianakos, M. Kostoglou, A. Konstandopoulos, Int. J. Hydrog. Energy 36 (2011) 189–202. doi: 10.1016/j.ijhydene.2010.09.061
71. [71]
  M. Nasir Uddin, W.M.A. Wan Daud, H.F. Abbas, Energy Convers. Manag. 87 (2014) 796–809. doi: 10.1016/j.enconman.2014.07.072
72. [72]
  S. Abanades, H. Kimura, H. Otsuka, Int. J. Hydrog. Energy 40 (2015) 10744–10755. doi: 10.1016/j.ijhydene.2015.07.023
73. [73]
  U.P.M. Ashik, W.M.A. Wan Daud, H.F. Abbas, Int. J. Hydrog. Energy 42 (2017) 938–952. doi: 10.1016/j.ijhydene.2016.09.025
74. [74]
  D. Paxman, S. Trottier, M.R. Flynn, L. Kostiuk, M. Secanell, Int. J. Hydrog. Energy 42 (2017) 25166–25184. doi: 10.1016/j.ijhydene.2017.08.134
75. [75]
  T. Keipi, T. Li, T. Løvås, H. Tolvanen, J. Konttinen, Energy 135 (2017) 823–832. doi: 10.1016/j.energy.2017.06.176
76. [76]
  L.J.J. Catalan, E. Rezaei, Int. J. Hydrog. Energy 45 (2020) 2486–2503. doi: 10.1016/j.ijhydene.2019.11.143
77. [77]
  T. Becker, M. Richter, D.W. Agar, Int. J. Hydrog. Energy 48 (2023) 2112–2129. doi: 10.1016/j.ijhydene.2022.10.069
78. [78]
  N. Ozalp, K. Ibrik, M. Al-Meer, Energy 55 (2013) 74–81. doi: 10.1016/j.energy.2013.02.022
79. [79]
  S. Kazemi, S.M. Alavi, M. Rezaei, Fuel Process. Technol. 240 (2023) 107575. doi: 10.1016/j.fuproc.2022.107575
80. [80]
  S. Kazemi, S.M. Alavi, M. Rezaei, E. Akbari, Fuel 342 (2023) 127797. doi: 10.1016/j.fuel.2023.127797
81. [81]
  Q. Yan, T. Ketelboeter, Z. Cai, Molecules 27 (2022) 503. doi: 10.3390/molecules27020503
82. [82]
  A.R. da Costa Labanca, Int. J. Hydrog. Energy 45 (2020) 25698–25707. doi: 10.1016/j.ijhydene.2020.03.081
83. [83]
  J. Riley, C. Atallah, R. Siriwardane, R. Stevens, Int. J. Hydrog. Energy 46 (2021) 20338–20358. doi: 10.1016/j.ijhydene.2021.03.151
84. [84]
  F. Pruvost, S. Cloete, J. Hendrik Cloete, C. Dhoke, A. Zaabout, Energy Convers. Manag. 253 (2022) 115187. doi: 10.1016/j.enconman.2021.115187
85. [85]
  M.E. Tabat, F.O. Omoarukhe, F. Güleç, et al., Energy Convers. Manag. 278 (2023) 116707. doi: 10.1016/j.enconman.2023.116707
86. [86]
  S. Cheon, M. Byun, D. Lim, H. Lee, H. Lim, Energies 14 (2021) 6012. doi: 10.3390/en14196012
87. [87]
  N. Sánchez-Bastardo, R. Schlögl, H. Ruland, Ind. Eng. Chem. Res. 60 (2021) 11855–11881. doi: 10.1021/acs.iecr.1c01679
88. [88]
