Citation: Xianrong Gu, Yang Qin, Su Sun, Lidan Guo, Xiangwei Zhu, Xiangnan Sun. High-performance floating-gate organic phototransistors based on n-type core-expanded naphthalene diimides[J]. Chinese Chemical Letters, ;2023, 34(3): 107306. doi: 10.1016/j.cclet.2022.03.029 shu

High-performance floating-gate organic phototransistors based on n-type core-expanded naphthalene diimides

Xianrong Gu ^{a, b, 1} ,
Yang Qin ^{a, b, 1} ,
Su Sun ^{a, 1} ,
Lidan Guo ^{a, *,} ,
Xiangwei Zhu ^{a, *,} ,
Xiangnan Sun ^{a, b, c, *,}

a.
Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China
b.
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
c.
School of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, China

guold@nanoctr.cn

zhuxw@nanoctr.cn

sunxn@nanoctr.cn

Received Date: 26 January 2022
Revised Date: 15 February 2022
Accepted Date: 7 March 2022
Available Online: 10 March 2022

Figures(5)

In the field of organic phototransistor, achieving both broad-spectral and high photosensitivity has always been a big challenge. The innovation of device structure has previously proven to be a possible solution to this problem. Here in this study, a novel organic phototransistor based on a high mobility n-type small molecule as the conducting layer and an isolated bulk heterojunction light-absorbing layer as the floating gate has been demonstrated in this study. With the special designed device structure, the phototransistor shows extremely high sensitivity to broad spectral and weak light irradiation, and the photoresponsivity and photocurrent/dark-current ratio of the device can reach up to 4840 mA/W and 1.8 × 10⁵ respectively. For conclusion, this study suggests a potential way to obtain high-performance phototransistors at room temperature, which will further promote the commercial application of organic phototransistors.
- Organic phototransistor,
- Bulk heterojunction,
- n-Type small molecule,
- Broad spectral photoresponse,
- Weak light irradiation
1. [1]
  S. Fratini, M. Nikolka, A. Salleo, G. Schweicher, H. Sirringhaus, Nat. Mater. 19 (2020) 491–502. doi: 10.1038/s41563-020-0647-2
2. [2]
  Y. Wang, Q. Gong, Q. Miao, Mater. Chem. Front. 4 (2020) 3505–3520. doi: 10.1039/D0QM00202J
3. [3]
  Y. Huang, D.L. Elder, A.L. Kwiram, et al., Adv. Mater. 33 (2021) 1904239. doi: 10.1002/adma.201904239
4. [4]
  P.C.Y. Chow, T. Someya, Adv. Mater. 32 (2020) 1902045. doi: 10.1002/adma.201902045
5. [5]
  H. Sirringhaus, Adv. Mater. 26 (2014) 1319–1335. doi: 10.1002/adma.201304346
6. [6]
  L. Lu, T. Zheng, Q. Wu, et al., Chem. Rev. 115 (2015) 12666–12731. doi: 10.1021/acs.chemrev.5b00098
7. [7]
  C. Liu, X. Liu, W. Lai, W. Huang, Adv. Mater. 30 (2018) 1802466. doi: 10.1002/adma.201802466
8. [8]
  S.A. McDonald, G. Konstantatos, S. Zhang, et al., Nat. Mater. 4 (2005) 138–142. doi: 10.1038/nmat1299
9. [9]
  H. Dong, H. Zhu, Q. Meng, X. Gong, W. Hu, Chem. Soc. Rev. 41 (2012) 1754–1808. doi: 10.1039/C1CS15205J
10. [10]
  C. Zhao, M.U. Ali, J. Ning, H. Meng, Front. Phys. 16 (2021) 43202. doi: 10.1007/s11467-021-1053-1
11. [11]
  D. Ji, T. Li, J. Liu, et al., Nat. Commun. 10 (2019) 12. doi: 10.1038/s41467-018-07943-y
12. [12]
  X. Xu, W. Deng, X. Zhang, et al., ACS Nano 13 (2019) 5910–5919. doi: 10.1021/acsnano.9b01734
13. [13]
  D. Baierl, L. Pancheri, M. Schmidt, et al., Nat. Commun. 3 (2012) 1175. doi: 10.1038/ncomms2180
