Citation: Siyu Chang, Jun Bu, Jinjin Li, Jin Lin, Zhenpeng Liu, Wenxiu Ma, Jian Zhang. Highly efficient electrocatalytic deuteration of acetylene to deuterated ethylene using deuterium oxide[J]. Chinese Chemical Letters, ;2023, 34(5): 107765. doi: 10.1016/j.cclet.2022.107765 shu

Highly efficient electrocatalytic deuteration of acetylene to deuterated ethylene using deuterium oxide

Siyu Chang ^a ,
Jun Bu ^a ,
Jinjin Li ^a ,
Jin Lin ^a ,
Zhenpeng Liu ^b ,
Wenxiu Ma ^a ,
Jian Zhang ^{a, b, *,}

a.
Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an 710129, China
b.
State Key Laboratory of Solidification Processing and School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710072, China

zhangjian@nwpu.edu.cn

Received Date: 5 April 2022
Revised Date: 6 August 2022
Accepted Date: 19 August 2022
Available Online: 21 August 2022

Figures(4)

Deuterated ethylene is an important building block for manufacturing various deuterated polyolefins and chemicals. However, low-cost and large-scale production of deuterated ethylene still remain a great challenge. Herein, with D₂O as the D source, we first propose an electrocatalytic deuteration strategy for continuous production of deuterated ethylene from acetylene under ambient conditions. Specially, Ag nanoparticles exhibit a very high deuterated ethylene Faradic efficiency of up to 99.3% at –0.6 V vs. reversible hydrogen electrode. Meanwhile, Ag nanoparticles achieve a deuterated ethylene production rate of 3.72 × 10³ mmol h^–1 g_cat^–1 and an excellent long-term stability with deuterated ethylene Faradaic efficiencies of ~95% in a two-electrode flow cell, which substantially outperform state-of-the-art values for previously reported deuterated alkenes. In-situ electrochemical Infrared absorption and Raman spectroscopies reveal superior acetylene absorption and formation of deuterated ethylene on Ag nanoparticles. This efficient electrocatalytic deuteration strategy opens a new window for continuous and economic production of deuterated alkenes.
- Electrocatalysis,
- Deuteration,
- Acetylene,
- Deuterated ethylene,
- Deuterium oxide
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