Citation: Heshan Zheng, Yunying Hou, Shuo Li, Jun Ma, Jun Nan, Nannan Wang. Study on catalytic mechanisms of Fe₃O₄-rGO_x in three typical advanced oxidation processes for tetracycline hydrochloride degradation[J]. Chinese Chemical Letters, ;2023, 34(1): 107253. doi: 10.1016/j.cclet.2022.02.058 shu

Study on catalytic mechanisms of Fe₃O₄-rGO_x in three typical advanced oxidation processes for tetracycline hydrochloride degradation

Heshan Zheng ^a ,
Yunying Hou ^a ,
Shuo Li ^{a, b, c, **,} ,
Jun Ma ^{a, b} ,
Jun Nan ^{b, c} ,
Nannan Wang ^{d, *,}

a.
College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, China
b.
Urban Water Resources Development and Northern National Engineering Research Center, Harbin 150090, China
c.
School of Environment, Harbin Institute of Technology, Harbin 150090, China
d.
Department of Environmental Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China

^**

shuo_105@163.com

wnn_flying@163.com

Received Date: 2 December 2021
Revised Date: 19 January 2022
Accepted Date: 20 February 2022
Available Online: 23 February 2022

Figures(4)

This study explored the catalytic mechanism and performance impacted by the materials ratio of Fe₃O₄-GO_x composites in three typical advanced oxidation processes (AOPs) of O₃, peroxodisulfate (PDS) and photo-Fenton processes for tetracycline hydrochloride (TCH) degradation. The ratio of GO in the Fe₃O₄-GO_x composites exhibited different trends of degradation capacity in each AOPs based on different mechanisms. Fe₃O₄-rGO_20wt% exhibited the optimum catalytic performance which enhanced the ozone decomposition efficiency from 33.48% (ozone alone) to 51.83% with the major reactive oxygen species (ROS) of O₂^•−. In PDS and photo-Fenton processes, Fe₃O₄-rGO_5wt% had the highest catalytic performance in PDS and H₂O₂ decomposition for SO₄^•‒, and ^•OH generation, respectively. Compared with using PDS alone, PDS decomposition rate and TCH degradation rate could be increased by 5.97 and 1.73 times under Fe₃O₄-rGO_5wt% catalysis. In the photo-Fenton system, Fe₃O₄-rGO_5wt% with the best catalyst performance in H₂O₂ decomposition, and TCH degradation rate increased by 2.02 times compared with blank group. Meantime, the catalytic mechanisms in those systems of that the ROS produced by conversion between Fe²⁺/Fe³⁺ were also analyzed.
- Advanced oxidation progresses,
- Fe₃O₄,
- Graphene oxide,
- Mechanism,
- Reactive oxygen species
1. [1]
  T. Xia, Y. Lin, W. Li, M. Ju, Chin. Chem. Lett. 32 (2021) 2975–2987. doi: 10.1016/j.cclet.2021.02.058
2. [2]
  X. Feng, H. Guo, K. Patel, H. Zhou, X. Lou, Chem. Eng. J. 244 (2014) 327–334. doi: 10.1016/j.cej.2014.01.075
3. [3]
  J.N. Jing, C.J. Cao, S.J. Ma, et al., Chem. Eng. J. 407 (2021) 126890. doi: 10.1016/j.cej.2020.126890
4. [4]
  Y. Zhang, J.B. Zhou, X. Chen, et al., Chem. Eng. J. 369 (2019) 745–757. doi: 10.1016/j.cej.2019.03.108
5. [5]
  J. Hang, X. Tian, Y. Nie, et al., Environ. Sci. Technol. 51 (2017) 12699–12706. doi: 10.1021/acs.est.7b04503
