Citation: Shuang Li, Jiayu Sun, Guocheng Liu, Shuo Zhang, Zhong Zhang, Xiuli Wang. A new Keggin-type polyoxometallate-based bifunctional catalyst for trace detection and pH-universal photodegradation of phenol[J]. Chinese Chemical Letters, ;2024, 35(8): 109148. doi: 10.1016/j.cclet.2023.109148 shu

A new Keggin-type polyoxometallate-based bifunctional catalyst for trace detection and pH-universal photodegradation of phenol

College of Chemistry and Materials Engineering, Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell, Bohai University, Jinzhou 121013, China

lgch1004@sina.com

zhangzhong666@126.com

wangxiuli@bhu.edu.cn

Received Date: 17 August 2023
Revised Date: 8 September 2023
Accepted Date: 25 September 2023
Available Online: 21 November 2023

Figures(10)

The widespread application of phenolic substances in the field of food, medicine and industry, is harmful to the environment and human health. Therefore, it is very important to develop a convenient and effective method to detect and degrade phenolic compounds. Herein, we report a new keggin-type polyoxometallate-based metal-organic complex self-assembled under solvothermal condition, {[Cu(dap)(3-PA)]₄(SiW₁₂O₄₀)(H₂O)₂}·2H₂O (1, dap = 1,2-diaminopropane, 3-HPA = 3-pyridineacrylic acid). 1 shows an interesting 1D ladder-like structure. As a bifunctional catalyst, 1 can be employed as a colorimetric sensor toward phenol with the relatively low detection limit (LOD) of 0.36 µmol/L (S/N = 3) in the wide range (0.001–0.1 mmol/L). The title colorimetric sensor is applied to determine phenol in various water environment with good recoveries ranging from 95%–105%. In addition, 1 also exhibits excellent photocatalytic degradation toward phenol under visible light with the highest removal efficiency at 96% for 100 min and wide pH universality. The selectivity, stability and reliability of the detection of 1 towards phenol, as well as the detection for 4-chlorophenol, o-cresol, 4-nitrophenol and phloroglucinol were studied. Furthermore, the photocatalytic reaction kinetics and the mechanisms of photodegradation of phenol were also investigated in detail.
- POM-based metal-organic complex,
- Bifunctional catalyst,
- Phenolic colorimetric sensor,
- Low detection limit,
- pH-universal photocatalysis,
- Photodegraded phenol
1. [1]
  D.W. Li, Y. Cheng, H. Zuo, et al., J. Colloid. Interface. Sci. 603 (2021) 771–782. doi: 10.1016/j.jcis.2021.06.155
2. [2]
  S. Ray, S. Panjikar, R. Anand, ACS Sens. 2 (2017) 411–418. doi: 10.1021/acssensors.6b00843
3. [3]
  Y. Gong, X. Zhao, H. Zhang, et al., Appl. Catal. B 233 (2018) 35–45. doi: 10.1016/j.apcatb.2018.03.077
4. [4]
  X.H. Zhong, Y. Lu, F. Luo, et al., Chem. Eur. J. 24 (2018) 3045–3051. doi: 10.1002/chem.201705677
5. [5]
  W. Xu, Y.F. Zhang, X. Zhang, X.X. Xu, Q. Wang, J. Haz. Mat. 457 (2023) 131776. doi: 10.1016/j.jhazmat.2023.131776
6. [6]
  O.G. Sas, M. Castro, Á. Domínguez, B. González, Sep. Purif. Technol. 227 (2019) 115703. doi: 10.1016/j.seppur.2019.115703
7. [7]
  T. Dogan, E. Bayram, L. Uzun, S. Senel, A. Denizli, Inc. J. Appl. Polym. Sci. 132 (2015) 41981–41987. doi: 10.1002/app.41981
8. [8]
  Q. Wang, X.Y. Wang, H. Wei, Anal. Chem. 94 (2022) 10198–10205. doi: 10.1021/acs.analchem.2c01695
9. [9]
  Y. Wang, M.Z. Zhao, C. Hou, et al., J. Taiwan. Inst. Chem. E 102 (2019) 312–320. doi: 10.1016/j.jtice.2019.06.019
10. [10]
