Citation: Yongfu Li, Xinyue Lou, Chunyu Wang, Yan Wang, Yu Jia, Qi Lin, Yingwei Yang. Synthesis of stimuli-responsive pillararene-based supramolecular polymer materials for the detection and separation of metal ions[J]. Chinese Chemical Letters, ;2023, 34(5): 107877. doi: 10.1016/j.cclet.2022.107877 shu

Synthesis of stimuli-responsive pillararene-based supramolecular polymer materials for the detection and separation of metal ions

Yongfu Li ^{a, 1} ,
Xinyue Lou ^{a, 1} ,
Chunyu Wang ^b ,
Yan Wang ^{a, *,} ,
Yu Jia ^c ,
Qi Lin ^c ,
Yingwei Yang ^{a, *,}

a.
International Joint Research Laboratory of Nano-Micro Architecture Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
b.
State Key Laboratory of Supramolecular Structure and Materials, Institute of Theoretical Chemistry, Laboratory of Theoretical and Computational Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
c.
Key Laboratory of Eco-Functional Polymer Materials of the Ministry of Education, Key Laboratory of Eco-Environmental Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

ywyang@jlu.edu.cn

wangy2011@jlu.edu.cn

Received Date: 7 July 2022
Revised Date: 29 September 2022
Accepted Date: 2 October 2022
Available Online: 13 October 2022

Figures(4)

A stimuli-responsive supramolecular polymer network (G-(CN)₂⊂BXDSP5) with aggregation-induced emission (AIE) properties has been efficiently constructed by host–guest interactions between pillar[5]arene derivative BXDSP5 and a homoditopic guest G-(CN)₂, which shows not only excellent fluorescence properties due to the AIE effect but also desirable ion-sensing abilities in both solution and solid states, holding great potential in the applicable fluorescence detection for Fe³⁺. The resultant G-(CN)₂⊂BXDSP5 can be transformed into supramolecular polymer gel at high concentration via multiple noncovalent interactions, showing multi-stimuli-responsiveness in response to temperature change, mechanical force, and competitive agent. Meanwhile, the xerogel of supramolecular polymer material has been successfully used to remove Fe³⁺ from water with high adsorption efficiency. In addition, an ion-responsive film based on supramolecular polymer has also been developed, which can serve as a practical and convenient fluorescence test kit for detecting Fe³⁺.
- Aggregation-induced emission,
- Host–guest chemistry,
- Sensing and separation,
- Stimuli-responsive materials,
- Supramolecular polymer materials
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