6. [6]
  K. Roy, V.S. Moholkar, Chem. Eng. J. 386 (2020) 121294. doi: 10.1016/j.cej.2019.03.170
7. [7]
  T. Liu, K. Wu, M. Wang, et al., Chemosphere 262 (2021) 127845. doi: 10.1016/j.chemosphere.2020.127845
8. [8]
  L.L. Kong, L.Y. Fan, Chin. Chem. Lett. 27 (2016) 827–831. doi: 10.1016/j.cclet.2016.01.055
9. [9]
  Y. Su, M. Lu, R. Su, et al., Chin. Chem. Lett. 33 (2022) 2573–2578. doi: 10.1016/j.cclet.2021.08.078
10. [10]
  J. Wu, M. Lin, X.L. Weng, et al., Chem. Eng. J. 408 (2021) 127273. doi: 10.1016/j.cej.2020.127273
11. [11]
  J. Wu, J. Bai, Z. Wang, et al., Environ. Technol. 43 (2022) 95–106. doi: 10.1080/09593330.2020.1779353
12. [12]
  H. Guo, Z. Li, S.Y. Lin, et al., Chemosphere 265 (2021) 129089. doi: 10.1016/j.chemosphere.2020.129089
13. [13]
  Z. Ren, E. Kim, S.W. Pattinson, et al., Chem. Sci. 3 (2012) 209–216. doi: 10.1039/C1SC00511A
14. [14]
  F. Görmez, O. Görmez, B. Görmez, et al., J. Environ. Chem. Eng. 7 (2019) 102990. doi: 10.1016/j.jece.2019.102990
15. [15]
  M. Mortahida, J. Jang, M. Nawaz, S.R. Lim, D.S. Lee, Sci. Total Environ. 667 (2019) 741–750. doi: 10.1016/j.scitotenv.2019.02.376
16. [16]
  J. Wang, F. Yang, S. Wang, et al., J. Taiwan Inst. Chem. Eng. 99 (2019) 113–122. doi: 10.1016/j.jtice.2019.03.009
17. [17]
  H. Fan, G. Yi, X. Zhang, et al., Opt. Mater. 111 (2021) 110582. doi: 10.1016/j.optmat.2020.110582
18. [18]
  X. Wang, B. Guo, W. Fu, H. Yang, J. Water Process Eng. 31 (2019) 100814. doi: 10.1016/j.jwpe.2019.100814
19. [19]
  J. Nawrocki, B. Kasprzyk-Hordern, Appl. Catal. B: Environ. 99 (2010) 27–42. doi: 10.1016/j.apcatb.2010.06.033
20. [20]
  L. Jothinathan, J.Y. Hu, Water Res. 134 (2018) 63–73. doi: 10.1016/j.watres.2018.01.033
21. [21]
  X.W. Zhang, F. Wang, C.C. Wang, et al., Chem. Eng. J. 426 (2021) 131927. doi: 10.1016/j.cej.2021.131927
22. [22]
  Y. Gong, X. Zhao, H. Zhang, et al., Appl. Catal. B: Environ. 233 (2018) 35–45. doi: 10.1016/j.apcatb.2018.03.077
23. [23]
  Q.S. Wu, H.P. Yang, L. Kang, et al., Appl. Catal. B: Environ. 263 (2020) 118282. doi: 10.1016/j.apcatb.2019.118282
24. [24]
  H. Chen, J.L. Wang, J. Hazard. Mater. 403 (2021) 123697. doi: 10.1016/j.jhazmat.2020.123697
25. [25]
  D. Zheng, J. Cao, P. Wang, J. Zhao, C. Li, Environ. Technol. 42 (2020) 1–21.
26. [26]
  H. Chen, J.L. Wang, Chemosphere 234 (2019) 14–24. doi: 10.1016/j.chemosphere.2019.06.014
27. [27]
  M. Chen, N. Wang, X. Wang, Y. Zhou, L. Zhu, Chem. Eng. J. 413 (2021) 127539. doi: 10.1016/j.cej.2020.127539
28. [28]
  L. Yang, C.S. Chen, Y.J. Tu, Y.H. Huang, Z. Hui, Environ. Sci. Technol. 49 (2015) 6838–6845. doi: 10.1021/acs.est.5b00623
29. [29]
  L. Lei, X. Hao, X. Zhang, M. Zhou, Plasma Process Polym. 4 (2007) 455–462. doi: 10.1002/ppap.200600209
30. [30]
  S. Giannakis, K.Y.A. Lin, F. Ghanbari, Chem. Eng. J. 406 (2021) 127083. doi: 10.1016/j.cej.2020.127083
31. [31]
  G.D. Fang, D.D. Dionysiou, Y. Wang, et al., J. Hazard. Mater. 227-228 (2012) 394–401. doi: 10.1016/j.jhazmat.2012.05.074
32. [32]