  N.N. Xing, Y.S. Lyu, J. Yang, et al., Environ. Sci. Nano 9 (2022) 2815–2826. doi: 10.1039/D2EN00322H
11. [11]
  S.Z. Huang, Q. Tang, K.N. Wei, et al., Anal. Chim. Acta 1233 (2022) 340504. doi: 10.1016/j.aca.2022.340504
12. [12]
  T. Song, C. Xie, Q. Che, P. Yang, J. Ind. Eng. Chem. 122 (2023) 415–425. doi: 10.1016/j.jiec.2023.02.041
13. [13]
  Y. Yuan, W.G. Pan, R.T. Guo, et al., Sep. Purif. Technol. 297 (2022) 121538. doi: 10.1016/j.seppur.2022.121538
14. [14]
  X. Chen, R.T. Guo, W.G. Pan, et al., Appl. Catal. B: Environ. 318 (2022) 121839. doi: 10.1016/j.apcatb.2022.121839
15. [15]
  C. Hou, L.H. Fu, Y. Wang, et al., Carbohyd. Polym. 273 (2021) 118548. doi: 10.1016/j.carbpol.2021.118548
16. [16]
  S.W. Wu, D.Z. Guo, X.C. Xua, J.M. Pan, X.H. Niu, Sensor. Actuat. B: Chem. 303 (2020) 127225. doi: 10.1016/j.snb.2019.127225
17. [17]
  D. Zhang, W.Q. Zhang, Z.G. Lin, et al., Inorg. Chem. 59 (2020) 9756–9764. doi: 10.1021/acs.inorgchem.0c00976
18. [18]
  Z. Zhang, Y.L. Wang, Y. Liu, S.L. Huang, G.Y. Yang, Nanoscale 12 (2020) 18333–18341. doi: 10.1039/D0NR02945A
19. [19]
  L. Yang, Z. Zhang, C.N. Zhang, et al., Inorg. Chem. Front. 9 (2022) 4824–4833. doi: 10.1039/D2QI00838F
20. [20]
  X.T. Wang, W.J. Mao, D.S. Wang, et al., Talanta 257 (2023) 124270. doi: 10.1016/j.talanta.2023.124270
21. [21]
  B.X. Zeng, Y.Z. Li, G.P. Liu, et al., Inorg. Chem. 62 (2023) 10351–10358. doi: 10.1021/acs.inorgchem.3c01218
22. [22]
  R.D. Lai, Z.K. Zhu, Y.L. Wu, et al., Inorg. Chem. 61 (2022) 21047–21054. doi: 10.1021/acs.inorgchem.2c03576
23. [23]
  Y. Guan, H.P. Xiao, X.X. Li, S.T. Zheng, Polyoxometalates 2 (2023) 9140023. doi: 10.26599/POM.2023.9140023
24. [24]
  X.X. Li, C.H. Li, M.J. Hou, et al., Nat. Commun. 14 (2023) 5025. doi: 10.1038/s41467-023-40685-0
25. [25]
  S.R. Li, W.D. Liu, L.S. Long, L.S. Zheng, X.J. Kong, Polyoxometalates 2 (2023) 9140022. doi: 10.26599/POM.2023.9140022
26. [26]
  X.X. Li, T. Ji, J.Y. Gao, et al., Chem. Sci. 13 (2022) 4573–4580. doi: 10.1039/D1SC06779F
27. [27]
  J.C. Liu, J.F. Wang, Q. Han, et al., Angew. Chem. Int. Ed. 60 (2021) 11153–11157. doi: 10.1002/anie.202017318
28. [28]
  Q.Z. Wang, B.J. Xu, Y.Y. Wang, et al., Inorg. Chem. 60 (2021) 7753–7761. doi: 10.1021/acs.inorgchem.1c00135
29. [29]
  X.L. Wang, J.Y. Zhang, Z.H. Chang, et al., Inorg. Chem. 60 (2021) 3331–3337. doi: 10.1021/acs.inorgchem.0c03738
30. [30]
  D. Liu, B.K. Chen, J. Li, et al., Inorg. Chem. 60 (2021) 3909–3916. doi: 10.1021/acs.inorgchem.0c03698
31. [31]
  Y.N. Liu, J. Wang, L.N. Li, et al., Chem. Mater. 35 (2023) 3941–3950. doi: 10.1021/acs.chemmater.3c00120
32. [32]
  S.Z. Chang, H.Y. An, Y.H. Chen, et al., ACS. Sustain. Chem. Eng. 10 (2022) 4728–4740. doi: 10.1021/acssuschemeng.2c00351
33. [33]
  J.J. Xin, H.J. Pang, Z.X. Jin, et al., Inorg. Chem. 61 (2022) 16055–16063. doi: 10.1021/acs.inorgchem.2c02454
34. [34]
  Y. Lu, T. Zhang, Y.X. Zhang, et al., Dalton. Trans. 50 (2021) 15198–15209. doi: 10.1039/D1DT02644E
35. [35]
  Z.Y. Du, Z. Chen, R.K. Kang, et al., Inorg. Chem. 59 (2020) 12876–12883. doi: 10.1021/acs.inorgchem.0c01941
36. [36]
  I.D. Brown, D. Altermatt, Acta. Crystallogr. B 41 (1985) 244–247.
37. [37]
  Y. Hu, H.Y. An, X. Liu, et al., Dalton. Trans. 43 (2014) 2488–2498. doi: 10.1039/C3DT52987H
38. [38]
  R.J. Liu, X.K. Shang, C.X. Li, et al., Int. J. Hydrogen. Energ. 38 (2013) 9954–9960. doi: 10.1016/j.ijhydene.2013.06.009
39. [39]
