Citation: Yue Li, Bo Yu, Huimin Li, Bo Liu, Xiang Yu, Kewei Zhang, Gang Qin, Jiahao Lu, Lihui Zhang, Longlu Wang. Activation of hydrogen peroxide by molybdenum disulfide as Fenton-like catalyst and cocatalyst: Phase-dependent catalytic performance and degradation mechanism[J]. Chinese Chemical Letters, ;2023, 34(5): 107874. doi: 10.1016/j.cclet.2022.107874 shu

Activation of hydrogen peroxide by molybdenum disulfide as Fenton-like catalyst and cocatalyst: Phase-dependent catalytic performance and degradation mechanism

Yue Li ^{a, 1} ,
Bo Yu ^{a, b, 1} ,
Huimin Li ^{a, b} ,
Bo Liu ^a ,
Xiang Yu ^a ,
Kewei Zhang ^a ,
Gang Qin ^{b, *,} ,
Jiahao Lu ^a ,
Lihui Zhang ^a ,
Longlu Wang ^{c, *,}

a.
School of Chemical and Printing-Dyeing Engineering, Henan International Joint Laboratory of Rare Earth Composite Materials, Henan University of Engineering, Xinzheng 451191, China
b.
School of Material Science and Engineering, Henan Polytechnic University, Jiaozuo 454001, China
c.
College of Electronic and Optical Engineering & College of Microelectronics, Institute of Flexible Electronics (Future Technology), Nanjing University of Posts & Telecommunications, Nanjing 210023, China

clqingang@126.com

wanglonglu@hnu.edu.cn

Received Date: 21 May 2022
Revised Date: 16 August 2022
Accepted Date: 29 September 2022
Available Online: 4 October 2022

Figures(4)

Molybdenum disulfide (MoS₂) has attracted great attention in hydrogen peroxide (H₂O₂) activation as a Fenton-like catalyst and cocatalyst, but the distinct mechanism of generating ^•OH remains unclear. In this paper, the metallic 1T phase and semiconducting 2H phase of MoS₂ nanosheets were prepared and applied in MoS₂/H₂O₂ and MoS₂/Fe²⁺/H₂O₂ systems with and without light irradiation. Compared with 2H-MoS₂, 1T-MoS₂ exhibited superior removal rates in degrading organic pollutants in the two systems under light irradiation. However, the phase had little effect on activating H₂O₂ in the MoS₂/H₂O₂ system under dark conditions. This is because it was difficult for the surface ^•OH_ads generated in the MoS₂/H₂O₂ system to diffuse into solution, while the ^•OH_free radicals were mainly responsible for degrading organic pollutants. When introducing light irradiation, external energy may accelerate the desorption of ^•OH_ads into ^•OH_free. Interestingly, the conversion between Mo⁴⁺ and Mo⁵⁺ triggered the decomposition of H₂O₂ in the Fenton-like reaction, while the cycle of Mo⁴⁺/Mo⁶⁺ promoted the regeneration of Fe³⁺ when employing 1T-MoS₂ as a cocatalyst. Meanwhile, the 1T-MoS₂ catalysts exhibited excellent stability and ability to degrade various organics in the two systems. This work offers deeper insight into the MoS₂-based Fenton-like and cocatalytic mechanisms.
- Molybdenum sulfate,
- Phase,
- Fenton-like catalyst,
- Cocatalyst,
- Catalytic mechanism
1. [1]
  L. Wang, L. Xie, W. Zhao, et al., Chem. Eng. J. 405 (2021) 127028. doi: 10.1016/j.cej.2020.127028
2. [2]
  W. Xiang, M. Huang, Y. Wang, et al., Chin. Chem. Lett. 31 (2020) 2831–2834. doi: 10.1016/j.cclet.2020.08.006
3. [3]
  Y. Jin, Z. Chen, L. Yang, et al., J Alloy. Compd. 890 (2022) 161831. doi: 10.1016/j.jallcom.2021.161831
4. [4]
  J. Chen, Y. Tang, S. Wang, et al., Chin. Chem. Lett. 33 (2022) 1468–1474. doi: 10.1016/j.cclet.2021.08.103
5. [5]
  Y. Liu, Y.C. Zhang, X.F. Xu, J. Hazard. Mater. 163 (2009) 1310–1314. doi: 10.1016/j.jhazmat.2008.07.101
6. [6]
  L. Yang, J. Guo, T. Yang, et al., J. Hazard. Mater. 402 (2021) 123741. doi: 10.1016/j.jhazmat.2020.123741
7. [7]
  N. Wang, T. Zheng, G. Zhang, et al., J Environ. Chem. Eng. 4 (2016) 762–787. doi: 10.1016/j.jece.2015.12.016
8. [8]
  M. Xing, W. Xu, C. Dong, et al., Chem 4 (2018) 1359–1372. doi: 10.1016/j.chempr.2018.03.002
9. [9]
  S. Wang, L. Wang, L. Xie, et al., Nano. Res. 15 (2022) 4996–5003. doi: 10.1007/s12274-022-4158-0
10. [10]
  Z. Luo, R. Spinney, Z. Wei, et al., ACS ES&T Water 1 (2021) 2339–2347. doi: 10.1021/acsestwater.1c00193
11. [11]
  Q. Li, B. Hu, Q. Yang, et al., Environ. Res. 191 (2020) 110227. doi: 10.1016/j.envres.2020.110227
12. [12]
  Q. Yi, J. Ji, B. Shen, et al., Environ. Sci. Technol. 53 (2019) 9725–9733. doi: 10.1021/acs.est.9b01676
13. [13]
  W. Xiang, M. Huang, X. Wu, et al., Chin. Chem. Lett. 33 (2022) 1275–1278. doi: 10.1016/j.cclet.2021.07.072
14. [14]
  L. Zhu, J. Ji, J. Liu, et al., Angew. Chem. Int. Ed. 59 (2020) 13968–13976. doi: 10.1002/anie.202006059
15. [15]
  F. Cao, L. Zhang, H. Wang, et al., Angew. Chem. Int. Ed. 58 (2019) 16236–16242 doi: 10.1002/anie.201908289
16. [16]
  X. Nie, G. Li, S. Li, et al., Appl. Catal. B: Environ. 300 (2022) 120734. doi: 10.1016/j.apcatb.2021.120734
17. [17]
  J. Ji, Q. Yan, P. Yin, et al., Angew. Chem. Int. Ed. 60 (2021) 2903–2908. doi: 10.1002/anie.202013015
18. [18]
  Y. Li, H. Li, X. Lu, et al., J. Colloid. Interface Sci. 596 (2021) 384–395. doi: 10.3390/ijerph18020384
19. [19]
  Y. Li, K. Yin, L. Wang, et al., Appl. Catal. B 239 (2018) 537–544. doi: 10.1016/j.apcatb.2018.05.080
20. [20]
  Y. Li, L. Wang, T. Cai, et al., Chem. Eng. J. 321 (2017) 366–374. doi: 10.1016/j.cej.2017.03.139
21. [21]
  X. Hao, Z. Jin, H. Yang, et al., Appl. Catal. B 210 (2017) 45–56. doi: 10.1016/j.apcatb.2017.03.057
22. [22]
  Q. Yan, C. Lian, K. Huang, et al., Angew. Chem. Int. Ed. 133 (2021) 17292–17300. doi: 10.1002/ange.202105736
23. [23]
  Y. Chen, G. Zhang, Q. Ji, et al., ACS Appl. Mater. Interfaces 11 (2019) 26781–26788. doi: 10.1021/acsami.9b05978
24. [24]
  Y. Zhu, L. Wang, Y. Liu, et al., Appl. Catal. B-Environ. 241 (2019) 483–490. doi: 10.1016/j.apcatb.2018.09.062
25. [25]
  L. Xie, L. Wang, W. Zhao, et al., Nat. Commun. 12 (2021) 5070. doi: 10.1038/s41467-021-25381-1
26. [26]
  S. Wang, W. Xu, J. Wu, et al., Sep. Purif. Technol. 235 (2020) 116170. doi: 10.1016/j.seppur.2019.116170
27. [27]
  X.H. Zhang, N. Li, J. Wu, et al., Appl. Catal. B 229 (2018) 227–236. doi: 10.1016/j.apcatb.2018.02.025
28. [28]
  H. Li, S. Chen, X. Jia, et al., Nat. Commun. 8 (2017) 15377. doi: 10.1038/ncomms15377
29. [29]
  J. Chen, Y.M. Tang, S.H. Wang, et al., Chin. Chem. Lett. 33 (2022) 1468–1474. doi: 10.1016/j.cclet.2021.08.103
30. [30]
  M.A. Lukowski, A.S. Daniel, F. Meng, et al., J. Am. Chem. Soc. 135 (2013) 10274–10277. doi: 10.1021/ja404523s
31. [31]
  J. Luo, K. Fu, M. Sun, et al., ACS Appl. Mater. Interfaces 11 (2019) 38789–38797. doi: 10.1021/acsami.9b14019
32. [32]
  Y. Zhu, R. Zhu, Y. Xi, et al., Appl. Catal. B 255 (2019) 117739. doi: 10.1016/j.apcatb.2019.05.041
33. [33]
  Q. Liu, X. Li, Q. He, et al., Small 11 (2015) 5556–5564. doi: 10.1002/smll.201501822
34. [34]
  C. Sun, L. Wang, W. Zhao, et al., Adv. Funct. Mater. (2022) 2206163 doi: 10.1002/adfm.202206163
35. [35]
  Y. Nosaka, A.Y. Nosaka, Chem. Rev. 117 (2017) 11302–11336. doi: 10.1021/acs.chemrev.7b00161
36. [36]
  X. Liu, Y. Hou, T. Meng, et al., Chin. Chem. Lett. 34 (2023) 107489. doi: 10.1016/j.cclet.2022.05.003
37. [37]
  G.X. Huang, C.Y. Wang, C.W. Yang, et al., Environ. Sci. Technol. 51 (2017) 12611–12618 doi: 10.1021/acs.est.7b03007
1. [1]
  Yulong Liu , Haoran Lu , Tong Yang , Peng Cheng , Xu Han , Wenyan Liang . Catalytic applications of amorphous alloys in wastewater treatment: A review on mechanisms, recent trends, challenges and future directions. Chinese Chemical Letters, 2024, 35(10): 109492-. doi: 10.1016/j.cclet.2024.109492
2. [2]
  Weichen Zhu , Wei Zuo , Pu Wang , Wei Zhan , Jun Zhang , Lipin Li , Yu Tian , Hong Qi , Rui Huang . Fe-N-C heterogeneous Fenton-like catalyst for the degradation of tetracycline: Fe-N coordination and mechanism studies. Chinese Chemical Letters, 2024, 35(9): 109341-. doi: 10.1016/j.cclet.2023.109341
3. [3]
  Kexin Yin , Jingren Yang , Yanwei Li , Qian Li , Xing Xu . Metal-free diatomaceous carbon-based catalyst for ultrafast and anti-interference Fenton-like oxidation. Chinese Chemical Letters, 2024, 35(12): 109847-. doi: 10.1016/j.cclet.2024.109847
4. [4]
  Mengxiang Zhu , Tao Ding , Yunzhang Li , Yuanjie Peng , Ruiping Liu , Quan Zou , Leilei Yang , Shenglei Sun , Pin Zhou , Guosheng Shi , Dongting Yue . Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction. Chinese Chemical Letters, 2024, 35(12): 109833-. doi: 10.1016/j.cclet.2024.109833
5. [5]
  Chi Zhang , Ning Ding , Yuwei Pan , Lichun Fu , Ying Zhang . The degradation pathways of contaminants by reactive oxygen species generated in the Fenton/Fenton-like systems. Chinese Chemical Letters, 2024, 35(10): 109579-. doi: 10.1016/j.cclet.2024.109579
6. [6]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
7. [7]
