Citation: Qiangying Zhang, Xin Tan, Tao Yu. Effectively arsenic(Ⅴ) and fluoride removal in geothermal water using magnetic Fe₃O₄@MgO nanoparticles[J]. Chinese Chemical Letters, ;2023, 34(5): 107748. doi: 10.1016/j.cclet.2022.107748 shu

Effectively arsenic(Ⅴ) and fluoride removal in geothermal water using magnetic Fe₃O₄@MgO nanoparticles

Qiangying Zhang ^a ,
Xin Tan ^{a, b} ,
Tao Yu ^{c, *,}

a.
School of Science, Tibet University, Lhasa 850000, China
b.
School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, China
c.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China

yutao@tju.edu.cn

Received Date: 4 June 2022
Revised Date: 25 July 2022
Accepted Date: 12 August 2022
Available Online: 17 August 2022

Figures(5)

High residual concentration of arsenic and fluoride is a tricky problem to be solved in the process of reinjection after geothermal water utilization. We develop a method to simultaneously remove As(Ⅴ) and F⁻ from geothermal water using magnetic Fe₃O₄@MgO adsorbent, fabricated via a one-step method. The effects of pH, contact time, adsorbent dose and temperature on the removal efficiency were investigated systematically. The results show that the Fe₃O₄@MgO composite has a wide range of pH (2–11), ultrafast removal dynamics (As(Ⅴ): 2 min; F⁻: 30 min), and high removal efficiency (As(Ⅴ): 99.9%; F⁻: 96.6%). The adsorption kinetics follows the pseudo-second-order kinetics model, and the adsorption isotherm model fits Freundlich. The adsorption capacity of As(Ⅴ) and F⁻ can reach 123 and 98.4 mg/g, respectively. The exchange of As(Ⅴ) and F⁻ with Mg-hydroxyl groups hydrolysis by MgO was determined the adsorption mechanism. The Fe₃O₄@MgO adsorbent was capable of achieving the adsorption efficiency as high as 99.9% for As(Ⅴ) and 97.3% for F⁻ in real geothermal water, respectively. Hence, the proposed Fe₃O₄@MgO composite exhibited as an excellent adsorbent for the remediation of As- and F-contaminated geothermal water.
- Fe₃O₄@MgO adsorbent,
- Geothermal water,
- Arsenic(Ⅴ),
- Fluoride,
- Removal
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Effectively arsenic(Ⅴ) and fluoride removal in geothermal water using magnetic Fe3O4@MgO nanoparticles

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通讯作者: 陈斌, bchen63@163.com

Effectively arsenic(Ⅴ) and fluoride removal in geothermal water using magnetic Fe₃O₄@MgO nanoparticles