Citation: Guihuang Fang, Wei Chen, Hongwei Yang, Haisheng Fang, Chuang Yu, Maoxiang Wu. Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive[J]. Chinese Chemical Letters, ;2024, 35(6): 108799. doi: 10.1016/j.cclet.2023.108799 shu

Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive

Guihuang Fang ^{a, b, 1} ,
Wei Chen ^{a, 1} ,
Hongwei Yang ^a ,
Haisheng Fang ^{a, *,} ,
Chuang Yu ^{c, *,} ,
Maoxiang Wu ^{b, *,}

a.
Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
b.
Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

hsfang1981@hotmail.com

cyu2020@hust.edu.cn

mxwu@fjirsm.ac.cn

Received Date: 12 June 2023
Revised Date: 6 July 2023
Accepted Date: 11 July 2023
Available Online: 14 July 2023

Figures(4)

The addition of electrolyte additives is an effective strategy for tuning the property of the electrolyte to engineer the electrode/electrolyte interface, and there exist obvious discrepancies regarding the effect of fluoroethylene carbonate (FEC) as an electrolyte additive on the performance of cathodes. Herein FEC is introduced into the electrolyte of the LiMn_0.8Fe_0.2PO₄/Li cell and its effect on the properties of the LiMn_0.8Fe_0.2PO₄ is investigated. It is found that the addition of FEC in the electrolyte has a positive effect on the performance of the LiMn_0.8Fe_0.2PO₄ cathode, which can be attributed to the reduced products generated by the interfacial side-reactions on the LiMn_0.8Fe_0.2PO₄ cathode surface and the decreased metal dissolution in the FEC-containing electrolyte, thanks to the higher oxidation resistance of FEC and the easier and stronger binding of FEC and PF₆⁻.
- Lithium-ion batteries,
- LiMn_0.8Fe_0.2PO₄,
- Cathode,
- Electrolyte additives,
- Fluoroethylene carbonate
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沈阳化工大学材料科学与工程学院沈阳 110142

Improved performance of LiMn0.8Fe0.2PO4 by addition of fluoroethylene carbonate electrolyte additive

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Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive