Citation: Zhenchun Yang, Bixiao Guo, Zhenyu Hu, Kun Wang, Jiahao Cui, Lina Li, Chun Hu, Yubao Zhao. Molecular engineering towards dual surface local polarization sites on poly(heptazine imide) framework for boosting H₂O₂ photo-production[J]. Chinese Chemical Letters, ;2024, 35(8): 109251. doi: 10.1016/j.cclet.2023.109251 shu

Molecular engineering towards dual surface local polarization sites on poly(heptazine imide) framework for boosting H₂O₂ photo-production

Zhenchun Yang ^a ,
Bixiao Guo ^b ,
Zhenyu Hu ^a ,
Kun Wang ^a ,
Jiahao Cui ^a ,
Lina Li ^a ,
Chun Hu ^a ,
Yubao Zhao ^{a, *,}

a.
Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Institute of Environmental Research at Greater Bay, Guangzhou University, Guangzhou 510006, China
b.
Department of Environmental Science and Engineering, Guangzhou University, Guangzhou 510006, China

ybzhao@gzhu.edu.cn

Received Date: 7 July 2023
Revised Date: 7 October 2023
Accepted Date: 26 October 2023
Available Online: 2 November 2023

Figures(4)

The selective 2e⁻ ORR reaction on polymeric carbon nitride framework is one of the most promising approaches for solar-driven hydrogen peroxide production. Poly(heptazine imide) (PHI) as a class of K⁺-incorporated crystalline carbon nitride framework, is highly active for photocatalytic H₂O₂ production. An upgrade on the H₂O₂ photoproduction performance of PHI is realized and the mechanistic insights are revealed in this work. By photochemical reaction, the electron withdrawing groups of hydroxyl group and cyano group are grafted on the surface of PHI frameworks. The dual polarization sites on the surface contribute significantly to the enhancement of the exciton dissociation. The optimized PHI with dual polarization sites exhibits a remarkable photocatalytic H₂O₂ production performance, which is 2 times of the active pristine PHI. Most importantly, the photochemical reaction method is generally applicable to improve the exciton dissociation of a wide range of polymeric carbon nitride frameworks with various structure and compositions; and the thiourea-derived polymeric carbon nitride framework with dual surface polarization sites exhibits a remarkable photocatalytic performance with a high H₂O₂ production rate of 40.5 mmol h⁻¹ g⁻¹.
- Photocatalysis,
- Hydrogen peroxide production,
- Carbon nitride framework,
- Surface functionalization,
- ORR
1. [1]
  C. Cao, X. Wang, N. Yang, et al., Chem. Sci. 13 (2022) 863–889. doi: 10.1039/D1SC05482A
2. [2]
  Y. Wen, F. Huo, C. Yin, Chin. Chem. Lett. 30 (2019) 1834–1842. doi: 10.1016/j.cclet.2019.07.006
3. [3]
  Y. Xue, Y. Wang, Z. Pan, et al., Angew. Chem. Int. Ed. 60 (2021) 10469–10480. doi: 10.1002/anie.202011215
4. [4]
  J.M. Campos-Martin, G. Blanco-Brieva, J.L. Fierro, Angew. Chem. Int. Ed. 45 (2006) 6962–6984. doi: 10.1002/anie.200503779
5. [5]
  C. Xia, Y. Xia, P. Zhu, et al., Science 366 (2019) 226–231. doi: 10.1126/science.aay1844
6. [6]
  X. Hu, X. Zeng, Y. Liu, et al., Nanoscale 12 (2020) 16008–16027. doi: 10.1039/D0NR03178J
