Citation: Shuang Li, Jiayu Sun, Guocheng Liu, Shuo Zhang, Zhong Zhang, Xiuli Wang. A new Keggin-type polyoxometallate-based bifunctional catalyst for trace detection and pH-universal photodegradation of phenol[J]. Chinese Chemical Letters, ;2024, 35(8): 109148. doi: 10.1016/j.cclet.2023.109148 shu

A new Keggin-type polyoxometallate-based bifunctional catalyst for trace detection and pH-universal photodegradation of phenol

College of Chemistry and Materials Engineering, Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell, Bohai University, Jinzhou 121013, China

lgch1004@sina.com

zhangzhong666@126.com

wangxiuli@bhu.edu.cn

Received Date: 17 August 2023
Revised Date: 8 September 2023
Accepted Date: 25 September 2023
Available Online: 21 November 2023

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The widespread application of phenolic substances in the field of food, medicine and industry, is harmful to the environment and human health. Therefore, it is very important to develop a convenient and effective method to detect and degrade phenolic compounds. Herein, we report a new keggin-type polyoxometallate-based metal-organic complex self-assembled under solvothermal condition, {[Cu(dap)(3-PA)]₄(SiW₁₂O₄₀)(H₂O)₂}·2H₂O (1, dap = 1,2-diaminopropane, 3-HPA = 3-pyridineacrylic acid). 1 shows an interesting 1D ladder-like structure. As a bifunctional catalyst, 1 can be employed as a colorimetric sensor toward phenol with the relatively low detection limit (LOD) of 0.36 µmol/L (S/N = 3) in the wide range (0.001–0.1 mmol/L). The title colorimetric sensor is applied to determine phenol in various water environment with good recoveries ranging from 95%–105%. In addition, 1 also exhibits excellent photocatalytic degradation toward phenol under visible light with the highest removal efficiency at 96% for 100 min and wide pH universality. The selectivity, stability and reliability of the detection of 1 towards phenol, as well as the detection for 4-chlorophenol, o-cresol, 4-nitrophenol and phloroglucinol were studied. Furthermore, the photocatalytic reaction kinetics and the mechanisms of photodegradation of phenol were also investigated in detail.
- POM-based metal-organic complex,
- Bifunctional catalyst,
- Phenolic colorimetric sensor,
- Low detection limit,
- pH-universal photocatalysis,
- Photodegraded phenol
1. [1]
  D.W. Li, Y. Cheng, H. Zuo, et al., J. Colloid. Interface. Sci. 603 (2021) 771–782. doi: 10.1016/j.jcis.2021.06.155
2. [2]
  S. Ray, S. Panjikar, R. Anand, ACS Sens. 2 (2017) 411–418. doi: 10.1021/acssensors.6b00843
3. [3]
  Y. Gong, X. Zhao, H. Zhang, et al., Appl. Catal. B 233 (2018) 35–45. doi: 10.1016/j.apcatb.2018.03.077
4. [4]
  X.H. Zhong, Y. Lu, F. Luo, et al., Chem. Eur. J. 24 (2018) 3045–3051. doi: 10.1002/chem.201705677
5. [5]
  W. Xu, Y.F. Zhang, X. Zhang, X.X. Xu, Q. Wang, J. Haz. Mat. 457 (2023) 131776. doi: 10.1016/j.jhazmat.2023.131776
6. [6]
