Citation: Lingling Du, Shizheng Zheng, Lijun Zheng, Xiaxia Xing, Dachi Yang, Can Xue. Surface engineering on segmented copper-iron nanowires arrays[J]. Chinese Chemical Letters, ;2022, 33(8): 4017-4020. doi: 10.1016/j.cclet.2022.02.038 shu

Surface engineering on segmented copper-iron nanowires arrays

Lingling Du ^a ,
Shizheng Zheng ^a ,
Lijun Zheng ^a ,
Xiaxia Xing ^a ,
Dachi Yang ^{a, *,} ,
Can Xue ^{b, *,}

a.
Department of Electronics, College of Electronic Information and Optical Engineering, Nankai University, Tianjin 300350, China
b.
School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore

yangdachi@nankai.edu.cn

cxue@ntu.edu.sg

Received Date: 9 January 2022
Revised Date: 8 February 2022
Accepted Date: 16 February 2022
Available Online: 19 February 2022

Figures(5)

Surface engineering that could modulate the surface shape to be endowed with the high specific surface ratio, abundant chemical dangling bonds and improved defects exposure is highly desired and needs further exploring. Here, we report a facile strategy of surface engineering on decorating the controllable segmented copper-iron nanowires arrays (Cu-Fe NWs) with their respective hydroxides. Specifically, the pristine segmented Cu-Fe NWs are firstly synthesized via sequentially electrodepositing Cu NWs and Fe NWs inside the nanochannels of anode aluminum oxide (AAO) template. Subsequently, the surface and interface of Cu-Fe NWs are wet-chemically etched, in which the metallic Cu and Fe are partially converted into Cu(OH)_x nano-fibrous roots (NFRs) and FeO(OH)_y nanoparticles (NPs), and finally decorate around the respective outer-surface of Cu NWs and Fe NWs segments. As one case of the applications in hydrogen evolution reaction (HER), our surface-modified Cu-Fe NWs exhibit improved catalytic activity compared with Fe NWs.
- Surface engineering,
- Segment,
- Copper-iron nanowires,
- Wet-chemical etching,
- Galvanic reaction
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