Citation: Fei Yan, Jingnan Cui, Chao Wang, Xiangge Tian, Dawei Li, Yan Wang, Baojing Zhang, Lei Feng, Shanshan Huang, Xiaochi Ma. Real-time quantification for sulfite using a turn-on NIR fluorescent probe equipped with a portable fluorescence detector[J]. Chinese Chemical Letters, ;2022, 33(9): 4219-4222. doi: 10.1016/j.cclet.2022.03.006 shu

Real-time quantification for sulfite using a turn-on NIR fluorescent probe equipped with a portable fluorescence detector

Fei Yan ^{a, b} ,
Jingnan Cui ^c ,
Chao Wang ^{a, *,} ,
Xiangge Tian ^a ,
Dawei Li ^a ,
Yan Wang ^a ,
Baojing Zhang ^a ,
Lei Feng ^{b, d, *,} ,
Shanshan Huang ^a ,
Xiaochi Ma ^{a, b, *,}

a.
College of Pharmacy, Dalian Key Laboratory of Metabolic Target Characterization and Traditional Chinese Medicine Intervention, Academy of Integrative Medicine, Dalian Medical University, Dalian 116044, China
b.
Second Affiliated Hospital, Dalian Medical University, Dalian 116044, China
c.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China
d.
School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China

wach_edu@sina.com

leifeng@dmu.edu.cn

maxc1978@163.com

Received Date: 14 November 2021
Revised Date: 25 February 2022
Accepted Date: 2 March 2022
Available Online: 4 March 2022

Figures(5)

Sulfur dioxide and its derivative sulfite widely existed in air, water as the environment pollutant. Sulfite is also commonly used as preservative and additive in fresh fruits, vegetables, wines and pharmaceutical materials. Due to sulfite is closely related with human diseases, it is very urgent for the sensitive and rapid quantification of sulfite in various samples. In our study, a turn-on near infrared (NIR) fluorescent probe (MDQ) was developed for sulfite detection based on a Michael addition reaction, with high sensitivity (LOD 4.16 nmol/L), selectivity and fast response time (400 s). Using MDQ, a quantify method for sulfite in traditional Chinese medicines (TCMs) was developed with the advantages of high precision, accuracy and convenient operation. Furthermore, according to the photophysical property of MDQ, a portable fluorescence detector is designed to quantify sulfite for TCMs and surface water in Dalian city of China. Therefore, the developed fluorescent probe MDQ and portable fluorescent detector as a rapid inspection instrument were successfully used to real-time monitor the sulfite in various complex samples.
- Sulfite,
- Fluorescent probe,
- Portable fluorescence detector,
- Traditional Chinese medicine,
- Surface water
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