Citation: An-An Zhang, Rui Wang, Hai-Bo Huang, Tian-Fu Liu, Rong Cao. Post-modification of metal-organic framework for improved CO₂ photoreduction efficiency[J]. Chinese Chemical Letters, ;2023, 34(3): 107311. doi: 10.1016/j.cclet.2022.03.034 shu

Post-modification of metal-organic framework for improved CO₂ photoreduction efficiency

An-An Zhang ^{a, b, 1} ,
Rui Wang ^{a, b, 1} ,
Hai-Bo Huang ^b ,
Tian-Fu Liu ^{b, c} ,
Rong Cao ^{a, b, c, *,}

a.
Department of Chemistry, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350002, China

rcao@fjirsm.ac.cn

Received Date: 5 January 2022
Revised Date: 30 January 2022
Accepted Date: 10 March 2022
Available Online: 13 March 2022

Figures(4)

Utilizing metal-organic frameworks (MOFs) to design photocatalysts for CO₂ reduction catalysts is an excellent idea but currently restricted by the relatively low activity. Enhancing CO₂ affinity and tuning the oxidation state of metal clusters in MOFs might be a solution to improve the catalytic performance. Herein, the Cl-bridge atoms in the metal clusters of a cobalt MOF were easily exchanged with OH⁻, which simultaneously oxidized a portion of Co(Ⅱ) to Co(Ⅲ) and resulted in a much enhanced photocatalytic activity for CO₂ reduction. In contrast, the original framework does not exhibit such superior activity. Comprehensive characterizations on their physicochemical properties revealed that the introduction of hydroxyl group not only greatly increases the CO₂ affinity but also alters the oxidation state of metal clusters, resulting in significantly improved photocatalytic activities for CO₂ reduction. This work provides important insight into the design of efficient photocatalysts.
- Metal-organic framework,
- Post-modification,
- Hydroxyl group,
- Ion exchange,
- CO₂ photoreduction
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Post-modification of metal-organic framework for improved CO2 photoreduction efficiency

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通讯作者: 陈斌, bchen63@163.com

Post-modification of metal-organic framework for improved CO₂ photoreduction efficiency