Citation: Yuanyuan Liang, Lei Mei, Qiuyan Jin, Junshan Geng, Jingyang Wang, Kang Liu, Kongqiu Hu, Jipan Yu, Weiqun Shi. Hierarchical assembly of uranyl metallacycles involving macrocyclic hosts[J]. Chinese Chemical Letters, ;2022, 33(7): 3539-3542. doi: 10.1016/j.cclet.2022.03.092 shu

Hierarchical assembly of uranyl metallacycles involving macrocyclic hosts

Yuanyuan Liang ^{a, b} ,
Lei Mei ^{a, *,} ,
Qiuyan Jin ^{a, b} ,
Junshan Geng ^a ,
Jingyang Wang ^a ,
Kang Liu ^a ,
Kongqiu Hu ^a ,
Jipan Yu ^a ,
Weiqun Shi ^{a, *,}

a.
Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

meil@ihep.ac.cn

shiwq@ihep.ac.cn

Received Date: 31 January 2022
Revised Date: 20 March 2022
Accepted Date: 21 March 2022
Available Online: 24 March 2022

Figures(4)

Actinide metallacycles are an emerging class of functional coordination assemblies, but multi-level assembly from metallacycle units toward hierarchical supramolecular structures are still rarely investigated. In this work, we put forward a novel supramolecular inclusion-based method through introducing two macrocyclic hosts, cucurbit[7]uril (CB[7]) and cucurbit[8]uril (CB[8]) to facilitate hierarchical assembly of uranyl metallacycles with higher complexity, and successfully prepare two different kinds of uranyl metallacycle-based complexes with intriguing hierarchical structures, a CB[7]-based four-member molecular necklace ([4]MN) and a CB[8]-involved ring-in-ring supramolecular polymer chain. The results obtained here prove the feasibility of supramolecular inclusion for regulating coordination assembly of uranyl metallacycles and related hierarchical structures. It is believed that this method can be used to achieve the construction of actinide coordination assemblies with higher structural complexity.
- Metallacycle,
- Coordination self-assembly,
- Uranyl,
- Cucurbituril,
- Hierarchical structure,
- Molecular necklace
1. [1]
  B. Moulton, M.J. Zaworotko, Chem. Rev. 101 (2001) 1629-1658. doi: 10.1021/cr9900432
2. [2]
  H. Li, Z.J. Yao, D. Liu, G.X. Jin, Coord. Chem. Rev. 293 (2015) 139-157.
3. [3]
  D.W. Zhang, T.K. Ronson, J.R. Nitschke, Acc. Chem. Res. 51 (2018) 2423-2436. doi: 10.1021/acs.accounts.8b00303
4. [4]
  L. Chen, Q.H. Chen, M.Y. Wu, F.L. Jiang, M.C. Hong, Acc. Chem. Res. 48 (2015) 201-210. doi: 10.1021/ar5003076
5. [5]
  T.R. Cook, Y.R. Zheng, P.J. Stang, Chem. Rev. 113 (2013) 734-777. doi: 10.1021/cr3002824
6. [6]
  R. Chakrabarty, P.S. Mukherjee, P.J. Stang, Chem. Rev. 111 (2011) 6810-6918. doi: 10.1021/cr200077m
7. [7]
  T.R. Cook, P.J. Stang, Chem. Rev. 115 (2015) 7001-7045. doi: 10.1021/cr5005666
8. [8]
  W. Wang, Y.X. Wang, H.B. Yang, Chem. Soc. Rev. 45. (2016) 2656-2693. doi: 10.1039/C5CS00301F
9. [9]
  W.X. Gao, H.J. Feng, B.B. Guo, Y. Lu, G.X. Jin, Chem. Rev. 120 (2020) 6288-6325. doi: 10.1021/acs.chemrev.0c00321
10. [10]
  S. Datta, M.L. Saha, P.J. Stang, Acc. Chem. Res. 51 (2018) 2047-2063. doi: 10.1021/acs.accounts.8b00233
11. [11]