7. [7]
  C. Huang, E. Fan, H. Xu, et al., Solid State Sci. 113 (2021) 106533. doi: 10.1016/j.solidstatesciences.2021.106533
8. [8]
  Y. Huang, Y. Jian, L. Li, et al., Angew. Chem. Int. Ed. 60 (2021) 5245–5249. doi: 10.1002/anie.202014317
9. [9]
  H. Wang, Y. Xu, D. Xu, et al., ACS EST Eng. 2 (2022) 140–157. doi: 10.1021/acsestengg.1c00337
10. [10]
  C. Zhao, Z. Chen, R. Shi, et al., Adv. Mater. 32 (2020) 1907296. doi: 10.1002/adma.201907296
11. [11]
  S. Zhang, Y. Yang, Y. Zhai, et al., Chin. Chem. Lett. 34 (2023) 107652. doi: 10.1016/j.cclet.2022.06.075
12. [12]
  X. Chen, W. Zhang, L. Zhang, et al., ACS Appl. Mater. Interfaces 13 (2021) 25868–25878. doi: 10.1021/acsami.1c02953
13. [13]
  H. Cheng, H. Lv, J. Cheng, et al., Adv. Mater. 34 (2022) 2107480. doi: 10.1002/adma.202107480
14. [14]
  K. Sahel, L. Elsellami, I. Mirali, et al., Appl. Catal. B 188 (2016) 106–112. doi: 10.1016/j.apcatb.2015.12.044
15. [15]
  J. Luo, C. Fan, L. Tang, et al., Appl. Catal. B 301 (2022) 120757. doi: 10.1016/j.apcatb.2021.120757
16. [16]
  V. Briega-Martos, A. Ferre-Vilaplana, A. de la Peña, et al., ACS Catal. 7 (2017) 1015–1024. doi: 10.1021/acscatal.6b03043
17. [17]
  H. Zhang, L.H. Guo, L. Zhao, et al., J. Phys. Chem. Lett. 6 (2015) 958–963. doi: 10.1021/acs.jpclett.5b00149
18. [18]
  Y. Kofuji, S. Ohkita, Y. Shiraishi, et al., ACS Sustain. Chem. Eng. 5 (2017) 6478–6485. doi: 10.1021/acssuschemeng.7b00575
19. [19]
  L. Li, L. Xu, Z. Hu, et al., Adv. Funct. Mater. 31 (2021) 2106120. doi: 10.1002/adfm.202106120
20. [20]
  F. Liu, R. Shi, Z. Wang, et al., Angew. Chem. Int. Ed. 58 (2019) 11791–11795. doi: 10.1002/anie.201906416
21. [21]
  Y. Shiraishi, T. Takii, T. Hagi, et al., Nat. Mater. 18 (2019) 985–993. doi: 10.1038/s41563-019-0398-0
22. [22]
  Q. Tian, L. Jing, S. Ye, et al., Small 17 (2021) e2103224. doi: 10.1002/smll.202103224
23. [23]
  L. Xu, Y. Liu, L. Li, et al., ACS Catal. 11 (2021) 14480–14488. doi: 10.1021/acscatal.1c03690
24. [24]
  C. Liu, T. Bao, L. Yuan, et al., Adv. Funct. Mater. 32 (2021) 2111404.
25. [25]
  L. Li, D. Cruz, A. Savateev, et al., Appl. Catal. B 229 (2018) 249–253. doi: 10.1016/j.apcatb.2018.01.065
26. [26]
  M. Li, Q. Zheng, D.P. Durkin, et al., J. Hazard. Mater. 436 (2022) 129251. doi: 10.1016/j.jhazmat.2022.129251
27. [27]
  X. Li, J. Zhang, Y. Huo, et al., Appl. Catal. B 280 (2021) 119452. doi: 10.1016/j.apcatb.2020.119452
28. [28]
  Y. Fu, C.A. Liu, M. Zhang, et al., Adv. Energy Mater. 8 (2018) 1802525. doi: 10.1002/aenm.201802525
29. [29]
  D. Li, C. Wen, J. Huang, et al., Appl. Catal. B 307 (2022) 121099. doi: 10.1016/j.apcatb.2022.121099
30. [30]
  K. Li, L. Bao, S. Cao, et al., ACS Appl. Energy Mater. 4 (2021) 12965–12973. doi: 10.1021/acsaem.1c02602
31. [31]
  L. Dai, A. Dong, X. Meng, et al., Angew. Chem. Int. Ed. 62 (2023) e202300224. doi: 10.1002/anie.202300224
32. [32]
  J. Yang, A. Acharjya, M.Y. Ye, et al., Angew. Chem. Int. Ed. 60 (2021) 19797–19803. doi: 10.1002/anie.202104870
33. [33]
