Citation: Jingbin Li, Zhiwei Jiao, Junfang Li, Hua Bai, Guangcheng Xi. Plasmonic rhenium trioxide self-assembled microtubes for highly sensitive, stable and reproducible surface-enhanced Raman spectroscopy detection[J]. Chinese Chemical Letters, ;2023, 34(3): 107572. doi: 10.1016/j.cclet.2022.05.086 shu

Plasmonic rhenium trioxide self-assembled microtubes for highly sensitive, stable and reproducible surface-enhanced Raman spectroscopy detection

Jingbin Li ^{a, b, c} ,
Zhiwei Jiao ^{a, c, *,} ,
Junfang Li ^b ,
Hua Bai ^b ,
Guangcheng Xi ^{b, *,}

a.
College of Sciences, China Jiliang University, Hangzhou 310018, China
b.
Institute of Industrial and Consumer Product Safety, Chinese Academy of Inspection and Quarantine, Beijing 100176, China
c.
Key Laboratory of Intelligent Manufacturing Quality Big Data Tracing and Analysis of Zhejiang Province, China Jiliang University, Hangzhou 310018, China

jzwgj@163.com

xiguangcheng@caiq.org.cn

Received Date: 16 March 2022
Revised Date: 16 May 2022
Accepted Date: 26 May 2022
Available Online: 28 May 2022

Figures(4)

Compared with noble metals, improving the sensitivity of semiconducting surface-enhanced Raman scattering (SERS) substrates is of great significance to their fundamental research and practical application of Raman spectroscopy. Herein, a simple chemical method is developed to synthesize a rhenium trioxide (ReO₃) microtubes assembled with highly crystalline nanoparticles. The ReO₃ microtubes show a strong and well-defined surface plasmon resonance (SPR) behavior in visible region, which is rare for non-noble metals. As a low-cost SERS substrate, the plasmonic ReO₃ microtubes exhibit a Raman enhancement factor of 8.9 × 10⁵ and a lowest detection limit of 1.0 × 10⁻⁹ mol/L for phenolic pollutants. Moreover, these ReO₃ microtubule SERS substrates show excellent chemical stability and can resist the corrosion of strong acids and bases.
- SERS,
- ReO₃,
- Surface plasmon resonance,
- Microtubes,
- Self assembly
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