Citation: Yijia Jiao, Yuzhu Li, Yuting Zhou, Peipei Cen, Yi Ding, Yan Guo, Xiangyu Liu. Structural evolution and zero-field SMM behaviour in ferromagnetically-coupled disk-type Co₇ clusters bearing exclusively end-on azido bridges[J]. Chinese Chemical Letters, ;2024, 35(8): 109082. doi: 10.1016/j.cclet.2023.109082 shu

Structural evolution and zero-field SMM behaviour in ferromagnetically-coupled disk-type Co₇ clusters bearing exclusively end-on azido bridges

Yijia Jiao ^a ,
Yuzhu Li ^a ,
Yuting Zhou ^a ,
Peipei Cen ^b ,
Yi Ding ^a ,
Yan Guo ^a ,
Xiangyu Liu ^{a, *,}

a.
State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China
b.
College of Public Health, College of Basic Medical Science, Ningxia Medical University, Yinchuan 750021, China

xiangyuliu432@126.com

Received Date: 14 August 2023
Revised Date: 2 September 2023
Accepted Date: 11 September 2023
Available Online: 14 September 2023

Figures(5)

Concise chemistry leads to a family of heptanuclear Co^Ⅱ-clusters, [Co₇(N₃)₁₂(CH₃CN)₁₂] [Y₂(NO₃)₄(piv)₄]·2CH₃CN (DC1) (pivH = pivalic acid), [Co₇(N₃)₁₂(CH₃CN)₁₀(NO₃)_0.4 (Cl)_1.6]·4CH₃CN (DC2) and [Co₇(N₃)₁₂(CH₃CN)₁₀(NO₃)₂]·4CH₃CN (DC3), in which the metal ions are exclusively bridged by end-on azido ligands to stabilize a beautiful disk-like topology. The resulting clusters exhibit interesting structural transformations and thermodynamically-distinct steady states verified by theoretical calculations. Magnetic studies reveal the first observation of zero-field SMM behaviour in disk-like heptanuclear Co^Ⅱ complexes.
- Multinuclear Co^Ⅱ-clusters,
- Disk-like motif,
- Structural modulation,
- Ferromagnetic coupling,
- Zero-field SMM
1. [1]
  M. Nakano, H. Oshio, Chem. Soc. Rev. 40 (2011) 3239-3248. doi: 10.1039/c0cs00223b
2. [2]
  A. Landart-Gereka, M.M. Quesada-Moreno, I.F. Díaz-Ortega, et al., Inorg. Chem. Front. 9 (2022) 2810-2831. doi: 10.1039/d2qi00275b
3. [3]
  P. Kumar Sahu, R. Kharel, S. Shome, S. Goswami, S. Konar, Coordin. Chem. Rev. 475 (2023) 214871. doi: 10.1016/j.ccr.2022.214871
4. [4]
  E. Arias-Egido, M.A. Laguna-Marco, C. Piquer, et al., Mater. Des. 196 (2020) 109083. doi: 10.1016/j.matdes.2020.109083
5. [5]
  Z. Wang, J.J. Liu, M.Y. Li, G. Chen, Chem. Eng. J. 462 (2023) 142154. doi: 10.1016/j.cej.2023.142154
6. [6]
  B.D. Nath, K. Takaishi, T. Ema, Catal. Sci. Technol. 10 (2020) 12-34. doi: 10.1039/c9cy01894h
7. [7]
  S. Schmitz, X. Qiu, M. Gloss, et al., Front. Chem. 7 (2019) 681. doi: 10.3389/fchem.2019.00681
8. [8]
  G.P. Guedes, S. Soriano, N.M. Comerlato, et al., Inorg. Chem. Commun. 37 (2013) 101-105. doi: 10.1016/j.inoche.2013.09.034
9. [9]
  M. Wang, Y. Guo, Z. Han, et al., Inorg. Chem. 61 (2022) 9785-9791. doi: 10.1021/acs.inorgchem.2c01299
10. [10]
  Q.C. Luo, N. Ge, Y.Q. Zhai, et al., Chin. Chem. Lett. 34 (2023) 107547. doi: 10.1016/j.cclet.2022.05.061
11. [11]
  M. Wang, X. Meng, N. Liu, et al., Chin. Chem. Lett. 34 (2023) 107995. doi: 10.1016/j.cclet.2022.107995
12. [12]
  B.H. Wilson, J.S. Ward, D.C. Young, et al., Angew. Chem. Int. Ed. 61 (2022) e202113837. doi: 10.1002/anie.202113837
