Citation: Yuchen Wang, Yaoyu Liu, Xiongfei Huang, Guanjie He, Kai Yan. Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor[J]. Chinese Chemical Letters, ;2024, 35(8): 109301. doi: 10.1016/j.cclet.2023.109301 shu

Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor

Yuchen Wang ^{a, b} ,
Yaoyu Liu ^a ,
Xiongfei Huang ^a ,
Guanjie He ^{c, *,} ,
Kai Yan ^{a, *,}

a.
Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China
b.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China
c.
Electrochemical Innovation Lab, Department of Chemical Engineering, University College London, London, WC1E 7JE, United Kingdom

g.he@ucl.ac.uk

yank9@mail.sysu.edu.cn

Received Date: 6 August 2023
Revised Date: 25 October 2023
Accepted Date: 11 November 2023
Available Online: 15 November 2023

Figures(4)

Metal-nanocluster materials have gradually become a promising electrode candidate for supercapacitor application. The high-efficient and rational architecture of these metal-nanocluster electrode materials with satisfied supercapacitive performance are full of challenges. Herein, Fe-nanocluster anchored porous carbon (FAPC) nanosheets were constructed through a facile and low-cost impregnation-activation strategy. Various characterization methods documented that FAPC nanosheets possessed a mesopore-dominated structure with large surface area and abundant Fe-N₄ active sites, which are crucial for supercapacitive energy storage. The optimal FAPC electrode exhibited a high specific capacitance of 378 F/g at a specific current of 1 A/g and an excellent rate capability (271 F/g at 10 A/g), which are comparable or even superior to that of most reported carbon candidates. Furthermore, the FAPC-based device achieved a desired specific energy of 14.8 Wh/kg at a specific power of 700 W/kg. This work opens a new avenue to design metal-nanocluster materials for high-performance biomass waste-based supercapacitors.
- Fe nanoclusters,
- Biomass waste,
- Porous carbon nanosheets,
- Supercapacitor,
- Charge transfer
1. [1]
  H. Tao, Q. Fan, T. Ma, et al., Prog. Mater. Sci. 111 (2020) 100637. doi: 10.1016/j.pmatsci.2020.100637
2. [2]
  A.C. Forse, C. Merlet, J.M. Griffin, C.P. Grey, J. Am. Chem. Soc. 138 (2016) 5731–5744. doi: 10.1021/jacs.6b02115
3. [3]
  M. Salanne, B. Rotenberg, K. Naoi, et al., Nat. Energy 1 (2016) 16070. doi: 10.1038/nenergy.2016.70
4. [4]
  S. Li, Z. Yang, M. Wu, et al., Energy Environ. Mater. 5 (2022) 1238–1250. doi: 10.1002/eem2.12240
5. [5]
  C.C. Chen, J. Maier, Nat. Energy 3 (2018) 102–108. doi: 10.1038/s41560-017-0084-x
6. [6]
  L. Zhang, D. Shi, T. Liu, et al., Mater. Today 25 (2019) 35–65. doi: 10.1016/j.mattod.2018.11.002
7. [7]
  M. Papac, V. Stevanović, A. Zakutayev, R. O'Hayre, Nat. Mater. 20 (2021) 301–313. doi: 10.1038/s41563-020-00854-8
8. [8]
  A.G. Kelly, D. O'Suilleabhain, C. Gabbett, J.N. Coleman, Nat. Rev. Mater. 7 (2022) 217–234.
9. [9]
  L. Liu, A. Corma, Chem. Rev. 118 (2018) 4981–5079. doi: 10.1021/acs.chemrev.7b00776
10. [10]
  Y. Wang, Y. Qu, B. Qu, et al., Adv. Mater. 33 (2021) 2105482. doi: 10.1002/adma.202105482
11. [11]
  L. Zhao, J. Bian, X. Zhang, et al., Adv. Mater. 34 (2022) 2205303. doi: 10.1002/adma.202205303
12. [12]
  C. Zhai, Y. Chen, X. Huang, et al., Environ. Funct. Mater. 1 (2022) 219–229.
13. [13]
  A.Y. Zha, Q.B. Zha, Z. Li, et al., Rare Met. 42 (2023) 1274–1282. doi: 10.1007/s12598-022-02172-1
14. [14]
