Citation: Tong Su, Yue Wang, Qizhen Zhu, Mengyao Xu, Ning Qiao, Bin Xu. Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage[J]. Chinese Chemical Letters, ;2024, 35(8): 109191. doi: 10.1016/j.cclet.2023.109191 shu

Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage

State Key Laboratory of Organic-Inorganic Composites, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, China

zhuqz@mail.buct.edu.cn

qiaoning@buct.edu.cn

xubin@mail.buct.edu.cn

Received Date: 20 August 2023
Revised Date: 15 September 2023
Accepted Date: 6 October 2023
Available Online: 13 October 2023

Figures(5)

KTi₂(PO₄)₃ is a promising anode material for potassium storage, but suffers from low conductivity and difficult balance between high capacity and good structural stability. Herein, the Ti₃C₂T MXene is used as a multifunctional binder to fabricate the KTi₂(PO₄)₃ electrode by the traditional homogenizing-coating method. The MXene nanosheets, together with the conductive agent super P nanoparticles, construct a multiple conductive network for fast electron/ion transfer and high electrochemical kinetics. Moreover, the network ensures the structural stability of the KTi₂(PO₄)₃ electrode during the de-intercalation/intercalation of 4 K⁺ ions, which is beneficial for simultaneously achieving high capacity and good cycle performance. Therefore, the MXene-bonded KTi₂(PO₄)₃ electrode delivers a reversible capacity of 255.2 mAh/g at 50 mA/g, outstanding rate capability with 132.3 mAh/g at 2 A/g, and excellent cycle performance with 151.6 mAh/g at 1 A/g after 2000 cycles. This work not only suggests a high-performance anode material for potassium-ion batteries, but also demonstrates that the MXene is a promising binder material for constructing conductive electrodes in rechargeable batteries.
- MXene,
- Ti₃C₂T,
- KTi₂(PO₄)₃,
- Anode,
- Conductive network,
- Potassium storage
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Multiple conductive network for KTi2(PO4)3 anode based on MXene as a binder for high-performance potassium storage

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通讯作者: 陈斌, bchen63@163.com

Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage