Citation: Tianran Lin, Chunsuo Tian, Ying Sun, Shendong Liu, Di Wang, Li Hou, Shulin Zhao. Information encryption with a high information-carrying capacity based on a stimulus-responsive hydrogen-bonded organic framework and a smartphone[J]. Chinese Chemical Letters, ;2023, 34(5): 107864. doi: 10.1016/j.cclet.2022.107864 shu

Information encryption with a high information-carrying capacity based on a stimulus-responsive hydrogen-bonded organic framework and a smartphone

State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin 541004, China

tianranlin@163.com

houli@gxnu.edu.cn

Received Date: 4 July 2022
Revised Date: 15 September 2022
Accepted Date: 27 September 2022
Available Online: 29 September 2022

Figures(4)

Information-carrying capacity has become an important factor in the development of encryption and anti-counterfeiting. Herein, a hydrogen-bonded organic framework (HOF-PyTTA) was developed as novel anti-counterfeiting ink without rare metals and a smartphone-based APP was written for encryption and anti-counterfeiting. We found that the fluorescence of HOF-PyTTA can be quenched by Fe³⁺ ions and recovered by the addition of ascorbic acid. And the fluorescence of HOF-PyTTA can be enhanced by the increasing concentrations of ethanol. Based on these stimulus-response properties, four anti-counterfeiting models with gradually increased security were studied. Mode one was printed by HOFs ink and decrypted by UV light. Mode two was based on HOF-PyTTA and CsPbBr₃ inks (or HOF-PyTTA-Fe³⁺) which are used to separately print the genuine and pirated information. A decryption reagent was applied to get the genuine information. Furthermore, we successfully construct a dynamic information encryption anti-counterfeiting model using a fluorescence array in combination with an information encryption anti-counterfeiting APP. The circular array is printed by several concentrations of HOF-PyTTA ink and different RGB thresholds are set with the help of the information encryption anti-counterfeiting APP, to obtain distinct encrypted anti-counterfeiting information, thus accomplishing a high information-carrying capacity.
- Hydrogen-bonded organic framework,
- Fluorescence array,
- Smartphone,
- Anti-counterfeiting,
- Message encryption
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