Citation: Yongjing Deng, Feiyang Li, Zijian Zhou, Mengzhu Wang, Yongkang Zhu, Jianwei Zhao, Shujuan Liu, Qiang Zhao. Chiral induction and Sb³⁺ doping in indium halides to trigger second harmonic generation and circularly polarized luminescence[J]. Chinese Chemical Letters, ;2024, 35(8): 109085. doi: 10.1016/j.cclet.2023.109085 shu

Chiral induction and Sb³⁺ doping in indium halides to trigger second harmonic generation and circularly polarized luminescence

Yongjing Deng ^a ,
Feiyang Li ^b ,
Zijian Zhou ^a ,
Mengzhu Wang ^a ,
Yongkang Zhu ^a ,
Jianwei Zhao ^c ,
Shujuan Liu ^{a, *,} ,
Qiang Zhao ^{a, *,}

a.
State Key Laboratory of Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM) & Institute of Flexible Electronics (Future Technology), Nanjing University of Posts & Telecommunications (NJUPT), Nanjing 210023, China
b.
School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212100, China
c.
Shenzhen HUASUAN Technology Co., Ltd., Shenzhen 518000, China

iamsjliu@njupt.edu.cn

iamqzhao@njupt.edu.cn

Received Date: 24 July 2023
Revised Date: 25 August 2023
Accepted Date: 11 September 2023
Available Online: 12 September 2023

Figures(5)

Recently, organic-inorganic hybrid metal halides (HMHs) have attracted extensive attention as promising multifunctional materials by virtue of their structural diversity and tunable photophysical properties. However, it remains a challenge to design HMHs with specific functions on demand. Herein, by introducing R/S-methylbenzylamine (R/S-MBA) and doping Sb³⁺, we have achieved both second harmonic generation (SHG) and circularly polarized luminescence (CPL) properties in lead-free indium halides. The introduction of chiral organic cations can break the symmetry and induce the indium halides to crystallize in the chiral space group. The Sb³⁺ with ns² electronic configuration can serve as the dopants to promote the formation of self-trapped excitons, so as to activate highly efficient luminescence. As a result, the as-prepared Sb³⁺ doped (R/S-MBA)₃InCl₆ show not only SHG responses but also CPL signals with luminescence dissymmetry factor of −5.3 × 10⁻³ and 4.7 × 10⁻³. This work provides a new inspiration for the exploitation of chiral multifunctional materials.
- Hybrid metal halides,
- Self-trapped excitons,
- Chiral induction,
- Second-harmonic generation,
- Circularly polarized luminescence
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沈阳化工大学材料科学与工程学院沈阳 110142

Chiral induction and Sb3+ doping in indium halides to trigger second harmonic generation and circularly polarized luminescence

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通讯作者: 陈斌, bchen63@163.com

Chiral induction and Sb³⁺ doping in indium halides to trigger second harmonic generation and circularly polarized luminescence