Citation: Yuchen Wang, Yaoyu Liu, Xiongfei Huang, Guanjie He, Kai Yan. Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor[J]. Chinese Chemical Letters, ;2024, 35(8): 109301. doi: 10.1016/j.cclet.2023.109301 shu

Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor

Yuchen Wang ^{a, b} ,
Yaoyu Liu ^a ,
Xiongfei Huang ^a ,
Guanjie He ^{c, *,} ,
Kai Yan ^{a, *,}

a.
Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China
b.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China
c.
Electrochemical Innovation Lab, Department of Chemical Engineering, University College London, London, WC1E 7JE, United Kingdom

g.he@ucl.ac.uk

yank9@mail.sysu.edu.cn

Received Date: 6 August 2023
Revised Date: 25 October 2023
Accepted Date: 11 November 2023
Available Online: 15 November 2023

Figures(4)

Metal-nanocluster materials have gradually become a promising electrode candidate for supercapacitor application. The high-efficient and rational architecture of these metal-nanocluster electrode materials with satisfied supercapacitive performance are full of challenges. Herein, Fe-nanocluster anchored porous carbon (FAPC) nanosheets were constructed through a facile and low-cost impregnation-activation strategy. Various characterization methods documented that FAPC nanosheets possessed a mesopore-dominated structure with large surface area and abundant Fe-N₄ active sites, which are crucial for supercapacitive energy storage. The optimal FAPC electrode exhibited a high specific capacitance of 378 F/g at a specific current of 1 A/g and an excellent rate capability (271 F/g at 10 A/g), which are comparable or even superior to that of most reported carbon candidates. Furthermore, the FAPC-based device achieved a desired specific energy of 14.8 Wh/kg at a specific power of 700 W/kg. This work opens a new avenue to design metal-nanocluster materials for high-performance biomass waste-based supercapacitors.
- Fe nanoclusters,
- Biomass waste,
- Porous carbon nanosheets,
- Supercapacitor,
- Charge transfer
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