Citation: Yajie Li, Geng Zhang, Bin Chen, Wei Zhao, Liting Sha, Da Wang, Jia Yu, Siqi Shi. Understanding the separator pore size inhibition effect on lithium dendrite via phase-field simulations[J]. Chinese Chemical Letters, ;2022, 33(6): 3287-3290. doi: 10.1016/j.cclet.2022.03.065 shu

Understanding the separator pore size inhibition effect on lithium dendrite via phase-field simulations

Yajie Li ^a ,
Geng Zhang ^{b, *,} ,
Bin Chen ^a ,
Wei Zhao ^a ,
Liting Sha ^a ,
Da Wang ^a ,
Jia Yu ^c ,
Siqi Shi ^{a, c, d, **,}

a.
School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China
b.
Physical Science and Engineering Division, King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia
c.
Materials Genome Institute, Shanghai University, Shanghai 200444, China
d.
Zhejiang Laboratory, Hangzhou 311100, China

geng.zhang@kaust.edu.sa

sqshi@shu.edu.cn

Received Date: 9 March 2022
Revised Date: 14 March 2022
Accepted Date: 15 March 2022
Available Online: 17 March 2022

Figures(4)

Dendrite growth in lithium-ion batteries may bring thermal run-away especially at high current densities, which remains the major bottleneck to implement safe and fast charging for portable electronic devices or electronical vehicles. Designing dendrite inhibition separators with proper pore size is considered to be one of the most promising strategies to guarantee the battery safety. However, due to the impossible observation of lithium-ion distribution under separator by experiments, the underlying dendrite inhibition mechanism is still not fully understood. Here, we apply the phase-field model, which takes the separator phase into account to construct the electrochemical system total free energy, to study the ion re-distribution behavior of porous separator and understand the pore size inhibition effect on lithium dendrite. The numerical results indicate that separator with smaller pore size is beneficial to smoother electrodeposition, since the lithium-ion concentration on the electrode surface is more uniform under denser separator pores, when their sizes is larger than the critical nucleus. The proposed model could capture the physicochemical process of electrodeposition under multiphase structures, so it could also be used to explore dendrite growth under composite electrodes and composite solid electrolytes.
- Lithium-ion batteries,
- Pore size,
- Ionic distribution,
- Phase-field simulations,
- Dendrite growth
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