Citation: Peipei Jia, Yixiong Hu, Zhiyong Zeng, Yute Wang, Bo Song, Yanrong Jiang, Haitao Sun, Ming Wang, Wenwei Qiu, Lin Xu. Construction of FRET-based metallacycles with efficient photosensitization efficiency and photocatalytic activity[J]. Chinese Chemical Letters, ;2023, 34(1): 107511. doi: 10.1016/j.cclet.2022.05.025 shu

Construction of FRET-based metallacycles with efficient photosensitization efficiency and photocatalytic activity

Peipei Jia ^a ,
Yixiong Hu ^a ,
Zhiyong Zeng ^a ,
Yute Wang ^a ,
Bo Song ^a ,
Yanrong Jiang ^b ,
Haitao Sun ^b ,
Ming Wang ^a ,
Wenwei Qiu ^{a, *,} ,
Lin Xu ^{a, c, *,}

a.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Shanghai Frontiers Science Center of Molecule Intelligent Syntheses, Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China
b.
State Key Laboratory of Precision Spectroscopy, East China Normal University, Shanghai 200241, China
c.
Institute of Eco-Chongming, Shanghai 202162, China

wwqiu@chem.ecnu.edu.cn

lxu@chem.ecnu.edu.cn

Received Date: 24 December 2021
Revised Date: 8 May 2022
Accepted Date: 10 May 2022
Available Online: 16 May 2022

Figures(7)

The fabrication of highly effective photosensitizers has received considerable attention because of their attractive functions and applications in the fields of photodynamic therapy, photosynthesis, photocatalysis, etc. Thus, it is highly desirable to develop a new approach to enhance photosensitization efficiency. Herein, through coordination-driven self-assembly, a series of metallacycles with efficient fluorescence resonance energy transfer (FRET) were effectively constructed, which displayed higher photosensitization efficiency and photocatalytic activity than their model metallacycles without FRET due to broadband absorption and singlet energy transfer from the energy acceptor to the energy donor. Moreover, iodization of fluorophores induced a significant enhancement of the photosensitization efficiency and photocatalytic activity of the metallacycles. This research provides an efficient strategy for improving photosensitization efficiency and a promising platform for the preparation of effective photosensitizers and photocatalysts.
- Self-assembly,
- Metallacycle,
- FRET,
- Photosensitization,
- Photocatalytic
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