  Q. Zhi, W. Liu, R. Jiang, et al., J. Am. Chem. Soc. 144 (2022) 21328–21336. doi: 10.1021/jacs.2c09482
34. [34]
  Y. Zhao, P. Zhang, Z. Yang, et al., Nat. Commun. 12 (2021) 3701. doi: 10.1038/s41467-021-24048-1
35. [35]
  Q. Wu, J. Cao, X. Wang, et al., Nat. Commun. 12 (2021) 483. doi: 10.1038/s41467-020-20823-8
36. [36]
  Z. Teng, Q. Zhang, H. Yang, et al., Nat. Catal. 4 (2021) 374–384. doi: 10.1038/s41929-021-00605-1
37. [37]
  F. Yu, L. Wang, Q. Xing, et al., Chin. Chem. Lett. 31 (2020) 1648–1653. doi: 10.1016/j.cclet.2019.08.020
38. [38]
  G. Zhang, G. Li, T. Heil, et al., Angew. Chem. Int. Ed. 131 (2019) 3471–3475. doi: 10.1002/ange.201811938
39. [39]
  A. Savateev, S. Pronkin, J.D. Epping, et al., ChemCatChem 9 (2017) 167–174. doi: 10.1002/cctc.201601165
40. [40]
  A. Savateev, S. Pronkin, M.G. Willinger, et al., Chem. Asian J. 12 (2017) 1517–1522. doi: 10.1002/asia.201700209
41. [41]
  Z. Yang, L. Li, J. Cui, et al., Chem. Eur. J. 28 (2022) e202202122. doi: 10.1002/chem.202202122
42. [42]
  Z. Yang, L. Li, J. Gao, et al., ACS EST Eng. 2 (2022) 2142–2149. doi: 10.1021/acsestengg.2c00178
43. [43]
  Z. Yang, L. Li, S. Zeng, et al., ACS Appl. Mater. Interfaces 15 (2023) 8232–8240. doi: 10.1021/acsami.2c22366
44. [44]
  C. Merschjann, S. Tschierlei, T. Tyborski, et al., Adv. Mater. 27 (2015) 7993–7999. doi: 10.1002/adma.201503448
45. [45]
  R. Chen, Z. Ren, Y. Liang, et al., Nature 610 (2022) 296–301. doi: 10.1038/s41586-022-05183-1
46. [46]
  S. Wu, H. Yu, S. Chen, et al., ACS Catal. 10 (2020) 14380–14389. doi: 10.1021/acscatal.0c03359
47. [47]
  J. Cheng, Y. Hou, K. Lian, et al., ACS Catal. 12 (2022) 1797–1808. doi: 10.1021/acscatal.1c05013
48. [48]
  K.C. Bedin, A.C. Martins, A.L. Cazetta, et al., Chem. Eng. J. 286 (2016) 476–484. doi: 10.1016/j.cej.2015.10.099
49. [49]
  L. Kong, J. Wang, Y. Jia, et al., J. Raman Spectrosc. 41 (2010) 989–995. doi: 10.1002/jrs.2536
50. [50]
  Z. Zhai, H. Zhang, F. Niu, et al., ACS Nano 16 (2022) 21002–21012. doi: 10.1021/acsnano.2c08643
51. [51]
  L. Du, Q. Tian, X. Zheng, et al., Energy Environ. Mater. 5 (2021) 912–917.
52. [52]
  G. Zhang, Y. Xu, M. Rauf, et al., Adv. Sci. 9 (2022) e2201677. doi: 10.1002/advs.202201677
53. [53]
  S. Gao, X. Wang, C. Song, et al., Appl. Catal. B 295 (2021) 120272. doi: 10.1016/j.apcatb.2021.120272
54. [54]
  Z. Fang, Y. Bai, L. Li, et al., Nano Energy 75 (2020) 104865. doi: 10.1016/j.nanoen.2020.104865
55. [55]
  W. Ren, J. Cheng, H. Ou, et al., J. Catal. 389 (2020) 636–645. doi: 10.1016/j.jcat.2020.07.005
56. [56]
  L.L. Liu, F. Chen, J.H. Wu, et al., P. Natl. Acad. Sci. U. S. A. 120 (2023) e2215305120. doi: 10.1073/pnas.2215305120
57. [57]
  X. He, H. Shang, C. Wang, et al., Chin. Chem. Lett. 32 (2021) 3377–3381. doi: 10.1016/j.cclet.2021.04.028
58. [58]
  R.R. Pawar, Lalhmunsiama, M. Kim, et al., Appl. Clay Sci. 162 (2018) 339–350. doi: 10.1016/j.clay.2018.06.014
59. [59]
  S. Yu, J. Li, Y. Zhang, et al., Nano Energy 50 (2018) 383–392. doi: 10.1016/j.nanoen.2018.05.053
60. [60]