13. [13]
  S. Mondal, A. Lunghi, J. Am. Chem. Soc. 144 (2022) 22965-22975. doi: 10.1021/jacs.2c08876
14. [14]
  C.M. Liu, D.Q. Zhang, X. Hao, D.B. Zhu, Inorg. Chem. Front. 7 (2020) 3340-3351. doi: 10.1039/d0qi00632g
15. [15]
  S. Li, Z. Weng, L. Jiang, et al., Chin. Chem. Lett. 34 (2023) 107251. doi: 10.1016/j.cclet.2022.02.056
16. [16]
  X.L. Li, L. Zhao, J. Wu, et al., Chem. Sci. 13 (2022) 10048-10056. doi: 10.1039/d2sc03156f
17. [17]
  Q. Chen, M.H. Zeng, Y.L. Zhou, H.H. Zou, M. Kurmoo, Chem. Mater. 22 (2010) 2114-2119. doi: 10.1021/cm903651e
18. [18]
  D.I. Alexandropoulos, L. Cunha-Silva, A. Escuer, T.C. Stamatatos, Chem 20 (2014) 13860-13864. doi: 10.1002/chem.201403815
19. [19]
  X.T. Wang, B.W. Wang, Z.M. Wang, W. Zhang, S. Gao, Inorg. Chim. Acta 361 (2008) 3895-3902. doi: 10.1016/j.ica.2008.03.020
20. [20]
  D.M. Chen, X.Z. Ma, X.J. Zhang, N. Xu, P. Cheng, Inorg. Chem. 54 (2015) 2976-2982. doi: 10.1021/acs.inorgchem.5b00074
21. [21]
  L.Q. Wei, B.W. Li, S. Hu, M.H. Zeng, CrystEngComm 13 (2011) 510-516. doi: 10.1039/C0CE00085J
22. [22]
  E.C. Yang, Z.Y. Liu, L. Zhang, N. Yang, X.J. Zhao, Dalton Trans. 45 (2016) 8134-8141. doi: 10.1039/C6DT00010J
23. [23]
  I. Radu, V.C. Kravtsov, S.M. Ostrovsky, et al., Inorg. Chem. 56 (2017) 2662-2676. doi: 10.1021/acs.inorgchem.6b02827
24. [24]
  D. Shao, F.X. Xu, L. Yin, et al., Chin. J. Chem. 40 (2022) 2193-2202. doi: 10.1002/cjoc.202200284
25. [25]
  A. Świtlicka, B. Machura, M. Penkala, et al., Inorg. Chem. Front. 7 (2020) 2637-2650. doi: 10.1039/d0qi00257g
26. [26]
  A. Castro-Alvarez, Y. Gil, L. Llanos, D. Aravena, Inorg. Chem. Front. 7 (2020) 2478-2486. doi: 10.1039/d0qi00487a
27. [27]
  W. Wang, H. Hai, S.H. Zhang, et al., J. Clust. Sci. 25 (2013) 357-365. doi: 10.1504/IJCEELL.2013.055406
28. [28]
  A. Escuer, J. Esteban, S.P. Perlepes, T.C. Stamatatos, Coordin. Chem. Rev. 275 (2014) 87-129. doi: 10.1016/j.ccr.2014.04.001
29. [29]
  S. Li, Z. Weng, L. Jiang, et al., Chin. Chem. Lett. 34 (2023) 107489. doi: 10.1016/j.cclet.2022.05.003
30. [30]
  Y.F. Zeng, X. Hu, F.C. Liu, X.H. Bu, Chem. Soc. Rev. 38 (2009) 469-480. doi: 10.1039/B718581M
31. [31]
  J. Netz, A.O. Mitrushchenkov, A. Kohn, J. Chem. Theory Comput. 17 (2021) 5530-5537. doi: 10.1021/acs.jctc.1c00294
32. [32]
  S.F.M. Schmidt, M.P. Merkel, G.E. Kostakis, et al., Dalton Trans. 46 (2017) 15661-15665. doi: 10.1039/C7DT03149A
33. [33]
  J.K. Staab, N.F. Chilton, J. Chem. Theory Comput. 18 (2022) 6588-6599. doi: 10.1021/acs.jctc.2c00611
34. [34]
  J. Han, R. Cheng, L. Liu, H. Ohno, S. Fukami, Nat. Mater. 22 (2023) 684-695. doi: 10.1038/s41563-023-01492-6
35. [35]
  T.C. Stamatatos, E. Rentschler, Chem. Commun. 55 (2018) 11-26.
36. [36]
  K.X. Yu, J.G.C. Kragskow, Y.S. Ding, et al., Chem. Eur. J. 6 (2020) 1777-1793.
37. [37]
  X.M. Zhang, K. Wang, Y.Q. Wang, E.Q. Gao, Dalton Trans. 40 (2011) 12742-12749. doi: 10.1039/c1dt11068c
38. [38]
  Y.S. Ding, K.X. Yu, D. Reta, et al., Nat. Commun. 9 (2018) 3134. doi: 10.1038/s41467-018-05587-6
39. [39]
  A. Lunghi, Sci. Adv. 8 (2022) eabn7880. doi: 10.1126/sciadv.abn7880