  Z. Chen, S. Mitchell, E. Vorobyeva, et al., Adv. Funct. Mater. 27 (2017) 1605785. doi: 10.1002/adfm.201605785
15. [15]
  Y. Peng, B. Lu, S. Chen, Adv. Mater. 30 (2018) 1801995. doi: 10.1002/adma.201801995
16. [16]
  A. Han, B. Wang, A. Kumar, et al., Small Methods 3 (2019) 1800471. doi: 10.1002/smtd.201800471
17. [17]
  P. Wang, D. Zhao, L. Yin, Energy Environ. Sci. 14 (2021) 1794–1834. doi: 10.1039/D0EE02651D
18. [18]
  S. Joseph, J.M. Lee, M.R. Benzigar, et al., Carbon 180 (2021) 101–109. doi: 10.1016/j.carbon.2021.05.006
19. [19]
  X. Hong, S. Li, R. Wang, J. Fu, J. Alloys Compd. 775 (2019) 15–21. doi: 10.1016/j.jallcom.2018.10.099
20. [20]
  P. Yin, X. Luo, Y. Ma, et al., Nat. Commun. 12 (2021) 3135. doi: 10.1038/s41467-021-23426-z
21. [21]
  J.C. Li, Z.Q. Yang, D.M. Tang, et al., NPG Asia Mater. 10 (2018) e461-e461. doi: 10.1038/am.2017.212
22. [22]
  Y. Wang, Z. Chen, M. Zhang, et al., Green Energy Environ. 7 (2022) 1053–1061. doi: 10.1016/j.gee.2021.01.019
23. [23]
  Y. Wang, Y. Liu, A. Ejaz, K. Yan, Chin. Chem. Lett. 34 (2023) 107538. doi: 10.1016/j.cclet.2022.05.052
24. [24]
  J. Deng, T. Xiong, F. Xu, et al., Green Chem. 17 (2015) 4053–4060. doi: 10.1039/C5GC00523J
25. [25]
  H. Yang, X. Chen, W.T. Chen, et al., ACS Nano 13 (2019) 8087–8098. doi: 10.1021/acsnano.9b02930
26. [26]
  Y. Liu, B. Huang, X. Zhang, et al., J. Power Sources 412 (2019) 125–133. doi: 10.1016/j.jpowsour.2018.11.024
27. [27]
  H. Peng, B. Yao, X. Wei, et al., Adv. Energy Mater. 9 (2019) 1803665. doi: 10.1002/aenm.201803665
28. [28]
  J. Guo, J. Xu, X. Xiao, et al., Green Chem. 24 (2022) 8827–8839. doi: 10.1039/D2GC03100K
29. [29]
  L. Borchardt, M. Oschatz, S. Kaskel, Mater. Horiz. 1 (2014) 157–168. doi: 10.1039/C3MH00112A
30. [30]
  M. Liu, J. Lee, T.C. Yang, et al., Small Methods 5 (2021) 2001165. doi: 10.1002/smtd.202001165
31. [31]
  K.A. Owusu, L. Qu, J. Li, et al., Nat. Commun. 8 (2017) 14264. doi: 10.1038/ncomms14264
32. [32]
  Y. Wang, Y. Liu, M. Zhang, et al., Sci. China Mater. 65 (2022) 1805–1813. doi: 10.1007/s40843-021-1978-3
33. [33]
  V. Augustyn, P. Simon, B. Dunn, Energy Environ. Sci. 7 (2014) 1597–1614. doi: 10.1039/c3ee44164d
34. [34]
  C. Leng, Z. Zhao, Y. Song, et al., Nano-Micro Lett. 13 (2021) 8. doi: 10.1007/s40820-020-00535-w
35. [35]
  L. Guan, L. Pan, T. Peng, et al., ACS Sustain. Chem. Eng. 7 (2019) 8405–8412. doi: 10.1021/acssuschemeng.9b00050
36. [36]
  X. Bo, K. Xiang, Y. Zhang, et al., J. Energy Chem. 39 (2019) 1–7. doi: 10.1016/j.jechem.2019.01.006
37. [37]
  J. Li, Y. Zou, C. Xiang, et al., J. Energy Storage 42 (2021) 103017. doi: 10.1016/j.est.2021.103017
38. [38]
  M. Li, H. Xiao, T. Zhang, et al., ACS Sustain. Chem. Eng. 7 (2019) 4716–4723. doi: 10.1021/acssuschemeng.8b04607
1. [1]
  Zixuan Guo , Xiaoshuai Han , Chunmei Zhang , Shuijian He , Kunming Liu , Jiapeng Hu , Weisen Yang , Shaoju Jian , Shaohua Jiang , Gaigai Duan . Activation of biomass-derived porous carbon for supercapacitors: A review. Chinese Chemical Letters, 2024, 35(7): 109007-. doi: 10.1016/j.cclet.2023.109007
2. [2]
  Shu-Ran Xu , Fang-Xing Xiao . Metal halide perovskites quantum dots: Synthesis, and modification strategies for solar CO2 conversion. Chinese Journal of Structural Chemistry, 2023, 42(12): 100173-100173. doi: 10.1016/j.cjsc.2023.100173
3. [3]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
4. [4]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
5. [5]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