  Y.J. Jang, V.K.H. Bui, P.T. Nguyen, Y.C. Lee, M.I. Kim, Chemosensors 9 (2021) 219–228. doi: 10.3390/chemosensors9080219
40. [40]
  T.S. Cheng, M.Z.M. Nasir, A. Appl. Mater. Today 9 (2017) 212–219. doi: 10.1016/j.apmt.2017.07.005
41. [41]
  A. Saeed, M. Umer, N. Yamasaki, et al., ChemElectroChem 7 (2020) 3943–3950. doi: 10.1002/celc.202000544
42. [42]
  S.R. Jia, X.K. Zhang, F. Yuan, T. Xia, ChemistrySelect 7 (2022) e202202984. doi: 10.1002/slct.202202984
43. [43]
  D.P. Li, Y.L. Tong, J. Huang, et al., J. Mol. Catal. A: Chem. 345 (2011) 108–116. doi: 10.1016/j.molcata.2011.06.002
44. [44]
  Y.H. Xiong, S.H. Chen, F.G. Ye, et al., Anal. Methods 7 (2015) 1300–1306. doi: 10.1039/C4AY02687J
45. [45]
  H.J. Liu, Y.J. Du, J. Gao, et al., Ind. Eng. Chem. Res. 59 (2020) 42–51. doi: 10.1021/acs.iecr.9b04391
46. [46]
  Z.W. Guo, L.H. Lin, J.P. Ye, et al., Angew. Chem. Int. Ed. 62 (2023) e202305260. doi: 10.1002/anie.202305260
47. [47]
  R.G. Yang, Y.M. Fu, X. Meng, et al., Inorg. Chem. Front. 10 (2023) 3699. doi: 10.1039/D3QI00217A
48. [48]
  F.L. Wang, Y.P. Feng, P. Chen, et al., Appl. Catal. B 227 (2018) 114–122. doi: 10.1016/j.apcatb.2018.01.024
49. [49]
  M.F. Atitar, A. Bouziani, R. Dillert, M. Azzouzib, D.W. Bahnemann, Catal. Sci. Technol. 8 (2018) 985–995. doi: 10.1039/C7CY01903C
50. [50]
  R. Farouq, J. Chin. Chem. Soc. 65 (2018) 1333–1339. doi: 10.1002/jccs.201800029
51. [51]
  Z.H. Wang, C.Z. Wang, C.W. Zhang, W.J. Li, Innov. Food. Sci. Emerg. 44 (2017) 224–234. doi: 10.1016/j.ifset.2017.02.013
52. [52]
  T.T. Cao, T.F. Xu, F.X. Deng, W.W. Qiao, C.W. Cui, J. Photoch. Photobio. A 407 (2021) 113025. doi: 10.1016/j.jphotochem.2020.113025
53. [53]
  E.F. Grosu, C. Gabriela, R. Froidevaux, Res. Chem. Intermediat. 44 (2018) 7731–7752. doi: 10.1007/s11164-018-3583-x
54. [54]
  L.H. Yuan, J. Chai, S.W. Wang, et al., Environ. Technol. Innov. 30 (2023) 103085. doi: 10.1016/j.eti.2023.103085
55. [55]
  K.F. Zhang, Y.X. Liu, J.G. Deng, et al., Appl. Catal. B: Environ. 224 (2018) 350–359. doi: 10.1016/j.apcatb.2017.10.044
1. [1]
  Yue Li , Minghao Fan , Conghui Wang , Yanxun Li , Xiang Yu , Jun Ding , Lei Yan , Lele Qiu , Yongcai Zhang , Longlu Wang . 3D layer-by-layer amorphous MoS_x assembled from [Mo₃S₁₃]^2- clusters for efficient removal of tetracycline: Synergy of adsorption and photo-assisted PMS activation. Chinese Chemical Letters, 2024, 35(9): 109764-. doi: 10.1016/j.cclet.2024.109764
2. [2]
  Xiangshuai Li , Jian Zhao , Li Luo , Zhuohao Jiao , Ying Shi , Shengli Hou , Bin Zhao . Visual and portable detection of metronidazole realized by metal-organic framework flexible sensor and smartphone scanning. Chinese Chemical Letters, 2024, 35(10): 109407-. doi: 10.1016/j.cclet.2023.109407
3. [3]
  Yuxin Wang , Zhengxuan Song , Yutao Liu , Yang Chen , Jinping Li , Libo Li , Jia Yao . Methyl functionalization of trimesic acid in copper-based metal-organic framework for ammonia colorimetric sensing at high relative humidity. Chinese Chemical Letters, 2024, 35(6): 108779-. doi: 10.1016/j.cclet.2023.108779
4. [4]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
5. [5]
  Guorong Li , Yijing Wu , Chao Zhong , Yixin Yang , Zian Lin . Predesigned covalent organic framework with sulfur coordination: Anchoring Au nanoparticles for sensitive colorimetric detection of Hg(Ⅱ). Chinese Chemical Letters, 2024, 35(5): 108904-. doi: 10.1016/j.cclet.2023.108904
6. [6]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