  H.X. Wang, W. Rong, S.H. Wei, et al., Chin. Chem. Lett. 27 (2016) 1572–1576. doi: 10.1016/j.cclet.2016.03.003
33. [33]
  J. Hang, X.H. Yi, C.C. Wang, et al., J. Hazard. Mater. 424 (2022) 127415. doi: 10.1016/j.jhazmat.2021.127415
1. [1]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
2. [2]
  Yuanyi Zhou , Ke Ma , Jinfeng Liu , Zirun Zheng , Bo Hu , Yu Meng , Zhizhong Li , Mingshan Zhu . Is reactive oxygen species the only way for cancer inhibition over single atom nanomedicine? Autophagy regulation also works. Chinese Chemical Letters, 2024, 35(6): 109056-. doi: 10.1016/j.cclet.2023.109056
3. [3]
  Zhongyu Wang , Lijun Wang , Huaixin Zhao . DNA-based nanosystems to generate reactive oxygen species for nanomedicine. Chinese Chemical Letters, 2024, 35(11): 109637-. doi: 10.1016/j.cclet.2024.109637
4. [4]
  Ying Chen , Li Li , Junyao Zhang , Tongrui Sun , Xuan Zhang , Shiqi Zhang , Jia Huang , Yidong Zou . Tailored ionically conductive graphene oxide-encased metal ions for ultrasensitive cadaverine sensor. Chinese Chemical Letters, 2024, 35(8): 109102-. doi: 10.1016/j.cclet.2023.109102
5. [5]
  Qinyu Zhao , Yunchao Zhao , Songjing Zhong , Zhaoyang Yue , Zhuoheng Jiang , Shaobo Wang , Quanhong Hu , Shuncheng Yao , Kaikai Wen , Linlin Li . Urchin-like piezoelectric ZnSnO₃/Cu₃P p-n heterojunction for enhanced cancer sonodynamic therapy. Chinese Chemical Letters, 2024, 35(12): 109644-. doi: 10.1016/j.cclet.2024.109644
6. [6]
  Jia Fu , Shilong Zhang , Lirong Liang , Chunyu Du , Zhenqiang Ye , Guangming Chen . PEDOT-based thermoelectric composites: Preparation, mechanism and applications. Chinese Chemical Letters, 2024, 35(9): 109804-. doi: 10.1016/j.cclet.2024.109804
7. [7]
  Linghui Zou , Meng Cheng , Kaili Hu , Jianfang Feng , Liangxing Tu . Vesicular drug delivery systems for oral absorption enhancement. Chinese Chemical Letters, 2024, 35(7): 109129-. doi: 10.1016/j.cclet.2023.109129
8. [8]
  Xiaoning Li , Quanyu Shi , Meng Li , Ningxin Song , Yumeng Xiao , Huining Xiao , Tony D. James , Lei Feng . Functionalization of cellulose carbon dots with different elements (N, B and S) for mercury ion detection and anti-counterfeit applications. Chinese Chemical Letters, 2024, 35(7): 109021-. doi: 10.1016/j.cclet.2023.109021
9. [9]
  Shaojie Deng , Peihua Ma , Qinghong Bai , Xin Xiao . The transformation of nor-seco-cucurbit[10]uril to cucurbit[5]uril and cucurbit[8]uril controlled by its own concentration. Chinese Chemical Letters, 2025, 36(2): 109878-. doi: 10.1016/j.cclet.2024.109878
10. [10]
  Weidan Meng , Yanbo Zhou , Yi Zhou . Green innovation unleashed: Harnessing tungsten-based nanomaterials for catalyzing solar-driven carbon dioxide conversion. Chinese Chemical Letters, 2025, 36(2): 109961-. doi: 10.1016/j.cclet.2024.109961
11. [11]
  Ming-Yi Sun , Lu Zhang , Ya Li , Chong-Chen Wang , Peng Wang , Xueying Ren , Xiao-Hong Yi . Recovering Ag⁺ with nano-MOF-303 to form Ag/AgCl/MOF-303 photocatalyst: The role of stored Cl⁻ ions. Chinese Chemical Letters, 2025, 36(2): 110035-. doi: 10.1016/j.cclet.2024.110035