  O.G. Sas, M. Castro, Á. Domínguez, B. González, Sep. Purif. Technol. 227 (2019) 115703. doi: 10.1016/j.seppur.2019.115703
7. [7]
  T. Dogan, E. Bayram, L. Uzun, S. Senel, A. Denizli, Inc. J. Appl. Polym. Sci. 132 (2015) 41981–41987. doi: 10.1002/app.41981
8. [8]
  Q. Wang, X.Y. Wang, H. Wei, Anal. Chem. 94 (2022) 10198–10205. doi: 10.1021/acs.analchem.2c01695
9. [9]
  Y. Wang, M.Z. Zhao, C. Hou, et al., J. Taiwan. Inst. Chem. E 102 (2019) 312–320. doi: 10.1016/j.jtice.2019.06.019
10. [10]
  N.N. Xing, Y.S. Lyu, J. Yang, et al., Environ. Sci. Nano 9 (2022) 2815–2826. doi: 10.1039/D2EN00322H
11. [11]
  S.Z. Huang, Q. Tang, K.N. Wei, et al., Anal. Chim. Acta 1233 (2022) 340504. doi: 10.1016/j.aca.2022.340504
12. [12]
  T. Song, C. Xie, Q. Che, P. Yang, J. Ind. Eng. Chem. 122 (2023) 415–425. doi: 10.1016/j.jiec.2023.02.041
13. [13]
  Y. Yuan, W.G. Pan, R.T. Guo, et al., Sep. Purif. Technol. 297 (2022) 121538. doi: 10.1016/j.seppur.2022.121538
14. [14]
  X. Chen, R.T. Guo, W.G. Pan, et al., Appl. Catal. B: Environ. 318 (2022) 121839. doi: 10.1016/j.apcatb.2022.121839
15. [15]
  C. Hou, L.H. Fu, Y. Wang, et al., Carbohyd. Polym. 273 (2021) 118548. doi: 10.1016/j.carbpol.2021.118548
16. [16]
  S.W. Wu, D.Z. Guo, X.C. Xua, J.M. Pan, X.H. Niu, Sensor. Actuat. B: Chem. 303 (2020) 127225. doi: 10.1016/j.snb.2019.127225
17. [17]
  D. Zhang, W.Q. Zhang, Z.G. Lin, et al., Inorg. Chem. 59 (2020) 9756–9764. doi: 10.1021/acs.inorgchem.0c00976
18. [18]
  Z. Zhang, Y.L. Wang, Y. Liu, S.L. Huang, G.Y. Yang, Nanoscale 12 (2020) 18333–18341. doi: 10.1039/D0NR02945A
19. [19]
  L. Yang, Z. Zhang, C.N. Zhang, et al., Inorg. Chem. Front. 9 (2022) 4824–4833. doi: 10.1039/D2QI00838F
20. [20]
  X.T. Wang, W.J. Mao, D.S. Wang, et al., Talanta 257 (2023) 124270. doi: 10.1016/j.talanta.2023.124270
21. [21]
  B.X. Zeng, Y.Z. Li, G.P. Liu, et al., Inorg. Chem. 62 (2023) 10351–10358. doi: 10.1021/acs.inorgchem.3c01218
22. [22]
  R.D. Lai, Z.K. Zhu, Y.L. Wu, et al., Inorg. Chem. 61 (2022) 21047–21054. doi: 10.1021/acs.inorgchem.2c03576
23. [23]
  Y. Guan, H.P. Xiao, X.X. Li, S.T. Zheng, Polyoxometalates 2 (2023) 9140023. doi: 10.26599/POM.2023.9140023
24. [24]
  X.X. Li, C.H. Li, M.J. Hou, et al., Nat. Commun. 14 (2023) 5025. doi: 10.1038/s41467-023-40685-0
25. [25]
  S.R. Li, W.D. Liu, L.S. Long, L.S. Zheng, X.J. Kong, Polyoxometalates 2 (2023) 9140022. doi: 10.26599/POM.2023.9140022
26. [26]
  X.X. Li, T. Ji, J.Y. Gao, et al., Chem. Sci. 13 (2022) 4573–4580. doi: 10.1039/D1SC06779F
27. [27]
  J.C. Liu, J.F. Wang, Q. Han, et al., Angew. Chem. Int. Ed. 60 (2021) 11153–11157. doi: 10.1002/anie.202017318
28. [28]
  Q.Z. Wang, B.J. Xu, Y.Y. Wang, et al., Inorg. Chem. 60 (2021) 7753–7761. doi: 10.1021/acs.inorgchem.1c00135
29. [29]
  X.L. Wang, J.Y. Zhang, Z.H. Chang, et al., Inorg. Chem. 60 (2021) 3331–3337. doi: 10.1021/acs.inorgchem.0c03738
30. [30]
  D. Liu, B.K. Chen, J. Li, et al., Inorg. Chem. 60 (2021) 3909–3916. doi: 10.1021/acs.inorgchem.0c03698
31. [31]