14. [14]
  H.L. Park, J. Jun, M.H. Kim, S.H. Lee, Org. Electron. 100 (2022) 106385. doi: 10.1016/j.orgel.2021.106385
15. [15]
  K. Baeg, M. Binda, D. Natali, M. Caironi, Y. Noh, Adv. Mater. 25 (2013) 4267–4295. doi: 10.1002/adma.201204979
16. [16]
  Y. Guo, G. Yu, Y. Liu, Adv. Mater. 22 (2010) 4427–4447. doi: 10.1002/adma.201000740
17. [17]
  F. Pelayo García de Arquer, A. Armin, P. Meredith, E.H. Sargent, Nat. Rev. Mater. 2 (2017) 16100. doi: 10.1038/natrevmats.2016.100
18. [18]
  Y. He, J.T.E. Quinn, D. Hou, J.H.L. Ngai, Y. Li, J. Mater. Chem. C 5 (2017) 12163–12171. doi: 10.1039/C7TC03584E
19. [19]
  B. Lucas, T. Trigaud, C. Videlot-Ackermann, Polym. Int. 61 (2012) 374–389. doi: 10.1002/pi.3213
20. [20]
  P. Gu, Y. Yao, L. Feng, S. Niu, H. Dong, Polym. Chem. 6 (2015) 7933–7944. doi: 10.1039/C5PY01373A
21. [21]
  C. Wang, X. Zhang, W. Hu, Chem. Soc. Rev. 49 (2020) 653–670. doi: 10.1039/C9CS00431A
22. [22]
  H. Huang, L. Jiang, J. Peng, et al., Chem. Mater. 33 (2021) 8089–8096. doi: 10.1021/acs.chemmater.1c02839
23. [23]
  D. Li, J. Du, Y. Tang, et al., Adv. Funct. Mater. 31 (2021) 2105887. doi: 10.1002/adfm.202105887
24. [24]
  X. Luo, L. Du, W. Lv, et al., Synth. Met. 210 (2015) 230–235. doi: 10.1016/j.synthmet.2015.10.007
25. [25]
  G. Lu, J. Blakesley, S. Himmelberger, et al., Nat. Commun. 4 (2013) 1588. doi: 10.1038/ncomms2587
26. [26]
  G. Wang, K. Huang, Z. Liu, et al., ACS Appl. Mater. Interfaces 10 (2018) 36177–36186. doi: 10.1021/acsami.8b12009
27. [27]
  J. Tao, D. Liu, J. Jing, et al., Adv. Mater. 33 (2021) 2105466. doi: 10.1002/adma.202105466
28. [28]
  S. Kim, D. Lee, J. Lee, et al., Chem. Mater. 33 (2021) 7499–7508. doi: 10.1021/acs.chemmater.1c02409
29. [29]
  H. Han, S. Nam, J. Seo, et al., Sci. Rep. 5 (2015) 16457. doi: 10.1038/srep16457
30. [30]
  P.C.Y. Chow, N. Matsuhisa, P. Zalar, et al., Nat. Commun. 9 (2018) 4546. doi: 10.1038/s41467-018-06907-6
31. [31]
  H. Zhang, Y. Zhang, X. Song, et al., ACS Photonics 4 (2017) 584–592. doi: 10.1021/acsphotonics.6b00896
32. [32]
  Y. Zhang, Y. Yuan, J. Huang, Adv. Mater. 29 (2017) 1603969. doi: 10.1002/adma.201603969
33. [33]
  Y.S. Rim, Y.M. Yang, S. Bae, et al., Adv. Mater. 27 (2015) 6885–6891. doi: 10.1002/adma.201502996
34. [34]
  A. Pierre, A. Gaikwad, A.C. Arias, Nature Photon. 11 (2017) 193–199. doi: 10.1038/nphoton.2017.15
35. [35]
  A. Ng, X. Liu, W.Y. Jim, et al., J. Appl. Polym. Sci. 131 (2014) 39776.
36. [36]
  J. Ortigoza-Diaz, K. Scholten, C. Larson, et al., Micromachines 9 (2018) 422. doi: 10.3390/mi9090422
37. [37]
  X. Gao, C. Di, Y. Hu, et al., J. Am. Chem. Soc. 132 (2010) 3697–3699. doi: 10.1021/ja910667y
38. [38]
  R. Kroon, M. Lenes, J.C. Hummelen, P.W.M. Blom, B. de Boer, Polym. Rev. 48 (2008) 531–582. doi: 10.1080/15583720802231833
39. [39]
  B.M. Savoie, N.E. Jackson, L.X. Chen, T.J. Marks, M.A. Ratner, Acc. Chem. Res. 47 (2014) 3385–3394. doi: 10.1021/ar5000852
40. [40]
  N. Marjanović, T.B. Singh, G. Dennler, et al., Org. Electron. 7 (2006) 188–194. doi: 10.1016/j.orgel.2006.01.002
41. [41]
  S. Koul, N. Hakim, Trans. Electr. Electron. Mater. 19 (2018) 319–329. doi: 10.1007/s42341-018-0053-5
42. [42]
  F. Huang, Y. Li, H. Xia, et al., Carbon 118 (2017) 666–674. doi: 10.1016/j.carbon.2017.03.091
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