  R.S. Forgan, J.P. Sauvage, J.F. Stoddart, Chem. Rev. 111 (2011) 5434-5464. doi: 10.1021/cr200034u
12. [12]
  T.R. Cook, V. Vajpayee, M.H. Lee, P.J. Stang, K.W. Chi, Acc. Chem. Res. 46 (2013) 2464-2474. doi: 10.1021/ar400010v
13. [13]
  L. Xu, Y.X. Wang, L.J. Chen, H.B. Yang, Chem. Soc. Rev. 44 (2015) 2148-2167. doi: 10.1039/C5CS00022J
14. [14]
  Y.X. Hu, X.Y. Zhang, L. Xu, H.B. Yang, Isr. J. Chem. 59 (2019) 184-196. doi: 10.1002/ijch.201800102
15. [15]
  B.H. Northrop, H.B. Yang, P.J. Stang, Chem. Commun. 45 (2008) 5896-5908.
16. [16]
  L.J. Chen, H.B. Yang, Acc. Chem. Res. 51 (2018) 2699-2710. doi: 10.1021/acs.accounts.8b00317
17. [17]
  X.Q. Guo, L.P. Zhou, S.J. Hu, et al., J. Am. Chem. Soc. 143 (2021) 6202-6210. doi: 10.1021/jacs.1c01168
18. [18]
  Z. Wang, L.Z. He, B.Q. Liu, et al., J. Am. Chem. Soc. 142 (2020) 16409-16419. doi: 10.1021/jacs.0c07514
19. [19]
  C.L. Liu, R.L. Zhang, C.S. Lin, et al., J. Am. Chem. Soc. 139 (2017) 12474-12479. doi: 10.1021/jacs.7b05157
20. [20]
  X.Z. Li, L.P. Zhou, L.L. Yang, et al., J. Am. Chem. Soc. 139 (2017) 8237-8244. doi: 10.1021/jacs.7b02764
21. [21]
  X.Z. Li, L.P. Zhou, L.L. Yan, et al., Nat. Commun. 9 (2018) 547. doi: 10.1038/s41467-018-02940-7
22. [22]
  P. Thuery, C. Villiers, J. Jaud, M. Ephritikhine, B. Masci, J. Am. Chem. Soc. 126 (2004) 6838-6839. doi: 10.1021/ja0485964
23. [23]
  S. Wu, L. Mei, K.Q. Hu, et al., J. Inorg. Mater. 118 (2019) 243-249.
24. [24]
  J. Lee, J.T. Brewster, B. Song, et al., Chem. Commun. 54 (2018) 9422-9425. doi: 10.1039/C8CC05160G
25. [25]
  S. Pasquale, S. Sattin, E.C. Escudero-Adan, M. Martinez-Belmonte, J. de Mendoza, Nat. Commun. 3 (2012) 785. doi: 10.1038/ncomms1793
26. [26]
  L. Mei, P. Ren, Q.Y. Wu, et al., J. Am. Chem. Soc. 142 (2020) 16538-16545. doi: 10.1021/jacs.0c08048
27. [27]
  L.W. Cheng, C.Y. Liang, W. Liu, et al., J. Am. Chem. Soc. 142 (2020) 16218-16222. doi: 10.1021/jacs.0c08117
28. [28]
  L. Shao, X.Q. Hu, K. Sikligar, G.A. Baker, J.L. Atwood, Acc. Chem. Res. 54 (2021) 3191-3203. doi: 10.1021/acs.accounts.1c00275
29. [29]
  D. Fujita, Y. Ueda, S. Sato, N. Mizuno, T. Kumasaka, M. Fujita, Nature 540 (2016) 563-566. doi: 10.1038/nature20771
30. [30]
  H.B. Qiu, Z.M. Hudson, M.A. Winnik, I. Manners, Science 347 (2015) 1329- 1332. doi: 10.1126/science.1261816
31. [31]
  P.J. Santos, P.A. Gabrys, L.Z. Zornberg, M.S. Lee, R.J. Macfarlane, Nature 591 (2021) 586-591. doi: 10.1038/s41586-021-03355-z
32. [32]
  D.D. Boehr, R. Nussinov, P.E. Wright, Nat. Chem. Biol. 5 (2009) 789-796. doi: 10.1038/nchembio.232
33. [33]
  J.M. Lehn, Chem. Soc. Rev. 46 (2017) 2378-2379. doi: 10.1039/C7CS00115K
34. [34]
  D.Y. Xia, P. Wang, X.F. Ji, et al., Chem. Rev. 120 (2020) 6070-6123. doi: 10.1021/acs.chemrev.9b00839
35. [35]
  J.M. Lehn, Abstr. Pap. Am. Chem. S. 199 (1990) 399.
36. [36]
  L. Mei, Z.N. Xie, K.Q. Hu, et al., Chem. Eur. J. 23 (2017) 13995-14003. doi: 10.1002/chem.201702752
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