7. [7]
  Jie ZHANG , Xin LIU , Zhixin LI , Yuting PEI , Yuqi YANG , Huimin LI , Zhiqiang LIU . Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310
8. [8]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
9. [9]
  Haodong Wang , Xiaoxu Lai , Chi Chen , Pei Shi , Houzhao Wan , Hao Wang , Xingguang Chen , Dan Sun . Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108473-. doi: 10.1016/j.cclet.2023.108473
10. [10]
  Gengchen Guo , Tianyu Zhao , Ruichang Sun , Mingzhe Song , Hongyu Liu , Sen Wang , Jingwen Li , Jingbin Zeng . Au-Fe₃O₄ dumbbell-like nanoparticles based lateral flow immunoassay for colorimetric and photothermal dual-mode detection of SARS-CoV-2 spike protein. Chinese Chemical Letters, 2024, 35(6): 109198-. doi: 10.1016/j.cclet.2023.109198
11. [11]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141
12. [12]
  Xiaoyan Peng , Xuanhao Wu , Fan Yang , Yefei Tian , Mingming Zhang , Hongye Yuan . Gas sensors based on metal-organic frameworks: challenges and opportunities. Chinese Journal of Structural Chemistry, 2024, 43(3): 100251-100251. doi: 10.1016/j.cjsc.2024.100251
13. [13]
  Jia Chen , Yun Liu , Zerong Long , Yan Li , Hongdeng Qiu . Colorimetric detection of α-glucosidase activity using Ni-CeO₂ nanorods and its application to potential natural inhibitor screening. Chinese Chemical Letters, 2024, 35(9): 109463-. doi: 10.1016/j.cclet.2023.109463
14. [14]
  Xuying Yu , Jiarong Mi , Yulan Han , Cai Sun , Mingsheng Wang , Guocong Guo . A stable radiochromic semiconductive viologen-based metal–organic framework for dual-mode direct X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109233-. doi: 10.1016/j.cclet.2023.109233
15. [15]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
16. [16]
  Hualei Xu , Manman Han , Haiqiang Liu , Liang Qin , Lulu Chen , Hao Hu , Ran Wu , Chenyu Yang , Hua Guo , Jinrong Li , Jinxiang Fu , Qichen Hao , Yijun Zhou , Jinchao Feng , Xiaodong Wang . 4-Nitrocatechol as a novel matrix for low-molecular-weight compounds in situ detection and imaging in biological tissues by MALDI-MSI. Chinese Chemical Letters, 2024, 35(6): 109095-. doi: 10.1016/j.cclet.2023.109095
17. [17]
  Peng Wang , Daijie Deng , Suqin Wu , Li Xu . Cobalt-based deep eutectic solvent modified nitrogen-doped carbon catalyst for boosting oxygen reduction reaction in zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100199-100199. doi: 10.1016/j.cjsc.2023.100199
18. [18]
  Caixia Zhu , Qing Hong , Kaiyuan Wang , Yanfei Shen , Songqin Liu , Yuanjian Zhang . Single nanozyme-based colorimetric biosensor for dopamine with enhanced selectivity via reactivity of oxidation intermediates. Chinese Chemical Letters, 2024, 35(10): 109560-. doi: 10.1016/j.cclet.2024.109560
19. [19]
  Xiuwen Xu , Quan Zhou , Yacong Wang , Yunjie He , Qiang Wang , Yuan Wang , Bing Chen . Expanding the toolbox of metal-free organic halide perovskite for X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109272-. doi: 10.1016/j.cclet.2023.109272
20. [20]
  Ying Chen , Li Li , Junyao Zhang , Tongrui Sun , Xuan Zhang , Shiqi Zhang , Jia Huang , Yidong Zou . Tailored ionically conductive graphene oxide-encased metal ions for ultrasensitive cadaverine sensor. Chinese Chemical Letters, 2024, 35(8): 109102-. doi: 10.1016/j.cclet.2023.109102

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(269)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142