40. [40]
  D. Krylov, G. Velkos, C.H. Chen, et al., Inorg. Chem. Front. 7 (2020) 3521-3532. doi: 10.1039/d0qi00771d
41. [41]
  J. Krause, D.I. Alexandropoulos, L.M. Carrella, E. Rentschler, T.C. Stamatatos, Chem. Commun. 54 (2018) 12499-12502. doi: 10.1039/c8cc07722c
42. [42]
  A.A. Athanasopoulou, M. Pilkington, C.P. Raptopoulou, A. Escuer, T.C. Stamatatos, Chem. Commun. 50 (2014) 14942-14945. doi: 10.1039/C4CC07192A
43. [43]
  P.S. Perlepe, A.A. Athanasopoulou, K.I. Alexopoulou, et al., Dalton Trans. 43 (2014) 16605-16609. doi: 10.1039/C4DT02434F
44. [44]
  A.A. Athanasopoulou, C.P. Raptopoulou, A. Escuer, T.C. Stamatatos, RSC Adv. 4 (2014) 12680-12684. doi: 10.1039/C4RA00738G
45. [45]
  V.I. Ovcharenko, O.V. Kuznetsova, Russ. Chem. Rev. 89 (2020) 1261-1273. doi: 10.1070/rcr4981
46. [46]
  Y.Z. Zhang, W. Wernsdorfer, F. Pan, Z.M. Wang, S. Gao, Chem. Commun. 31 (2006) 3302-3304. doi: 10.1039/b605459e
47. [47]
  Y.L. Zhou, M.H. Zeng, L.Q. Wei, B.W. Li, M. Kurmoo, Chem. Mater. 22 (2010) 4295-4303. doi: 10.1021/cm1011229
48. [48]
  R.X. Zhao, Q.P. Huang, G. Li, et al., J. Clust. Sci. 25 (2014) 1099-1108. doi: 10.1007/s10876-014-0692-6
49. [49]
  S.H. Zhang, Y. Song, H. Liang, M.H. Zeng, CrystEngComm 11 (2009) 865-872. doi: 10.1039/b815675a
50. [50]
  M.E. Slater-Parry, J.P. Durrant, J.M. Howells, et al., Dalton Trans. 48 (2019) 1477-1488. doi: 10.1039/c8dt04229b
51. [51]
  H.L. Zheng, X.L. Chen, T. Li, et al., Chem 24 (2018) 7906-7912. doi: 10.1002/chem.201800516
52. [52]
  S.T. Meally, C. McDonald, P. Kealy, et al., Dalton Trans. 41 (2012) 5610-5616. doi: 10.1039/c2dt12229d
53. [53]
  M. Llunell, D. Casanova, J. Cirera, P. Alemany, S. Alvarez SHAPE Version 2.1, Shape Software, Barcelona, 2013.
54. [54]
  M. Kurmoo, Chem. Soc. Rev. 38 (2009) 1353-1379. doi: 10.1039/b804757j
55. [55]
  N.F. Chilton, R.P. Anderson, L.D. Turner, A. Soncini, K.S. Murray, J. Comput. Chem. 34 (2013) 1164-1175. doi: 10.1002/jcc.23234
56. [56]
  Y. Wu, J. Xi, T. Xiao, et al., Inorg. Chem. Front. 8 (2021) 5158-5168. doi: 10.1039/d1qi01208h
57. [57]
  M.R. Saber, M.K. Singh, K.R. Dunbar, Chem. Commun. 56 (2020) 8492-8495. doi: 10.1039/d0cc03238g
58. [58]
  C.E. Patrick, S. Kumar, G. Balakrishnan, et al., Phys. Rev. Lett. 120 (2018) 097202. doi: 10.1103/PhysRevLett.120.097202
59. [59]
  J. Mohapatra, M. Xing, J. Elkins, J.P. Liu, J. Alloys Compd. 824 (2020) 153874. doi: 10.1016/j.jallcom.2020.153874
60. [60]
  D. Gatteschi, A. Cornia, M. Mannini, R. Sessoli, Inorg. Chem. 48 (2009) 3408-3419. doi: 10.1021/ic8013283
61. [61]
  T.S. Mahapatra, D. Basak, S. Chand, et al., Dalton Trans. 45 (2016) 13576-13589. doi: 10.1039/C6DT02494G
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Structural evolution and zero-field SMM behaviour in ferromagnetically-coupled disk-type Co7 clusters bearing exclusively end-on azido bridges

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通讯作者: 陈斌, bchen63@163.com

Structural evolution and zero-field SMM behaviour in ferromagnetically-coupled disk-type Co₇ clusters bearing exclusively end-on azido bridges