Citation: Qiang Deng, Luolan Wang, Jing Li, Qian Cheng, Xiaozhao Liu, Changdong Chen, Qimeng Zhang, Wentao Zhong, Hua Wang, Lijue Wu, Chenghao Yang. Constructing oxygen-deficient V₂O₃@C nanospheres for high performance potassium ion batteries[J]. Chinese Chemical Letters, ;2023, 34(3): 107372. doi: 10.1016/j.cclet.2022.03.095 shu

Constructing oxygen-deficient V₂O₃@C nanospheres for high performance potassium ion batteries

Qiang Deng ^a ,
Luolan Wang ^a ,
Jing Li ^a ,
Qian Cheng ^a ,
Xiaozhao Liu ^a ,
Changdong Chen ^a ,
Qimeng Zhang ^a ,
Wentao Zhong ^a ,
Hua Wang ^b ,
Lijue Wu ^b ,
Chenghao Yang ^{a, *,}

a.
Guangzhou Key Laboratory for Surface Chemistry of Energy Materials, New Energy Research Institute, School of Environment and Energy, South China University of Technology, Guangzhou 510006, China
b.
Guangdong Jiana Energy Technology Co., Ltd., Qingtang Town, Yingde 513056, China

esyangc@scut.edu.cn

Received Date: 16 March 2022
Accepted Date: 23 March 2022
Available Online: 28 March 2022

Figures(5)

Potassium ion batteries (PIBs) have been regarded as promising alternatives to lithium ion batteries (LIBs) on account of their abundant resource and low cost in large scale energy storage applications. However, it still remains great challenges to explore suitable electrode materials that can reversibly accommodate large size of potassium ions. Here, we construct oxygen-deficient V₂O₃ nanoparticles encapsulated in amorphous carbon shell (O_d-V₂O₃@C) as anode materials for PIBs by subtly combining the strategies of morphology and deficiency engineering. The MOF derived nanostructure along with uniform carbon coating layer can not only enables fast K⁺ migration and charge transfer kinetics, but also accommodate volume change and maintain structural stability. Besides, the introduction of oxygen deficiency intrinsically tunes the electronic structure of materials according to DFT calculation, and thus lead to improved electrochemical performance. When utilized as anode for PIBs, O_d-V₂O₃@C electrode exhibits superior rate capability (reversible capacities of 262.8, 227.8, 201.5, 179.8, 156.9 mAh/g at 100, 200, 500, 1000 and 2000 mA/g, respectively), and ultralong cycle life (127.4 mAh/g after 1000 cycles at 2 A/g). This study demonstrates a feasible way to realize high performance PIBs through morphology and deficiency engineering.
- V₂O₃@C,
- Nanospheres,
- Oxygen deficiency,
- Potassium ion batteries,
- Anode
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沈阳化工大学材料科学与工程学院沈阳 110142

Constructing oxygen-deficient V2O3@C nanospheres for high performance potassium ion batteries

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通讯作者: 陈斌, bchen63@163.com

Constructing oxygen-deficient V₂O₃@C nanospheres for high performance potassium ion batteries