Citation: Xiuling Zhang, Yongzheng Zhang, Wenfeng Zhou, Huiling Liu, Dashuai Zhang, Hui Hu, Chao Lv, Suijun Liu, Longlong Geng. Construction of novel cluster-based MOF as multifunctional platform for CO₂ catalytic transformation and dye selective adsorption[J]. Chinese Chemical Letters, ;2023, 34(3): 107368. doi: 10.1016/j.cclet.2022.03.091 shu

Construction of novel cluster-based MOF as multifunctional platform for CO₂ catalytic transformation and dye selective adsorption

Xiuling Zhang ^{a, b, 1} ,
Yongzheng Zhang ^{a, 1} ,
Wenfeng Zhou ^{a, b} ,
Huiling Liu ^a ,
Dashuai Zhang ^{a, b, c, *,} ,
Hui Hu ^a ,
Chao Lv ^a ,
Suijun Liu ^{c, *,} ,
Longlong Geng ^{a, b, *,}

a.
College of Chemistry and Chemical Engineering, Dezhou University, Dezhou 253023, China
b.
School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255000, China
c.
Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry, School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

dashuai_74@163.com

sjliu@jxust.edu.cn

llgeng@126.com

Received Date: 17 January 2022
Revised Date: 5 March 2022
Accepted Date: 21 March 2022
Available Online: 25 March 2022

Figures(3)