  A. Bhaskar, M. Assadi, H.N. Somehsaraei, Energy Convers. Manag. X 10 (2021) 100079.
1. [1]
  Yi Zhang , Biao Wang , Chao Hu , Muhammad Humayun , Yaping Huang , Yulin Cao , Mosaad Negem , Yigang Ding , Chundong Wang . Fe–Ni–F electrocatalyst for enhancing reaction kinetics of water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100243-100243. doi: 10.1016/j.cjsc.2024.100243
2. [2]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
3. [3]
  Xiao Li , Wanqiang Yu , Yujie Wang , Ruiying Liu , Qingquan Yu , Riming Hu , Xuchuan Jiang , Qingsheng Gao , Hong Liu , Jiayuan Yu , Weijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166
4. [4]
  Jing Cao , Dezheng Zhang , Bianqing Ren , Ping Song , Weilin Xu . Mn incorporated RuO₂ nanocrystals as an efficient and stable bifunctional electrocatalyst for oxygen evolution reaction and hydrogen evolution reaction in acid and alkaline. Chinese Chemical Letters, 2024, 35(10): 109863-. doi: 10.1016/j.cclet.2024.109863
5. [5]
  Xinghui Yao , Zhouyu Wang , Da-Gang Yu . Sustainable electrosynthesis: Enantioselective electrochemical Rh(III)/chiral carboxylic acid-catalyzed oxidative CH cyclization coupled with hydrogen evolution reaction. Chinese Chemical Letters, 2024, 35(9): 109916-. doi: 10.1016/j.cclet.2024.109916
6. [6]
  Qijun Tang , Wenguang Tu , Yong Zhou , Zhigang Zou . High efficiency and selectivity catalyst for photocatalytic oxidative coupling of methane. Chinese Journal of Structural Chemistry, 2023, 42(12): 100170-100170. doi: 10.1016/j.cjsc.2023.100170
7. [7]
  Fanxin Kong , Hongzhi Wang , Huimei Duan . Inhibition effect of sulfation on Pt/TiO2 catalysts in methane combustion. Chinese Journal of Structural Chemistry, 2024, 43(5): 100287-100287. doi: 10.1016/j.cjsc.2024.100287
8. [8]
  Junchuan Sun , Lu Wang . Carbon exchange enabled supra-photothermal methane dry reforming. Chinese Journal of Structural Chemistry, 2024, 43(10): 100330-100330. doi: 10.1016/j.cjsc.2024.100330
9. [9]
  Junhua Wang , Xin Lian , Xichuan Cao , Qiao Zhao , Baiyan Li , Xian-He Bu . Dual polarization strategy to enhance CH₄ uptake in covalent organic frameworks for coal-bed methane purification. Chinese Chemical Letters, 2024, 35(8): 109180-. doi: 10.1016/j.cclet.2023.109180
10. [10]
  Yanling Yang , Zhenfa Ding , Huimin Wang , Jianhui Li , Yanping Zheng , Hongquan Guo , Li Zhang , Bing Yang , Qingqing Gu , Haifeng Xiong , Yifei Sun . Dynamic tracking of exsolved PdPt alloy/perovskite catalyst for efficient lean methane oxidation. Chinese Chemical Letters, 2024, 35(4): 108585-. doi: 10.1016/j.cclet.2023.108585
11. [11]
  Tinghui Yang , Min Kuang , Jianping Yang . Mesoporous CuCe dual-metal catalysts for efficient electrochemical reduction of CO2 to methane. Chinese Journal of Structural Chemistry, 2024, 43(8): 100350-100350. doi: 10.1016/j.cjsc.2024.100350
12. [12]
  Tao Ban , Xi-Yang Yu , Hai-Kuo Tian , Zheng-Qing Huang , Chun-Ran Chang . One-step conversion of methane and formaldehyde to ethanol over SA-FLP dual-active-site catalysts: A DFT study. Chinese Chemical Letters, 2024, 35(4): 108549-. doi: 10.1016/j.cclet.2023.108549
13. [13]
  Ziyang Yin , Lingbin Xie , Weinan Yin , Ting Zhi , Kang Chen , Junan Pan , Yingbo Zhang , Jingwen Li , Longlu Wang . Advanced development of grain boundaries in TMDs from fundamentals to hydrogen evolution application. Chinese Chemical Letters, 2024, 35(5): 108628-. doi: 10.1016/j.cclet.2023.108628
14. [14]
  Tianhao Li , Wenguang Tu , Zhigang Zou . In situ photocatalytically enhanced thermogalvanic cells for electricity and hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(1): 100195-100195. doi: 10.1016/j.cjsc.2023.100195
15. [15]
  Zhipeng Wan , Hao Xu , Peng Wu . Selective oxidation using in-situ generated hydrogen peroxide over titanosilicates. Chinese Journal of Structural Chemistry, 2024, 43(6): 100298-100298. doi: 10.1016/j.cjsc.2024.100298
16. [16]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
17. [17]
  Xiangyuan Zhao , Jinjin Wang , Jinzhao Kang , Xiaomei Wang , Hong Yu , Cheng-Feng Du . Ni nanoparticles anchoring on vacuum treated Mo2TiC2Tx MXene for enhanced hydrogen evolution activity. Chinese Journal of Structural Chemistry, 2023, 42(10): 100159-100159. doi: 10.1016/j.cjsc.2023.100159
18. [18]
  Chunru Liu , Ligang Feng . Advances in anode catalysts of methanol-assisted water-splitting reactions for hydrogen generation. Chinese Journal of Structural Chemistry, 2023, 42(10): 100136-100136. doi: 10.1016/j.cjsc.2023.100136
19. [19]
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20. [20]
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Thermal pyrolysis conversion of methane to hydrogen (H2): A review on process parameters, reaction kinetics and techno-economic analysis

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通讯作者: 陈斌, bchen63@163.com

Thermal pyrolysis conversion of methane to hydrogen (H₂): A review on process parameters, reaction kinetics and techno-economic analysis