Citation: Yufei Zhen, Zhiqiang Sun, Ziye Jia, Caihong Liu, Shishu Zhu, Xueyan Li, Wei Wang, Jun Ma. Facile preparation of α-MnO₂ nanowires for assembling free-standing membrane with efficient Fenton-like catalytic activity[J]. Chinese Chemical Letters, ;2023, 34(3): 107664. doi: 10.1016/j.cclet.2022.07.007 shu

Facile preparation of α-MnO₂ nanowires for assembling free-standing membrane with efficient Fenton-like catalytic activity

Yufei Zhen ^a ,
Zhiqiang Sun ^{a, *,} ,
Ziye Jia ^a ,
Caihong Liu ^b ,
Shishu Zhu ^{c, d, **,} ,
Xueyan Li ^e ,
Wei Wang ^a ,
Jun Ma ^a

a.
School of Environment, State Key Laboratory of Urban Water Resources and Environment, Harbin Institute of Technology, Harbin 150090, China
b.
Key Laboratory of Eco-Environments in Three Gorges Reservoir Region, Ministry of Education, School of Urban Construction and Environmental Engineering, Chongqing University, Chongqing 400044, China
c.
School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China
d.
Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, Sun Yat-sen University, Guangzhou 510275, China
e.
School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China

^**

sunhit@hit.edu.cn

zhushsh6@mail.sysu.edu.cn

Received Date: 22 April 2022
Revised Date: 19 June 2022
Accepted Date: 6 July 2022
Available Online: 8 July 2022

Figures(5)

Assembling MnO₂ nanowires into macroscopic membrane is a promising engineered technology for catalyst separation and enhancement of Fenton-like reaction activity, yet its development is limited by the deficiencies in preparation and property modulation of the MnO₂ nanowires. In this work, we developed a facile method using C₂H₅OH and CH₃COOK as reductive and vital control reagents to react with KMnO₄ by hydrothermal reaction at 140 ℃ for 12 h, to prepare the ultralong α-MnO₂ nanowires up to tens of micrometers with high purity and aspect ratio. Such strategy not only had the advantages of being mild, easily controlled and environmental pollution-free, but also endowed α-MnO₂ nanowires with excellent ability as a Fenton catalyst when assembled into free-standing membrane for degrading phenolic compounds (k_obs = 0.0738 ~ 0.1695 min⁻¹) in a continuous flow reaction. The reactive oxygen species (i.e., ^•OH) from Fenton-like reaction were enriched within this α-MnO₂ nanowire membrane via nanoconfinement effect, which further enhanced the mass transportation of ^•OH available for phenolic contaminants. MnO₂ nanowire membrane using our method possessed the high practical potential for water purify due to its easy-preparation and enhanced catalytic performances.
- α-MnO₂ nanowires,
- Formation mechanism,
- Free-standing membrane,
- Fenton-like system
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Facile preparation of α-MnO2 nanowires for assembling free-standing membrane with efficient Fenton-like catalytic activity

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Facile preparation of α-MnO₂ nanowires for assembling free-standing membrane with efficient Fenton-like catalytic activity