  Y.N. Liu, J. Wang, L.N. Li, et al., Chem. Mater. 35 (2023) 3941–3950. doi: 10.1021/acs.chemmater.3c00120
32. [32]
  S.Z. Chang, H.Y. An, Y.H. Chen, et al., ACS. Sustain. Chem. Eng. 10 (2022) 4728–4740. doi: 10.1021/acssuschemeng.2c00351
33. [33]
  J.J. Xin, H.J. Pang, Z.X. Jin, et al., Inorg. Chem. 61 (2022) 16055–16063. doi: 10.1021/acs.inorgchem.2c02454
34. [34]
  Y. Lu, T. Zhang, Y.X. Zhang, et al., Dalton. Trans. 50 (2021) 15198–15209. doi: 10.1039/D1DT02644E
35. [35]
  Z.Y. Du, Z. Chen, R.K. Kang, et al., Inorg. Chem. 59 (2020) 12876–12883. doi: 10.1021/acs.inorgchem.0c01941
36. [36]
  I.D. Brown, D. Altermatt, Acta. Crystallogr. B 41 (1985) 244–247.
37. [37]
  Y. Hu, H.Y. An, X. Liu, et al., Dalton. Trans. 43 (2014) 2488–2498. doi: 10.1039/C3DT52987H
38. [38]
  R.J. Liu, X.K. Shang, C.X. Li, et al., Int. J. Hydrogen. Energ. 38 (2013) 9954–9960. doi: 10.1016/j.ijhydene.2013.06.009
39. [39]
  Y.J. Jang, V.K.H. Bui, P.T. Nguyen, Y.C. Lee, M.I. Kim, Chemosensors 9 (2021) 219–228. doi: 10.3390/chemosensors9080219
40. [40]
  T.S. Cheng, M.Z.M. Nasir, A. Appl. Mater. Today 9 (2017) 212–219. doi: 10.1016/j.apmt.2017.07.005
41. [41]
  A. Saeed, M. Umer, N. Yamasaki, et al., ChemElectroChem 7 (2020) 3943–3950. doi: 10.1002/celc.202000544
42. [42]
  S.R. Jia, X.K. Zhang, F. Yuan, T. Xia, ChemistrySelect 7 (2022) e202202984. doi: 10.1002/slct.202202984
43. [43]
  D.P. Li, Y.L. Tong, J. Huang, et al., J. Mol. Catal. A: Chem. 345 (2011) 108–116. doi: 10.1016/j.molcata.2011.06.002
44. [44]
  Y.H. Xiong, S.H. Chen, F.G. Ye, et al., Anal. Methods 7 (2015) 1300–1306. doi: 10.1039/C4AY02687J
45. [45]
  H.J. Liu, Y.J. Du, J. Gao, et al., Ind. Eng. Chem. Res. 59 (2020) 42–51. doi: 10.1021/acs.iecr.9b04391
46. [46]
  Z.W. Guo, L.H. Lin, J.P. Ye, et al., Angew. Chem. Int. Ed. 62 (2023) e202305260. doi: 10.1002/anie.202305260
47. [47]
  R.G. Yang, Y.M. Fu, X. Meng, et al., Inorg. Chem. Front. 10 (2023) 3699. doi: 10.1039/D3QI00217A
48. [48]
  F.L. Wang, Y.P. Feng, P. Chen, et al., Appl. Catal. B 227 (2018) 114–122. doi: 10.1016/j.apcatb.2018.01.024
49. [49]
  M.F. Atitar, A. Bouziani, R. Dillert, M. Azzouzib, D.W. Bahnemann, Catal. Sci. Technol. 8 (2018) 985–995. doi: 10.1039/C7CY01903C
50. [50]
  R. Farouq, J. Chin. Chem. Soc. 65 (2018) 1333–1339. doi: 10.1002/jccs.201800029
51. [51]
  Z.H. Wang, C.Z. Wang, C.W. Zhang, W.J. Li, Innov. Food. Sci. Emerg. 44 (2017) 224–234. doi: 10.1016/j.ifset.2017.02.013
52. [52]
  T.T. Cao, T.F. Xu, F.X. Deng, W.W. Qiao, C.W. Cui, J. Photoch. Photobio. A 407 (2021) 113025. doi: 10.1016/j.jphotochem.2020.113025
53. [53]
  E.F. Grosu, C. Gabriela, R. Froidevaux, Res. Chem. Intermediat. 44 (2018) 7731–7752. doi: 10.1007/s11164-018-3583-x
54. [54]
  L.H. Yuan, J. Chai, S.W. Wang, et al., Environ. Technol. Innov. 30 (2023) 103085. doi: 10.1016/j.eti.2023.103085
55. [55]
  K.F. Zhang, Y.X. Liu, J.G. Deng, et al., Appl. Catal. B: Environ. 224 (2018) 350–359. doi: 10.1016/j.apcatb.2017.10.044
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