Citation: Shuya Liu, Yuhang Lin, Dongpeng Yan. Colorful ultralong room-temperature phosphorescence in dual-ligand metal-organic framework[J]. Chinese Chemical Letters, ;2023, 34(7): 107952. doi: 10.1016/j.cclet.2022.107952 shu

Colorful ultralong room-temperature phosphorescence in dual-ligand metal-organic framework

Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Key Laboratory of Radiopharmaceuticals, Ministry of Education, Beijing Normal University, Beijing 100875, China

yandp@bnu.edu.cn

Received Date: 7 July 2022
Revised Date: 18 October 2022
Accepted Date: 23 October 2022
Available Online: 27 October 2022

Figures(4)

Long afterglow organic-inorganic hybrid materials have attracted much attention in recent years and are widely used in information security, biological imaging and many other fields. Since up-conversion long-persistence materials are promising for bio-optical imaging due to their high penetration depth and elimination of autofluorescence background, it is highly desirable to combine down-conversion and up-conversion pathways to obtain smart materials with excitation-dependent tunable room-temperature phosphorescence properties. In this work, a metal-organic framework (Zn-DCPS-BIMB), consisting of divalent zinc ions, o-bis(imidazol-1-ylmethyl)benzene and 4,4′-dicarboxydiphenylsulfone, is designed to stabilize triplet excitons, coordinate the emission of different ligands, and endow materials with tunable emission color and up-conversion properties via heavy atoms effects promoting single-triplet orbital coupling and intersystem crossing.
- Room temperature phosphorescence,
- Information encryption,
- Metal-organic framework,
- Up-conversion luminescence,
- Organic-inorganic hybrids
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