Citation: Dongxue Song, Mingxia Li, Fan Yang, Menghan Yu, Zhenzi Li, Jie Chen, Xiaoshuang Zhang, Wei Zhou. Plasmon Bi in-situ anchored on BiOCl nanosheets assembled microspheres towards optimized photothermal-photocatalytic performance[J]. Chinese Chemical Letters, ;2024, 35(2): 108591. doi: 10.1016/j.cclet.2023.108591 shu

Plasmon Bi in-situ anchored on BiOCl nanosheets assembled microspheres towards optimized photothermal-photocatalytic performance

Dongxue Song ^a ,
Mingxia Li ^{a, *,} ,
Fan Yang ^a ,
Menghan Yu ^a ,
Zhenzi Li ^b ,
Jie Chen ^a ,
Xiaoshuang Zhang ^a ,
Wei Zhou ^{a, b, *,}

a.
School of Chemistry and Materials Science, Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People's Republic of China, Heilongjiang University, Harbin 150080, China
b.
Shandong Provincial Key Laboratory of Molecular Engineering, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Ji'nan 250353, China

limingxia@hlju.edu.cn

zwchem@hotmail.com

Received Date: 27 September 2022
Revised Date: 17 May 2023
Accepted Date: 18 May 2023
Available Online: 19 May 2023

Figures(7)

Interface engineering is of great importance to improve the photocatalytic performance. Herein, in-situ formation plasmon Bi/BiOCl nanosheets assembled heterojunction microspheres are fabricated via facile reductive solvothermal approach. The aldehyde group in the DMF structure is used to exert the weak reducing property of the solvent and thus strip out the metal Bi in BiOCl. The metal Bi is anchored on surface of BiOCl firmly due to in-situ formation engineered interface, which could realize efficient charge transfer channel. The resultant Bi/BiOCl heterojunctions assemblies with narrow bandgap of 3.05 eV and mesoporous structure extend the photoresponse to visible light region and could provide sufficient surface active sites. The visible-light-driven photocatalytic degradation of high-toxic norfloxacin for Bi/BiOCl heterojunctions is up to 95.5% within 20 min, representing several times that of pristine BiOCl nanosheets and the physical mixture. It is attributed to the in-situ formation of Bi/BiOCl heterojunctions and surface plasmon resonance (SPR) effect of plasmon Bi promoting charge transfer, and the obvious photothermal effect promoting the photocatalytic reaction, which are verified by experimental and density functional theory (DFT) calculations. This strategy provides ideal perspectives for fabricating metal/semiconductor heterojunctions photocatalysts with high-performance.
- Photocatalysis,
- BiOCl,
- Heterojunction,
- Plasmon Bi,
- Mesoporous structure
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