  Shiyu Pan , Bo Cao , Deling Yuan , Tifeng Jiao , Qingrui Zhang , Shoufeng Tang . Complexes of cupric ion and tartaric acid enhanced calcium peroxide Fenton-like reaction for metronidazole degradation. Chinese Chemical Letters, 2024, 35(7): 109185-. doi: 10.1016/j.cclet.2023.109185
8. [8]
  Yanhua Peng , Xin Yu , Ting Wang . Adaptive nanoconfined Fenton-like reactions: Tailoring carbon pathways for sustainable water treatment and energy harvesting. Chinese Chemical Letters, 2024, 35(12): 110198-. doi: 10.1016/j.cclet.2024.110198
9. [9]
  Xun Zhu , Chenchen Zhang , Yingying Li , Yin Lu , Na Huang , Dawei Wang . Degradation of perfluorooctanoic acid by inductively heated Fenton-like process over the Fe₃O₄/MIL-101 composite. Chinese Chemical Letters, 2024, 35(12): 109753-. doi: 10.1016/j.cclet.2024.109753
10. [10]
  Abiduweili Sikandaier , Yukun Zhu , Dongjiang Yang . In-situ decorated cobalt phosphide cocatalyst on Hittorf's phosphorus triggering efficient photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(2): 100242-100242. doi: 10.1016/j.cjsc.2024.100242
11. [11]
  Pengcheng Su , Shizheng Chen , Zhihong Yang , Ningning Zhong , Chenzi Jiang , Wanbin Li . Vapor-phase postsynthetic amination of hypercrosslinked polymers for efficient iodine capture. Chinese Chemical Letters, 2024, 35(9): 109357-. doi: 10.1016/j.cclet.2023.109357
12. [12]
  Ce Liang , Qiuhui Sun , Adel Al-Salihy , Mengxin Chen , Ping Xu . Recent advances in crystal phase induced surface-enhanced Raman scattering. Chinese Chemical Letters, 2024, 35(9): 109306-. doi: 10.1016/j.cclet.2023.109306
13. [13]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
14. [14]
  Xue Xin , Qiming Qu , Islam E. Khalil , Yuting Huang , Mo Wei , Jie Chen , Weina Zhang , Fengwei Huo , Wenjing Liu . Hetero-phase zirconia encapsulated with Au nanoparticles for boosting electrocatalytic nitrogen reduction. Chinese Chemical Letters, 2024, 35(5): 108654-. doi: 10.1016/j.cclet.2023.108654
15. [15]
  Tian Yang , Yi Liu , Lina Hua , Yaoyao Chen , Wuqian Guo , Haojie Xu , Xi Zeng , Changhao Gao , Wenjing Li , Junhua Luo , Zhihua Sun . Lead-free hybrid two-dimensional double perovskite with switchable dielectric phase transition. Chinese Chemical Letters, 2024, 35(6): 108707-. doi: 10.1016/j.cclet.2023.108707
16. [16]
  Shu Lin , Kezhen Qi . Phase-dependent lithium-alloying reactions for lithium-metal batteries. Chinese Chemical Letters, 2024, 35(4): 109431-. doi: 10.1016/j.cclet.2023.109431
17. [17]
  Wangyan Hu , Ke Li , Xiangnan Dou , Ning Li , Xiayan Wang . Nano-sized stationary phase packings retained by single-particle frit for microchip liquid chromatography. Chinese Chemical Letters, 2024, 35(4): 108806-. doi: 10.1016/j.cclet.2023.108806
18. [18]
  Zhaohong Chen , Mengzhen Li , Jinfei Lan , Shengqian Hu , Xiaogang Chen . Organic ferroelastic enantiomers with high T_c and large dielectric switching ratio triggered by order-disorder and displacive phase transition. Chinese Chemical Letters, 2024, 35(10): 109548-. doi: 10.1016/j.cclet.2024.109548
19. [19]
  Zhi-Yuan Yue , Hua-Kai Li , Na Wang , Shan-Shan Liu , Le-Ping Miao , Heng-Yun Ye , Chao Shi . Dehydration-triggered structural phase transition-associated ferroelectricity in a hybrid perovskite-type crystal. Chinese Chemical Letters, 2024, 35(10): 109355-. doi: 10.1016/j.cclet.2023.109355
20. [20]
  Zhuoer Cai , Yinan Zhang , Xiu-Ni Hua , Baiwang Sun . Phase transition arising from order-disorder motion in stable layered two-dimensional perovskite. Chinese Journal of Structural Chemistry, 2024, 43(11): 100426-100426. doi: 10.1016/j.cjsc.2024.100426

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(659)
HTML views(29)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142