  J. Moan, E. Wold, Nature 279 (1979) 450–451. doi: 10.1038/279450a0
61. [61]
  S. Trasatti, Pure Appl. Chem. 58 (1986) 955–966. doi: 10.1351/pac198658070955
62. [62]
  H. Yu, R. Shi, Y. Zhao, et al., Adv. Mater. 29 (2017) 1605148. doi: 10.1002/adma.201605148
63. [63]
  M.O. Eze, L.C. Nnamani, R.I. Ojiako, et al., Free Rad. Res. Cornms. 4 (1987) 105–108.
64. [64]
  R. Palominos, J. Freer, M.A. Mondaca, et al., J. Photoch. Photobio. A 193 (2008) 139–145. doi: 10.1016/j.jphotochem.2007.06.017
65. [65]
  J. Luo, Y. Liu, C. Fan, et al., ACS Catal. 11 (2021) 11440–11450. doi: 10.1021/acscatal.1c03103
1. [1]
  Zhenyu Hu , Zhenchun Yang , Shiqi Zeng , Kun Wang , Lina Li , Chun Hu , Yubao Zhao . Cationic surface polarization centers on ionic carbon nitride for efficient solar-driven H₂O₂ production and pollutant abatement. Chinese Chemical Letters, 2024, 35(10): 109526-. doi: 10.1016/j.cclet.2024.109526
2. [2]
  Tianhao Li , Wenguang Tu , Zhigang Zou . In situ photocatalytically enhanced thermogalvanic cells for electricity and hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(1): 100195-100195. doi: 10.1016/j.cjsc.2023.100195
3. [3]
  Qiang Zhang , Weiran Gong , Huinan Che , Bin Liu , Yanhui Ao . S doping induces to promoted spatial separation of charge carriers on carbon nitride for efficiently photocatalytic degradation of atrazine. Chinese Journal of Structural Chemistry, 2023, 42(12): 100205-100205. doi: 10.1016/j.cjsc.2023.100205
4. [4]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
5. [5]
  Zhen Shi , Wei Jin , Yuhang Sun , Xu Li , Liang Mao , Xiaoyan Cai , Zaizhu Lou . Interface charge separation in Cu2CoSnS4/ZnIn2S4 heterojunction for boosting photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100201-100201. doi: 10.1016/j.cjsc.2023.100201
6. [6]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
7. [7]
  Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632
8. [8]
  Fabrice Nelly Habarugira , Ducheng Yao , Wei Miao , Chengcheng Chu , Zhong Chen , Shun Mao . Synergy of sodium doping and nitrogen defects in carbon nitride for promoted photocatalytic synthesis of hydrogen peroxide. Chinese Chemical Letters, 2024, 35(8): 109886-. doi: 10.1016/j.cclet.2024.109886
9. [9]
  Wengao Zeng , Yuchen Dong , Xiaoyuan Ye , Ziying Zhang , Tuo Zhang , Xiangjiu Guan , Liejin Guo . Crystalline carbon nitride with in-plane built-in electric field accelerates carrier separation for excellent photocatalytic hydrogen evolution. Chinese Chemical Letters, 2024, 35(4): 109252-. doi: 10.1016/j.cclet.2023.109252
10. [10]
  Mengjun Zhao , Yuhao Guo , Na Li , Tingjiang Yan . Deciphering the structural evolution and real active ingredients of iron oxides in photocatalytic CO2 hydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100348-100348. doi: 10.1016/j.cjsc.2024.100348
11. [11]
  Deqi Fan , Yicheng Tang , Yemei Liao , Yan Mi , Yi Lu , Xiaofei Yang . Two birds with one stone: Functionalized wood composites for efficient photocatalytic hydrogen production and solar water evaporation. Chinese Chemical Letters, 2024, 35(9): 109441-. doi: 10.1016/j.cclet.2023.109441