6. [6]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
7. [7]
  Jun-Ming Cao , Kai-Yang Zhang , Jia-Lin Yang , Zhen-Yi Gu , Xing-Long Wu . Differential bonding behaviors of sodium/potassium-ion storage in sawdust waste carbon derivatives. Chinese Chemical Letters, 2024, 35(4): 109304-. doi: 10.1016/j.cclet.2023.109304
8. [8]
  Jieqiong Xu , Wenbin Chen , Shengkai Li , Qian Chen , Tao Wang , Yadong Shi , Shengyong Deng , Mingde Li , Peifa Wei , Zhuo Chen . Organic stoichiometric cocrystals with a subtle balance of charge-transfer degree and molecular stacking towards high-efficiency NIR photothermal conversion. Chinese Chemical Letters, 2024, 35(10): 109808-. doi: 10.1016/j.cclet.2024.109808
9. [9]
  Xinyu Huai , Jingxuan Liu , Xiang Wu . Cobalt-Doped NiMoO4 Nanosheet for High-performance Flexible Supercapacitor. Chinese Journal of Structural Chemistry, 2023, 42(10): 100158-100158. doi: 10.1016/j.cjsc.2023.100158
10. [10]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
11. [11]
  Xuexia Lin , Yihui Zhou , Jiafu Hong , Xiaofeng Wei , Bin Liu , Chong-Chen Wang . Facile preparation of ZIF-8/ZIF-67-derived biomass carbon composites for highly efficient electromagnetic wave absorption. Chinese Chemical Letters, 2024, 35(9): 109835-. doi: 10.1016/j.cclet.2024.109835
12. [12]
  Huizhong Wu , Ruiheng Liang , Ge Song , Zhongzheng Hu , Xuyang Zhang , Minghua Zhou . Enhanced interfacial charge transfer on Bi metal@defective Bi₂Sn₂O₇ quantum dots towards improved full-spectrum photocatalysis: A combined experimental and theoretical investigation. Chinese Chemical Letters, 2024, 35(6): 109131-. doi: 10.1016/j.cclet.2023.109131
13. [13]
  Ying Hou , Zhen Liu , Xiaoyan Liu , Zhiwei Sun , Zenan Wang , Hong Liu , Weijia Zhou . Laser constructed vacancy-rich TiO_2-x/Ti microfiber via enhanced interfacial charge transfer for operando extraction-SERS sensing. Chinese Chemical Letters, 2024, 35(9): 109634-. doi: 10.1016/j.cclet.2024.109634
14. [14]
  Hui Liu , Xiangyang Tang , Zhuang Cheng , Yin Hu , Yan Yan , Yangze Xu , Zihan Su , Futong Liu , Ping Lu . Constructing multifunctional deep-blue emitters with weak charge transfer excited state for high-performance non-doped blue OLEDs and single-emissive-layer hybrid white OLEDs. Chinese Chemical Letters, 2024, 35(10): 109809-. doi: 10.1016/j.cclet.2024.109809
15. [15]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
16. [16]
  Qiang Zhang , Weiran Gong , Huinan Che , Bin Liu , Yanhui Ao . S doping induces to promoted spatial separation of charge carriers on carbon nitride for efficiently photocatalytic degradation of atrazine. Chinese Journal of Structural Chemistry, 2023, 42(12): 100205-100205. doi: 10.1016/j.cjsc.2023.100205
17. [17]
  Uttam Pandurang Patil . Porous carbon catalysis in sustainable synthesis of functional heterocycles: An overview. Chinese Chemical Letters, 2024, 35(8): 109472-. doi: 10.1016/j.cclet.2023.109472
18. [18]
  Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632
19. [19]
  Binyang Qin , Mengqi Wang , Shimei Wu , Yining Li , Chilin Liu , Yufei Zhang , Haosen Fan . Carbon dots confined nanosheets assembled NiCo₂S₄@CDs cross-stacked architecture for enhanced sodium ion storage. Chinese Chemical Letters, 2024, 35(7): 108921-. doi: 10.1016/j.cclet.2023.108921
20. [20]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(267)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142