12. [12]
  Kun-Heng Li , Hong-Yang Zhao , Dan-Dan Wang , Ming-Hui Qi , Zi-Jian Xu , Jia-Mi Li , Zhi-Li Zhang , Shi-Wen Huang . Mitochondria-targeted nano-AIEgens as a powerful inducer for evoking immunogenic cell death. Chinese Chemical Letters, 2024, 35(5): 108882-. doi: 10.1016/j.cclet.2023.108882
13. [13]
  Feifei Wang , Hang Yao , Xinyue Wu , Yijian Tang , Yang Bai , Hui Chong , Huan Pang . Metal–organic framework and its composites modulate macrophage polarization in the treatment of inflammatory diseases. Chinese Chemical Letters, 2024, 35(5): 108821-. doi: 10.1016/j.cclet.2023.108821
14. [14]
  Yihao Zhang , Yang Jiao , Xianchao Jia , Qiaojia Guo , Chunying Duan . Highly effective self-assembled porphyrin MOCs nanomaterials for enhanced photodynamic therapy in tumor. Chinese Chemical Letters, 2024, 35(5): 108748-. doi: 10.1016/j.cclet.2023.108748
15. [15]
  Jiaqi Huang , Renjiang Kong , Yanmei Li , Ni Yan , Yeyang Wu , Ziwen Qiu , Zhenming Lu , Xiaona Rao , Shiying Li , Hong Cheng . Feedback enhanced tumor targeting delivery of albumin-based nanomedicine to amplify photodynamic therapy by regulating AMPK signaling and inhibiting GSTs. Chinese Chemical Letters, 2024, 35(8): 109254-. doi: 10.1016/j.cclet.2023.109254
16. [16]
  Haijing Cui , Weihao Zhu , Chuning Yue , Ming Yang , Wenzhi Ren , Aiguo Wu . Recent progress of ultrasound-responsive titanium dioxide sonosensitizers in cancer treatment. Chinese Chemical Letters, 2024, 35(10): 109727-. doi: 10.1016/j.cclet.2024.109727
17. [17]
  Xiangdong Lai , Tengfei Liu , Zengchao Guo , Yihan Wang , Jiang Xiao , Qingxiu Xia , Xiaohui Liu , Hui Jiang , Xuemei Wang . In situ formed fluorescent gold nanoclusters inhibit hair follicle regeneration in oxidative stress microenvironment via suppressing NFκB signal pathway. Chinese Chemical Letters, 2025, 36(2): 109762-. doi: 10.1016/j.cclet.2024.109762
18. [18]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
19. [19]
  Yuan CONG , Yunhao WANG , Wanping LI , Zhicheng ZHANG , Shuo LIU , Huiyuan GUO , Hongyu YUAN , Zhiping ZHOU . Construction and photocatalytic properties toward rhodamine B of CdS/Fe₃O₄ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2241-2249. doi: 10.11862/CJIC.20240219
20. [20]
  Chi Zhang , Ning Ding , Yuwei Pan , Lichun Fu , Ying Zhang . The degradation pathways of contaminants by reactive oxygen species generated in the Fenton/Fenton-like systems. Chinese Chemical Letters, 2024, 35(10): 109579-. doi: 10.1016/j.cclet.2024.109579

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(603)
HTML views(39)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Study on catalytic mechanisms of Fe3O4-rGOx in three typical advanced oxidation processes for tetracycline hydrochloride degradation

Metrics

通讯作者: 陈斌, bchen63@163.com

Study on catalytic mechanisms of Fe₃O₄-rGO_x in three typical advanced oxidation processes for tetracycline hydrochloride degradation