Synthetic conditions and ligands are the key structural defining factors of metal–organic frameworks (MOFs). Therefore, reasonable optimization of these aspects is considered to be an effective means for designing materials with novel structures and target functions. Herein, two novel Co(Ⅱ)-based MOFs, namely [Co(HL)(dibp)]_n (HL-8) and {[Co₂(L)(OH)(dibp)]·DMA}_n (HL-9) (H₃L = 2′, 6′-dimethyl-[1,1′-biphenyl]-3,4′,5-tricarboxylic acid; dibp = 4,4′-di(1H-imidazol-1-yl)-1,1′-biphenyl]), have been hydrothermally synthesized and structurally characterized. HL-8 crystallizes in the orthorhombic system (Pna2₁) with a grid layer structure, while HL-9 crystallizes in the monoclinic P2₁/n space group assembled through Co₄(OH)₂ clusters with organic ligands. Remarkably, benefiting from the finite cage-like structure, HL-9 exhibited enhanced performance in carbon dioxide (CO₂) adsorption/catalytic transformation and excellent size selectivity during dye molecular adsorption process.
- Metal–organic frameworks,
- Metal cluster,
- Catalysis,
- CO₂ cycloaddition,
- Dye separation
1. [1]
  H. Furukawa, K.E. Cordova, M. O'Keeffe, O.M. Yaghi, Science 341 (2013) 1230444. doi: 10.1126/science.1230444
2. [2]
  X.J. Kong, J.R. Li, Engineering 7 (2021) 1115–1139. doi: 10.1016/j.eng.2021.07.001
3. [3]
  G. Huang, L. Yang, Q. Yin, et al., Angew. Chem. Int. Ed. 59 (2020) 4385–4390. doi: 10.1002/anie.201916649
4. [4]
  L. Li, Z.B. Fang, W. Deng, et al., CCS Chem. 3 (2021) 2839–2849.
5. [5]
  Y. Zhou, L. Qin, M.K. Wu, L. Han, Cryst. Growth Des. 18 (2018) 5738–5744. doi: 10.1021/acs.cgd.8b00895
6. [6]
  F. Bi, X. Zhang, J. Chen, Y. Yang, Y. Wang, Appl. Catal. B: Environ. 269 (2020) 118767. doi: 10.1016/j.apcatb.2020.118767
7. [7]
  D.S. Zhang, Q. Gao, Z. Chang, et al., Adv. Mater. 30 (2018) 1804715. doi: 10.1002/adma.201804715
8. [8]
  J.Q. Liu, Z.D. Luo, Y. Pan, et al., Coord. Chem. Rev. 406 (2020) 213145. doi: 10.1016/j.ccr.2019.213145
9. [9]
  W. Du, Y.L. Bai, Z. Yang, et al., Chin. Chem. Lett. 31 (2020) 2309–2313. doi: 10.1016/j.cclet.2020.04.017
10. [10]
  L. He, M.X. Li, F. Chen, et al., J. Hazard. Mater. 417 (2021) 126113. doi: 10.1016/j.jhazmat.2021.126113
11. [11]
  J. He, Y. Xu, Z. Xiong, et al., Chemosphere 256 (2020) 127056. doi: 10.1016/j.chemosphere.2020.127056
12. [12]
  H. Hu, D. Zhang, H. Liu, et al., Chin. Chem. Lett. 32 (2021) 557–560. doi: 10.1016/j.cclet.2020.02.028
13. [13]
  B. Han, X. Ou, Z. Deng, et al., Angew. Chem. Int. Ed. 57 (2018) 16811–16815. doi: 10.1002/anie.201811545
14. [14]
  Y. Wang, Y. Pu, D. Yuan, et al., ACS App. Mater. Interfaces 11 (2019) 44058–44068. doi: 10.1021/acsami.9b12886
15. [15]
  X. Zhang, Y. Jin, G. Wang, et al., J. Solid State Chem. 296 (2021) 121979. doi: 10.1016/j.jssc.2021.121979
16. [16]
  G. Si, X. Kong, T. He, et al., Chin. Chem. Lett. 32 (2021) 918–922. doi: 10.1016/j.cclet.2020.07.023
17. [17]
  H. Bi, Z. Yin, X. Cao, et al., Adv. Mater. 25 (2013) 5916–5921. doi: 10.1002/adma.201302435
18. [18]
  L. Geng, G. Li, X. Zhang, et al., J. Solid State Chem. 296 (2021) 121960. doi: 10.1016/j.jssc.2021.121960
19. [19]
  Q. Wei, B.D. Ge, J. Zhang, et al., Chem. Asian J. 14 (2019) 269–277. doi: 10.1002/asia.201801555
20. [20]
  Y. Peng, Y. Li, Y. Ban, et al., Science 346 (2014) 1356–1359. doi: 10.1126/science.1254227
21. [21]
  L. Cao, T. Wang, C. Wang, Chin. J. Chem. 36 (2018) 754–764. doi: 10.1002/cjoc.201800144
22. [22]
  A.X. Tian, M.L. Yang, Y.B. Fu, J. Ying, X.L. Wang, Inorg. Chem. 58 (2019) 4190–4200. doi: 10.1021/acs.inorgchem.8b03248
23. [23]
  X. Zhang, H. Cheng, H. Zhang, Adv. Mater. 29 (2017) 1701704. doi: 10.1002/adma.201701704
24. [24]
  X. Wang, T. Zhang, Y. Li, et al., Inorg. Chem. 59 (2020) 17583–17590. doi: 10.1021/acs.inorgchem.0c02798
25. [25]
  A. Liu, X. Peng, Q. Jin, et al., ACS Appl. Mater. Interfaces 11 (2019) 4686–4700. doi: 10.1021/acsami.8b20447
26. [26]
  M. Položij, M. Rubeš, J. Čejka, P. Nachtigall, ChemCatChem 6 (2014) 2821–2824. doi: 10.1002/cctc.201402411
27. [27]
  S. Aslam, J. Zeng, F. Subhan, et al., J. Colloid Interface Sci. 505 (2017) 186–195. doi: 10.1016/j.jcis.2017.05.090
28. [28]
  L. Geng, W. Zhou, X. Wang, et al., J. Alloy. Compd. 888 (2021) 161494. doi: 10.1016/j.jallcom.2021.161494
29. [29]
  R. Mohammadian, M.K. Alavijeh, N. Kamyar, M.M. Amini, A. Shaabani, Polyhedron 156 (2018) 174–187. doi: 10.1016/j.poly.2018.09.029
30. [30]
  L. Jiao, J. Wang, H.L. Jiang, Acc. Mater. Res. 2 (2021) 327–339. doi: 10.1021/accountsmr.1c00009
31. [31]
  C. Gu, J. Li, G. Yang, et al., Chin. Chem. Lett. 31 (2020) 2263–2267. doi: 10.1016/j.cclet.2020.02.044
32. [32]
  M. Peng, C. Dong, R. Gao, et al., ACS Cent. Sci. 7 (2021) 262–273. doi: 10.1021/acscentsci.0c01486
33. [33]
  Y. Bai, Y. Dou, L.H. Xie, et al., Chem. Soc. Rev. 45 (2016) 2327–2367. doi: 10.1039/C5CS00837A
34. [34]
  X. Zhang, Y.Z. Zhang, Y.Q. Jin, et al., Inorg. Chem. 59 (2020) 11728–11735. doi: 10.1021/acs.inorgchem.0c01611
35. [35]
  Y.Z. Zhang, T. He, X.J. Kong, et al., ACS Mater. Lett. 1 (2019) 20–24. doi: 10.1021/acsmaterialslett.9b00021
36. [36]
  H.Z. Li, D.Y. Du, Y. Sun, F. Wang, J. Zhang, Dalton Trans. 49 (2020) 4690–4693. doi: 10.1039/D0DT00791A
37. [37]
  J. Li, W.J. Li, S.C. Xu, et al., Inorg. Chem. Commun. 106 (2019) 70–75. doi: 10.1016/j.inoche.2019.05.031
38. [38]
  R. Dalapati, B. Sakthivel, A. Dhakshinamoorthy, et al., CrystEngComm 18 (2016) 7855–7864. doi: 10.1039/C6CE01704E
39. [39]
  W.G. Cui, G.Y. Zhang, T.L. Hu, X.H. Bu, Coord. Chem. Rev. 387 (2019) 79–120. doi: 10.1016/j.ccr.2019.02.001
40. [40]
  H. Chen, T. Hu, L. Fan, X. Zhang, Inorg. Chem. 60 (2021) 1028–1036. doi: 10.1021/acs.inorgchem.0c03134
41. [41]
  Y.J. Chen, X. Huang, Y. Chen, et al., CCS Chem. 1 (2019) 561–570. doi: 10.31635/ccschem.019.20190028
42. [42]
  X. Zhang, R.H. Zhang, H. Hu, et al., Dalton Trans. 49 (2020) 2058–2062. doi: 10.1039/C9DT04736K
43. [43]
  J.J. Lv, F.L. Cao, M.L. Wang, et al., Polyhedron 195 (2021) 114982. doi: 10.1016/j.poly.2020.114982
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Construction of novel cluster-based MOF as multifunctional platform for CO2 catalytic transformation and dye selective adsorption

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通讯作者: 陈斌, bchen63@163.com

Construction of novel cluster-based MOF as multifunctional platform for CO₂ catalytic transformation and dye selective adsorption