Citation: Hengying Xiang, Nanping Deng, Lu Gao, Wen Yu, Bowen Cheng, Weimin Kang. 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery[J]. Chinese Chemical Letters, ;2024, 35(8): 109182. doi: 10.1016/j.cclet.2023.109182 shu

3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery

Hengying Xiang ^{a, b} ,
Nanping Deng ^{a, b, *,} ,
Lu Gao ^{a, b} ,
Wen Yu ^{a, b} ,
Bowen Cheng ^{a, b, *,} ,
Weimin Kang ^{a, b, *,}

a.
State Key Laboratory of Separation Membranes and Membrane Processes, Tiangong University, Tianjin 300387, China
b.
School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China

dengnanping@tiangong.edu.cn

bowen15@tiangong.edu.cn

kweimin@126.com

Received Date: 25 August 2023
Revised Date: 17 September 2023
Accepted Date: 6 October 2023
Available Online: 11 October 2023

Figures(5)

Satisfactory ionic conductivity, excellent mechanical stability, and high-temperature resistance are the prerequisites for the safe application of solid polymer electrolytes (SPEs) in all-solid-state lithium metal batteries (ASSLMBs). In this study, a novel poly(m-phenylene isophthalamide) (PMIA)-core/poly(ethylene oxide) (PEO)-shell nanofiber membrane and the functional Li_6.4La₃Zr_1.4Ta_0.6O₁₂ (LLZTO) ceramic nanoparticle are simultaneously introduced into the PEO-based SPEs to prepare composite polymer electrolytes (CPEs). The core PMIA layer of composite nanofibers can greatly improve the mechanical strength and thermal stability of the CPEs, while the shell PEO layer can provide the 3D continuous transport channels for lithium ions. In addition, the introduction of functional LLZTO nanoparticle not only reduces the crystallinity of PEO, but also promotes the dissociation of lithium salts and releases more Li⁺ ions through its interaction with the Lewis acid-base of anions, thereby overall improving the transport of lithium ions. Consequently, the optimized CPEs present high ionic conductivity of 1.38×10⁻⁴ S/cm at 30 ℃, significantly improved mechanical strength (8.5 MPa), remarkable thermal stability (without obvious shrinkage at 150 ℃), and conspicuous Li dendrites blocking ability (> 1800 h). The CPEs also both have good compatibility and cyclic stability with LiFePO₄ (> 2000 cycles) and high-voltage LiNi_0.8Mn_0.1Co_0.1O₂ (NMC811) (> 500 cycles) cathodes. In addition, even at low temperature (40 ℃), the assembled LiFePO₄/CPEs/Li battery still can cycle stably. The novel design can provide an effective way to exploit high-performance solid-state electrolytes.
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