Citation: Jintao Men, Ke Xu, Taiting Sha, Lei He, Yan Xu, Jie Mu, Tijian Yin, Qiong Ye. Self-powered stimuli responsive material for dual stimulation of heat and guest molecules[J]. Chinese Chemical Letters, ;2024, 35(2): 108427. doi: 10.1016/j.cclet.2023.108427 shu

Self-powered stimuli responsive material for dual stimulation of heat and guest molecules

Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics and School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

yeqiong@seu.edu.cn

Received Date: 27 February 2023
Revised Date: 20 March 2023
Accepted Date: 3 April 2023
Available Online: 7 April 2023

Figures(4)

Stimuli-responsive smart materials exhibit reverse chemical/physical changes in response to external stimuli and research on stimuli-responsive smart materials with self-powered properties is still uncultivated ground. Here, we report perovskite crystalline self-powered multiple stimuli-responsive materials triggered by chemical and thermal stimuli. [HMEP]PbI₃·(H₂O) (1; HMEP is a hydroxytris(1-methylethyl)phosphorus cation) crystallizes in a chiral space group P2₁ at 293 K and has the piezoelectric reaction (d₃₃ = 10 pC/N and output voltage = 1 V) of self-powered modes, this value is larger than the value of 3 pC/N for the classical piezoelectric material ZnO. Piezoelectric materials can generate energy due to mechanical deformation, and using thermal heating to lose water, [HMEP]PbI₃ (2) can be obtained. 2 crystallizes in the non-centrosymmetric space group, undergoes two reversible phase transitions at 243/255 K and 315/348 K, and shows second harmonic generation switching. Interestingly, 2 can return to the hydrated form 1 after absorbing water. This work will lay the foundation for self-powered stimuli-responsive compounds and contribute to the construction of novel organic-inorganic hybrid materials with second harmonic generation switching.
- Self-powered,
- Dual stimulation reactive,
- Phase transition,
- SHG switch,
- Organic-inorganic hybrid perovskite
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