12. [12]
  Jing Wang , Zenghui Li , Xiaoyang Liu , Bochao Su , Honghong Gong , Chao Feng , Guoping Li , Gang He , Bin Rao . Fine-tuning redox ability of arylene-bridged bis(benzimidazolium) for electrochromism and visible-light photocatalysis. Chinese Chemical Letters, 2024, 35(9): 109473-. doi: 10.1016/j.cclet.2023.109473
13. [13]
  Xiao-Ya Yuan , Cong-Cong Wang , Bing Yu . Recent advances in FeCl₃-photocatalyzed organic reactions via hydrogen-atom transfer. Chinese Chemical Letters, 2024, 35(9): 109517-. doi: 10.1016/j.cclet.2024.109517
14. [14]
  Rongxin Zhu , Shengsheng Yu , Xuanzong Yang , Ruyu Zhu , Hui Liu , Kaikai Niu , Lingbao Xing . Construction of pyrene-based hydrogen-bonded organic frameworks as photocatalysts for photooxidation of styrene in water. Chinese Chemical Letters, 2024, 35(10): 109539-. doi: 10.1016/j.cclet.2024.109539
15. [15]
  Zongyi Huang , Cheng Guo , Quanxing Zheng , Hongliang Lu , Pengfei Ma , Zhengzhong Fang , Pengfei Sun , Xiaodong Yi , Zhou Chen . Efficient photocatalytic biomass-alcohol conversion with simultaneous hydrogen evolution over ultrathin 2D NiS/Ni-CdS photocatalyst. Chinese Chemical Letters, 2024, 35(7): 109580-. doi: 10.1016/j.cclet.2024.109580
16. [16]
  Meijuan Chen , Liyun Zhao , Xianjin Shi , Wei Wang , Yu Huang , Lijuan Fu , Lijun Ma . Synthesis of carbon quantum dots decorating Bi₂MoO₆ microspherical heterostructure and its efficient photocatalytic degradation of antibiotic norfloxacin. Chinese Chemical Letters, 2024, 35(8): 109336-. doi: 10.1016/j.cclet.2023.109336
17. [17]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
18. [18]
  Lihua Ma , Song Guo , Zhi-Ming Zhang , Jin-Zhong Wang , Tong-Bu Lu , Xian-Shun Zeng . Sensitizing photoactive metal–organic frameworks via chromophore for significantly boosting photosynthesis. Chinese Chemical Letters, 2024, 35(5): 108661-. doi: 10.1016/j.cclet.2023.108661
19. [19]
  Jing-Jing Zhang , Lujun Lou , Rui Lv , Jiahui Chen , Yinlong Li , Guangwei Wu , Lingchao Cai , Steven H. Liang , Zhen Chen . Recent advances in photochemistry for positron emission tomography imaging. Chinese Chemical Letters, 2024, 35(8): 109342-. doi: 10.1016/j.cclet.2023.109342
20. [20]
  Hao Deng , Yuxin Hui , Chao Zhang , Qi Zhou , Qiang Li , Hao Du , Derek Hao , Guoxiang Yang , Qi Wang . MXene−derived quantum dots based photocatalysts: Synthesis, application, prospects, and challenges. Chinese Chemical Letters, 2024, 35(6): 109078-. doi: 10.1016/j.cclet.2023.109078

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(265)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Molecular engineering towards dual surface local polarization sites on poly(heptazine imide) framework for boosting H2O2 photo-production

Metrics

通讯作者: 陈斌, bchen63@163.com

Molecular engineering towards dual surface local polarization sites on poly(heptazine imide) framework for boosting H₂O₂ photo-production